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Starch

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For the Urhobo cuisine dish known as starch, see Usi (food). For the video game, see Starch (video game).
Starch
Cornstarch being mixed with water
Identifiers
ChemSpider
  • none
ECHA InfoCard 100.029.696 Edit this at Wikidata
EC Number
  • 232-679-6
RTECS number
  • GM5090000
UNII
Properties
(C
6H
10O
5)
n
Molar mass Variable
Appearance White powder
Density Variable[1]
Melting point decomposes
insoluble (see starch gelatinization)
Thermochemistry
4.1788 kilocalories per gram (17.484 kJ/g)[2] (Higher heating value)
Hazards
410 °C (770 °F; 683 K)
NIOSH (US health exposure limits):
PEL (Permissible)
 TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp)[3]
Safety data sheet (SDS) ICSC 1553
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Structure of the amylose molecule
Structure of the amylopectin molecule

Starch or amylum is a polymeric carbohydrate consisting of numerous glucose units joined by glycosidic bonds. This polysaccharide is produced by most green plants for energy storage. Worldwide, it is the most common carbohydrate in human diets, and is contained in large amounts in staple foods such as wheat, potatoes, maize (corn), rice, and cassava (manioc).

Pure starch is a white, tasteless and odorless powder that is insoluble in cold water or alcohol. It consists of two types of molecules: the linear and helical amylose and the branched amylopectin. Depending on the plant, starch generally contains 20 to 25% amylose and 75 to 80% amylopectin by weight.[4] Glycogen, the energy reserve of animals, is a more highly branched version of amylopectin.

In industry, starch is often converted into sugars, for example by malting. These sugars may be fermented to produce ethanol in the manufacture of beer, whisky and biofuel. In addition, sugars produced from processed starch are used in many processed foods.

Mixing most starches in warm water produces a paste, such as wheatpaste, which can be used as a thickening, stiffening or gluing agent. The principal non-food, industrial use of starch is as an adhesive in the papermaking process. A similar paste, clothing or laundry starch, can be applied to certain textile goods before ironing to stiffen them.

Etymology

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The word "starch" is from a Germanic root with the meanings "strong, stiff, strengthen, stiffen".[5]

Modern German Stärke (strength, starch) is related and refers to the main historical applications, its uses in textiles: sizing yarn for weaving, and starching linen.

The Greek term for starch, "amylon" (ἄμυλον), which means "not milled", is also related. It provides the root amyl, which is used as a prefix for several carbon compounds related to or derived from starch (e.g. amyl alcohol, amylose, amylopectin).

History

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Starch grains from the rhizomes of Typha (cattails, bullrushes) as flour have been identified from grinding stones in Europe dating back to 30,000 years ago.[6] Starch grains from sorghum were found on grind stones in caves in Ngalue, Mozambique dating up to 100,000 years ago.[7]

Pure extracted wheat starch paste was used in Ancient Egypt, possibly to glue papyrus.[8] The extraction of starch is first described in the Natural History of Pliny the Elder around 77–79 CE.[9] Romans used it also in cosmetic creams, to powder the hair and to thicken sauces. Persians and Indians used it to make dishes similar to gothumai wheat halva. Rice starch as surface treatment of paper has been used in paper production in China since 700 CE.[10] In the mid eighth century production of paper that was sized with wheat starch started in the Arabic world.[11] Laundry starch was first described in England in the beginning of the 15th century and was essential to make 16th century ruffed collars.[12]

Energy store of plants

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Potato starch granules in cells of the potato
Starch in endosperm in embryonic phase of maize seed

Plants produce glucose from carbon dioxide and water by photosynthesis. The glucose is used to generate the chemical energy required for general metabolism as well as a precursor to myriad organic building blocks such as nucleic acids, lipids, proteins, and structural polysaccharides such as cellulose. Most green plants store any extra glucose in the form of starch, which is packed into semicrystalline granules called starch or amyloplasts.[13] Toward the end of the growing season, starch accumulates in twigs of trees near the buds. Fruit, seeds, rhizomes, and tubers store starch to prepare for the next growing season. Young plants live on this stored energy in their roots, seeds, and fruits until they can find suitable soil in which to grow.[14] The starch is also consumed at night when photosynthesis is not occurring.

