Isotopes of thulium
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Standard atomic weight Ar°(Tm) | ||||||||||||||||||||||||||||||||||||
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Naturally occurring thulium (69Tm) is composed of 1 stable isotope, 169Tm (100% natural abundance). Thirty-four radioisotopes have been characterized, with the most stable being 171Tm with a half-life of 1.92 years, 170Tm with a half-life of 128.6 days, 168Tm with a half-life of 93.1 days, and 167Tm with a half-life of 9.25 days. All of the remaining radioactive isotopes have half-lives that are less than 64 hours, and the majority of these have half-lives that are less than 2 minutes. This element also has 26 meta states, with the most stable being 164mTm (t1/2 5.1 minutes), 160mTm (t1/2 74.5 seconds) and 155mTm (t1/2 45 seconds).
The isotopes of thulium range in atomic weight from 144.97007 u (145Tm) to 178.95534 u (179Tm). The primary decay mode before the most abundant stable isotope, 169Tm, is electron capture, and the primary mode after is beta emission. The primary decay products before 169Tm are erbium isotopes, and the primary products after are ytterbium isotopes.
List of isotopes
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life | decay mode(s)[4][n 1] |
daughter isotope(s)[n 2] |
nuclear spin and parity |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|
excitation energy | |||||||||
145Tm | 69 | 76 | 144.97007(43)# | 3.1(3) µs | (11/2−) | ||||
146Tm | 69 | 77 | 145.96643(43)# | 240(30) ms | p | 145Er | (6−) | ||
β+ (rare) | 146Er | ||||||||
146mTm | 71(6) keV | 72(23) ms | p | 145Er | (10+) | ||||
β+ (rare) | 146Er | ||||||||
147Tm | 69 | 78 | 146.96096(32)# | 0.58(3) s | β+ (85%) | 147Er | 11/2− | ||
p (15%) | 146Er | ||||||||
147mTm | 60(5) keV | 360(40) µs | 3/2+ | ||||||
148Tm | 69 | 79 | 147.95784(43)# | 0.7(2) s | β+ | 148Er | (10+) | ||
148mTm | 0.7 s | ||||||||
149Tm | 69 | 80 | 148.95272(32)# | 0.9(2) s | β+ (99.74%) | 149Er | (11/2−) | ||
β+, p (.26%) | 148Ho | ||||||||
150Tm | 69 | 81 | 149.94996(21)# | 3# s | β+ | 150Er | (1+) | ||
150m1Tm | 140(140)# keV | 2.20(6) s | β+ (98.8%) | 150Er | (6−) | ||||
β+, p (1.2%) | 149Ho | ||||||||
150m2Tm | 810(140)# keV | 5.2(3) ms | (10+) | ||||||
151Tm | 69 | 82 | 150.945483(22) | 4.17(10) s | β+ | 151Er | (11/2−) | ||
151m1Tm | 92(7) keV | 6.6(14) s | β+ | 151Er | (1/2+) | ||||
151m2Tm | 2655.67(22) keV | 451(24) ns | (27/2−) | ||||||
152Tm | 69 | 83 | 151.94442(8) | 8.0(10) s | β+ | 152Er | (2#)− | ||
152m1Tm | 100(80)# keV | 5.2(6) s | β+ | 152Er | (9)+ | ||||
152m2Tm | 2555.05(19)+X keV | 294(12) ns | (17+) | ||||||
153Tm | 69 | 84 | 152.942012(20) | 1.48(1) s | α (91%) | 149Ho | (11/2−) | ||
β+ (9%) | 153Er | ||||||||
153mTm | 43.2(2) keV | 2.5(2) s | α (92%) | 149Ho | (1/2+) | ||||
β+ (8%) | 153Er | ||||||||
154Tm | 69 | 85 | 153.941568(15) | 8.1(3) s | β+ (56%) | 154Er | (2−) | ||
α (44%) | 150Ho | ||||||||
154mTm | 70(50) keV | 3.30(7) s | α (90%) | 150Ho | (9+) | ||||
β+ (10%) | 154Er | ||||||||
155Tm | 69 | 86 | 154.939199(14) | 21.6(2) s | β+ (98.1%) | 155Er | (11/2−) | ||
α (1.9%) | 151Ho | ||||||||
155mTm | 41(6) keV | 45(3) s | β+ (92%) | 155Er | (1/2+) | ||||
α (8%) | 151Ho | ||||||||
156Tm | 69 | 87 | 155.938980(17) | 83.8(18) s | β+ (99.93%) | 156Er | 2− | ||
α (.064%) | 152Er | ||||||||
156mTm | 203.6(5) keV | ~400 ns | (11−) | ||||||
157Tm | 69 | 88 | 156.93697(3) | 3.63(9) min | β+ | 157Er | 1/2+ | ||
158Tm | 69 | 89 | 157.936980(27) | 3.98(6) min | β+ | 158Er | 2− | ||
158mTm | 50(100)# keV | ~20 ns | (5+) | ||||||
159Tm | 69 | 90 | 158.93498(3) | 9.13(16) min | β+ | 159Er | 5/2+ | ||
160Tm | 69 | 91 | 159.93526(4) | 9.4(3) min | β+ | 160Er | 1− | ||
160m1Tm | 70(20) keV | 74.5(15) s | IT (85%) | 160Tm | 5(+#) | ||||
