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Lead tetrafluoride

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Lead tetrafluoride

Unit cell of lead tetrafluoride
Names
IUPAC name
Tetrafluoroplumbane
Other names
Lead(IV) fluoride
Lead tetrafluoride
Tetrafluoridolead
Tetrafluoroplumbous anhydride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.102 Edit this at Wikidata
EC Number
  • 232-012-9
UNII
  • InChI=1S/4FH.Pb/h4*1H;/q;;;;+4/p-4
    Key: YAFKGUAJYKXPDI-UHFFFAOYSA-J
  • F[Pb](F)(F)F
Properties
PbF4
Molar mass 283.194 g/mol [1]
Appearance white to beige crystals [2]
Density 6.7 g/cm3 [2]
Melting point 600 °C (1,112 °F; 873 K)[2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lead tetrafluoride is a compound of lead and fluorine. The yellow solid (melting point 600 °C) is the only room-temperature stable tetrahalide of lead.[3] Lead tetrafluoride is isostructural with tin(IV) fluoride and contains planar layers of octahedrally coordinated lead, where the octahedra share four corners and there are two terminal, unshared, fluorine atoms trans to one another.[4]

References

  1. ^ "Lead(IV) fluoride | F4Pb - PubChem". Archived from the original on 2017-02-22. Retrieved 2017-02-22.
  2. ^ a b c "Lead Tetrafluoride | 7783-59-7".
  3. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 375–376, 381–382. ISBN 978-0-08-037941-8.
  4. ^ Inorganic Chemistry [Paperback],2d Edition, Housecroft, Sharpe,2004, Pearson Education ISBN 0130399132, ISBN 978-0130399137