Green algae and land-plants store their starch in the plastids, whereas red algae, glaucophytes, cryptomonads, dinoflagellates and the parasitic apicomplexa store a similar type of polysaccharide called floridean starch in their cytosol or periplast.[15]

Especially when hydrated, glucose takes up much space and is osmotically active. Starch, on the other hand, being insoluble and therefore osmotically inactive, can be stored much more compactly. The semicrystalline granules generally consist of concentric layers of amylose and amylopectin which can be made bioavailable upon cellular demand in the plant.[16]

Amylose consists of long chains derived from glucose molecules connected by α-1,4-glycosidic linkage. Amylopectin is highly branched but also derived from glucose interconnected by α-1,6-glycosidic linkages. The same type of linkage is found in the animal reserve polysaccharide glycogen. By contrast, many structural polysaccharides such as chitin, cellulose, and peptidoglycan are linked by β-glycosidic bonds, which are more resistant to hydrolysis.[17]

Structure of starch particles

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Within plants, starch is stored in semi-crystalline granules. Each plant species has a distinctive starch granular size: rice starch is relatively small (about 2 μm), potato starches have larger granules (up to 100 μm) while wheat and tapioca fall in-between.[18] Unlike other botanical sources of starch, wheat starch has a bimodal size distribution, with both smaller and larger granules ranging from 2 to 55 μm.[18]

Some cultivated plant varieties have pure amylopectin starch without amylose, known as waxy starches. The most used is waxy maize, others are glutinous rice and waxy potato starch. Waxy starches undergo less retrogradation, resulting in a more stable paste. A maize cultivar with a relatively high proportion of amylose starch, amylomaize, is cultivated for the use of its gel strength and for use as a resistant starch (a starch that resists digestion) in food products.

Biosynthesis

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Plants synthesize starch in two types of tissues. The first type is storage tissues, for example, cereal endosperm, and storage roots and stems such as cassava and potato. The second type is green tissue, for example, leaves, where many plant species synthesize transitory starch on a daily basis. In both tissue types, starch is synthesized in a plastids (amyloplasts and chloroplasts).

The biochemical pathway involves conversion of glucose 1-phosphate to ADP-glucose using the enzyme glucose-1-phosphate adenylyltransferase. This step requires energy in the form of ATP. A number of starch synthases available in plastids then adds the ADP-glucose via α-1,4-glycosidic bond to a growing chain of glucose residues, liberating ADP. The ADP-glucose is almost certainly added to the non-reducing end of the amylose polymer, as the UDP-glucose is added to the non-reducing end of glycogen during glycogen synthesis.[19] The small glucan chain, further agglomerate to form initials of starch granules.

The biosynthesis and expansion of granules represent a complex molecular event that can be subdivided into four major steps, namely, granule initiation, coalescence of small granules,[20] phase transition, and expansion. Several proteins have been characterized for their involvement in each of these processes. For instance, a chloroplast membrane-associated protein, MFP1, determines the sites of granule initiation.[21] Another protein named PTST2 binds to small glucan chains and agglomerates to recruit starch synthase 4 (SS4).[22] Three other proteins, namely, PTST3, SS5, and MRC, are also known to be involved in the process of starch granule initiation.[23][24][25] Furthermore, two proteins named ESV and LESV play a role in the aqueous-to-crystalline phase transition of glucan chains.[26] Several catalytically active starch synthases, such as SS1, SS2, SS3, and GBSS, are critical for starch granule biosynthesis and play a catalytic role at each step of granule biogenesis and expansion.[27]

In addition to above proteins, starch branching enzymes (BEs) introduces α-1,6-glycosidic bonds between the glucose chains, creating the branched amylopectin. The starch debranching enzyme (DBE) isoamylase removes some of these branches. Several isoforms of these enzymes exist, leading to a highly complex synthesis process.[28]

Degradation

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The starch that is synthesized in plant leaves during the day is transitory: it serves as an energy source at night. Enzymes catalyze release of glucose from the granules. The insoluble, highly branched starch chains require phosphorylation in order to be accessible for degrading enzymes. The enzyme glucan, water dikinase (GWD) installs a phosphate at the C-6 position of glucose, close to the chain's 1,6-alpha branching bonds. A second enzyme, phosphoglucan, water dikinase (PWD) phosphorylates the glucose molecule at the C-3 position. After the second phosphorylation, the first degrading enzyme, beta-amylase (BAM) attacks the glucose chain at its non-reducing end. Maltose is the main product released. If the glucose chain consists of three or fewer molecules, BAM cannot release maltose. A second enzyme, disproportionating enzyme-1 (DPE1), combines two maltotriose molecules. From this chain, a glucose molecule is released. Now, BAM can release another maltose molecule from the remaining chain. This cycle repeats until starch is fully degraded. If BAM comes close to the phosphorylated branching point of the glucose chain, it can no longer release maltose. In order for the phosphorylated chain to be degraded, the enzyme isoamylase (ISA) is required.[29]