β+ (15%) | 160Er | ||||||||
160m2Tm | 98.2+X keV | ~200 ns | (8) | ||||||
161Tm | 69 | 92 | 160.93355(3) | 30.2(8) min | β+ | 161Er | 7/2+ | ||
161m1Tm | 7.4(2) keV | 5# min | 1/2+ | ||||||
161m2Tm | 78.20(3) keV | 110(3) ns | 7/2− | ||||||
162Tm | 69 | 93 | 161.933995(28) | 21.70(19) min | β+ | 162Er | 1− | ||
162mTm | 130(40) keV | 24.3(17) s | IT (82%) | 162Tm | 5+ | ||||
β+ (18%) | 162Er | ||||||||
163Tm | 69 | 94 | 162.932651(6) | 1.810(5) h | β+ | 163Er | 1/2+ | ||
164Tm | 69 | 95 | 163.93356(3) | 2.0(1) min | β+ | 164Er | 1+ | ||
164mTm | 10(6) keV | 5.1(1) min | IT (80%) | 164Tm | 6− | ||||
β+ (20%) | 164Er | ||||||||
165Tm | 69 | 96 | 164.932435(4) | 30.06(3) h | β+ | 165Er | 1/2+ | ||
166Tm | 69 | 97 | 165.933554(13) | 7.70(3) h | β+ | 166Er | 2+ | ||
166mTm | 122(8) keV | 340(25) ms | IT | 166Tm | 6− | ||||
167Tm | 69 | 98 | 166.9328516(29) | 9.25(2) d | EC | 167Er | 1/2+ | ||
167m1Tm | 179.480(19) keV | 1.16(6) µs | (7/2)+ | ||||||
167m2Tm | 292.820(20) keV | 0.9(1) µs | 7/2− | ||||||
168Tm | 69 | 99 | 167.934173(3) | 93.1(2) d | β+ (99.99%) | 168Er | 3+ | ||
β− (.01%) | 168Yb | ||||||||
169Tm | 69 | 100 | 168.9342133(27) | Observationally Stable[n 3] | 1/2+ | 1.0000 | |||
170Tm | 69 | 101 | 169.9358014(27) | 128.6(3) d | β− (99.86%) | 170Yb | 1− | ||
EC (.14%) | 170Er | ||||||||
170mTm | 183.197(4) keV | 4.12(13) µs | (3)+ | ||||||
171Tm | 69 | 102 | 170.9364294(28) | 1.92(1) y | β− | 171Yb | 1/2+ | ||
171mTm | 424.9560(15) keV | 2.60(2) µs | 7/2− | ||||||
172Tm | 69 | 103 | 171.938400(6) | 63.6(2) h | β− | 172Yb | 2− | ||
173Tm | 69 | 104 | 172.939604(5) | 8.24(8) h | β− | 173Yb | (1/2+) | ||
173mTm | 317.73(20) keV | 10(3) µs | (7/2−) | ||||||
174Tm | 69 | 105 | 173.94217(5) | 5.4(1) min | β− | 174Yb | (4)− | ||
175Tm | 69 | 106 | 174.94384(5) | 15.2(5) min | β− | 175Yb | (1/2+) | ||
176Tm | 69 | 107 | 175.94699(11) | 1.85(3) min | β− | 176Yb | (4+) | ||
177Tm | 69 | 108 | 176.94904(32)# | 90(6) s | β− | 177Yb | (7/2−) | ||
178Tm | 69 | 109 | 177.95264(43)# | 30# s | β− | 178Yb | |||
179Tm | 69 | 110 | 178.95534(54)# | 20# s | β− | 179Yb | 1/2+# |
- ^ Abbreviations:
EC: Electron capture
IT: Isomeric transition - ^ Bold for stable isotopes
- ^ Believed to undergo α decay to 165Ho
Notes
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
References
- ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- ^ "Standard Atomic Weights: Thulium". CIAAW. 2021.
- ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
- ^ "Universal Nuclide Chart". nucleonica.
{{cite web}}
: Unknown parameter|registration=
ignored (|url-access=
suggested) (help)
- Isotope masses from:
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. Archived from the original (PDF) on 2008-09-23.
{{cite journal}}
: Unknown parameter|deadurl=
ignored (|url-status=
suggested) (help)
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. Archived from the original (PDF) on 2008-09-23.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter; J. K. Böhlke; P. De Bièvre; H. Hidaka; H. S. Peiser; K. J. R. Rosman; P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051.
{{cite journal}}
: Unknown parameter|laysummary=
ignored (help)
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. Archived from the original (PDF) on 2008-09-23.
{{cite journal}}
: Unknown parameter|deadurl=
ignored (|url-status=
suggested) (help) - National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved 23 February 2017.
- N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide (ed.). CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9.
{{cite book}}
: Unknown parameter|nopp=
ignored (|no-pp=
suggested) (help)
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. Archived from the original (PDF) on 2008-09-23.