The products of starch degradation are predominantly maltose[30] and smaller amounts of glucose. These molecules are exported from the plastid to the cytosol, maltose via the maltose transporter and glucose by the plastidic glucose translocator (pGlcT).[31] These two sugars are used for sucrose synthesis. Sucrose can then be used in the oxidative pentose phosphate pathway in the mitochondria, to generate ATP at night.[29]

Starch industry

[edit]
Glucose syrup
Starch mill at Ballydugan (Northern Ireland), built in 1792
West Philadelphia Starch works at Philadelphia (Pennsylvania), 1850
Faultless Starch Company at Kansas City

In addition to starchy plants consumed directly, 66 million tonnes of starch were processed industrially in 2008. By 2011, production had increased to 73 million tons.[32]

In the EU the starch industry produced about 11 million tonnes in 2011, with around 40% being used for industrial applications and 60% for food uses,[33] most of the latter as glucose syrups.[34] In 2017 EU production was 11 million ton of which 9,4 million ton was consumed in the EU and of which 54% were starch sweeteners.[35]

The US produced about 27.5 million tons of starch in 2017, of which about 8.2 million tons was high fructose syrup, 6.2 million tons was glucose syrups, and 2.5 million tons were starch products.[clarification needed] The rest of the starch was used for producing ethanol (1.6 billion gallons).[36][37]

Industrial processing

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The starch industry extracts and refines starches from crops by wet grinding, washing, sieving and drying. Today, the main commercial refined starches are cornstarch, tapioca, arrowroot,[38] and wheat, rice, and potato starches. To a lesser extent, sources of refined starch are sweet potato, sago and mung bean. To this day, starch is extracted from more than 50 types of plants.

Crude starch is processed on an industrial scale to maltodextrin and glucose syrups and fructose syrups. These massive conversions are mediated by a variety of enzymes, which break down the starch to varying extents. Here breakdown involves hydrolysis, i.e. cleavage of bonds between sugar subunits by the addition of water. Some sugars are isomerized. The processes have been described as occurring in two phases: liquefaction and saccharification. The liquefaction converts starch into dextrins. Amylase is a key enzyme for producing dextrin. The saccharification converts dextrin into maltoses and glucose. Diverse enzymes are used in this second phase, including pullanase and other amylases.[39]

Corn starch, 800x magnified, under polarized light, showing characteristic extinction cross
Rice starch under transmitted light microscopy. A characteristic of rice starch is that granules have an angular outline and tend to clump.

Dextrinization

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If starch is subjected to dry heat, it breaks down to form dextrins, also called "pyrodextrins" in this context. This break down process is known as dextrinization. (Pyro)dextrins are mainly yellow to brown in color and dextrinization is partially responsible for the browning of toasted bread.[40]

Food

[edit]
Sago starch extraction from palm stems

Starch is the most common carbohydrate in the human diet and is contained in many staple foods. The major sources of starch intake worldwide are the cereals (rice, wheat, and maize) and the root vegetables (potatoes and cassava).[41] Many other starchy foods are grown, some only in specific climates, including acorns, arrowroot, arracacha, bananas, barley, breadfruit, buckwheat, canna, colocasia, cuckoo-pint, katakuri, kudzu, malanga, millet, oats, oca, polynesian arrowroot, sago, sorghum, sweet potatoes, rye, taro, chestnuts, water chestnuts, and yams, and many kinds of beans, such as favas, lentils, mung beans, peas, and chickpeas.

Before processed foods, people consumed large amounts of uncooked and unprocessed starch-containing plants, which contained high amounts of resistant starch. Microbes within the large intestine ferment or consume the starch, producing short-chain fatty acids, which are used as energy, and support the maintenance and growth of the microbes. Upon cooking, starch is transformed from an insoluble, difficult-to-digest granule into readily accessible glucose chains with very different nutritional and functional properties.[42]

In current diets, highly processed foods are more easily digested and release more glucose in the small intestine—less starch reaches the large intestine and more energy is absorbed by the body. It is thought that this shift in energy delivery (as a result of eating more processed foods) may be one of the contributing factors to the development of metabolic disorders of modern life, including obesity and diabetes.[43]

The amylose/amylopectin ratio, molecular weight and molecular fine structure influences the physicochemical properties as well as energy release of different types of starches.[44] In addition, cooking and food processing significantly impacts starch digestibility and energy release. Starch has been classified as rapidly digestible starch, slowly digestible starch and resistant starch, depending upon its digestion profile.[45] Raw starch granules resist digestion by human enzymes and do not break down into glucose in the small intestine - they reach the large intestine instead and function as prebiotic dietary fiber.[46] When starch granules are fully gelatinized and cooked, the starch becomes easily digestible and releases glucose quickly within the small intestine. When starchy foods are cooked and cooled, some of the glucose chains re-crystallize and become resistant to digestion again. Slowly digestible starch can be found in raw cereals, where digestion is slow but relatively complete within the small intestine.[47] Widely used prepared foods containing starch are bread, pancakes, cereals, noodles, pasta, porridge and tortilla.

During cooking with high heat, sugars released from starch can react with amino acids via the Maillard reaction, forming advanced glycation end-products (AGEs), contributing aromas, flavors and texture to foods.[48] One example of a dietary AGE is acrylamide. Recent evidence suggests that the intestinal fermentation of dietary AGEs may be associated with insulin resistance, atherosclerosis, diabetes and other inflammatory diseases.[49][50] This may be due to the impact of AGEs on intestinal permeability.[51]

Starch gelatinization during cake baking can be impaired by sugar competing for water, preventing gelatinization and improving texture.


Starch sugars

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Karo corn syrup advert 1917
Niagara corn starch advert 1880s

Starch can be hydrolyzed into simpler carbohydrates by acids, various enzymes, or a combination of the two. The resulting fragments are known as dextrins. The extent of conversion is typically quantified by dextrose equivalent (DE), which is roughly the fraction of the glycosidic bonds in starch that have been broken.

These starch sugars are by far the most common starch based food ingredient and are used as sweeteners in many drinks and foods. They include:

  • Maltodextrin, a lightly hydrolyzed (DE 10–20) starch product used as a bland-tasting filler and thickener.
  • Various glucose syrups (DE 30–70), also called corn syrups in the US, viscous solutions used as sweeteners and thickeners in many kinds of processed foods.
  • Dextrose (DE 100), commercial glucose, prepared by the complete hydrolysis of starch.
  • High fructose syrup, made by treating dextrose solutions with the enzyme glucose isomerase, until a substantial fraction of the glucose has been converted to fructose. In the U.S. high-fructose corn syrup is significantly cheaper than sugar, and is the principal sweetener used in processed foods and beverages.[52] Fructose also has better microbiological stability. One kind of high fructose corn syrup, HFCS-55, is sweeter than sucrose because it is made with more fructose, while the sweetness of HFCS-42 is on par with sucrose.[53][54]
  • Sugar alcohols, such as maltitol, erythritol, sorbitol, mannitol and hydrogenated starch hydrolysate, are sweeteners made by reducing sugars.

Modified starches

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The modified food starches are E coded according to European Food Safety Authority and INS coded Food Additives according to the Codex Alimentarius:[55]

INS 1400, 1401, 1402, 1403 and 1405 are in the EU food ingredients without an E-number.[56] Typical modified starches for technical applications are cationic starches, hydroxyethyl starch, carboxymethylated starches and thiolated starches.[57]

Use as food additive

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As an additive for food processing, food starches are typically used as thickeners and stabilizers in foods such as puddings, custards, soups, sauces, gravies, pie fillings, and salad dressings, and to make noodles and pastas. They function as thickeners, extenders, emulsion stabilizers and are exceptional binders in processed meats.

Gummed sweets such as jelly beans and wine gums are not manufactured using a mold in the conventional sense. A tray is filled with native starch and leveled. A positive mold is then pressed into the starch leaving an impression of 1,000 or so jelly beans. The jelly mix is then poured into the impressions and put onto a stove to set. This method greatly reduces the number of molds that must be manufactured.

Resistant starch

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Main article: Resistant starch

Resistant starch is starch that escapes digestion in the small intestine of healthy individuals. High-amylose starch from wheat or corn has a higher gelatinization temperature than other types of starch, and retains its resistant starch content through baking, mild extrusion and other food processing techniques. It is used as an insoluble dietary fiber in processed foods such as bread, pasta, cookies, crackers, pretzels and other low moisture foods. It is also utilized as a dietary supplement for its health benefits. Published studies have shown that resistant starch helps to improve insulin sensitivity,[58][59] reduces pro-inflammatory biomarkers interleukin 6 and tumor necrosis factor alpha[60][61] and improves markers of colonic function.[62] It has been suggested that resistant starch contributes to the health benefits of intact whole grains.[63]

Synthetic starch

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A cell-free chemoenzymatic process has been demonstrated to synthesize starch from CO2 and hydrogen.y. The chemical pathway of 11 core reactions was drafted by computational pathway design and converts CO2 to starch at a rate that is ~8.5-fold higher than starch synthesis in maize.[64][65]

Non-food applications

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Starch adhesive

Papermaking

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Papermaking is the largest non-food application for starches globally, consuming many millions of metric tons annually.[33] In a typical sheet of copy paper for instance, the starch content may be as high as 8%. Both chemically modified and unmodified starches are used in papermaking. In the wet part of the papermaking process, generally called the "wet-end", the starches used are cationic and have a positive charge bound to the starch polymer. These starch derivatives associate with the anionic or negatively charged paper fibers / cellulose and inorganic fillers. Cationic starches together with other retention and internal sizing agents help to give the necessary strength properties to the paper web formed in the papermaking process (wet strength), and to provide strength to the final paper sheet (dry strength).

In the dry end of the papermaking process, the paper web is rewetted with a starch based solution. The process is called surface sizing. Starches used have been chemically, or enzymatically depolymerized at the paper mill or by the starch industry (oxidized starch). The size/starch solutions are applied to the paper web by means of various mechanical presses (size presses). Together with surface sizing agents the surface starches impart additional strength to the paper web and additionally provide water hold out or "size" for superior printing properties. Starch is also used in paper coatings as one of the binders for the coating formulations which include a mixture of pigments, binders and thickeners. Coated paper has improved smoothness, hardness, whiteness and gloss and thus improves printing characteristics.

Adhesives

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Corrugated board adhesives are the next largest application of non-food starches globally. Starch glues are mostly based on unmodified native starches, plus some additive such as borax and caustic soda. Part of the starch is gelatinized to carry the slurry of uncooked starches and prevent sedimentation. This opaque glue is called a SteinHall adhesive. The glue is applied on tips of the fluting. The fluted paper is pressed to paper called liner. This is then dried under high heat, which causes the rest of the uncooked starch in glue to swell/gelatinize. This gelatinizing makes the glue a fast and strong adhesive for corrugated board production.

Starch is used in the manufacture of various adhesives or glues[66] for book-binding, wallpaper adhesives, paper sack production, tube winding, gummed paper, envelope adhesives, school glues and bottle labeling. Starch derivatives, such as yellow dextrins, can be modified by addition of some chemicals to form a hard glue for paper work; some of those forms use borax or soda ash, which are mixed with the starch solution at 50–70 °C (122–158 °F) to create a very good adhesive. Sodium silicate can be added to reinforce these formula.

A related large non-food starch application is in the construction industry, where starch is used in the gypsum wall board manufacturing process. Chemically modified or unmodified starches are added to the stucco containing primarily gypsum. Top and bottom heavyweight sheets of paper are applied to the formulation, and the process is allowed to heat and cure to form the eventual rigid wall board. The starches act as a glue for the cured gypsum rock with the paper covering, and also provide rigidity to the board.

Other

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  • Clothing or laundry starch is used in the laundering of clothes. It was widely used in Europe in the 16th and 17th centuries.
  • Textile chemicals from starch: warp sizing agents are used to reduce breaking of yarns during weaving. Starch is mainly used to size cotton based yarns. Modified starch is also used as textile printing thickener.
  • In oil exploration, starch is used to adjust the viscosity of drilling fluid, which is used to lubricate the drill head and suspend the grinding residue in petroleum extraction.
  • Starch is also used to make some packing peanuts, and some drop ceiling tiles.
  • In the printing industry, food grade starch[67] is used in the manufacture of anti-set-off spray powder used to separate printed sheets of paper to avoid wet ink being set off.
  • For body powder, powdered corn starch is used as a substitute for talcum powder, and similarly in other health and beauty products.
  • Starch is used to produce various bioplastics, synthetic polymers that are biodegradable. An example is polylactic acid based on glucose from starch.
  • Glucose from starch can be further fermented to biofuel corn ethanol using the so-called wet milling process. Today most bioethanol production plants use the dry milling process to ferment corn or other feedstock directly to ethanol.[68]
  • In the pharmaceutical industry, starch is also used as an excipient, as tablet disintegrant, and as binder. Synthetic amylose made from cellulose has a well-controlled degree of polymerization. Therefore, it can be used as a potential drug deliver carrier.[69]

Chemical tests

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Main article: Iodine test
Granules of wheat starch, stained with iodine, photographed through a light microscope

A solution of triiodide (I3−) (formed by mixing iodine and potassium iodide) can be used to test for starch. The colorless solution turns dark blue in the presence of starch.[70] The strength of the resulting blue color depends on the amount of amylose present. Waxy starches with little or no amylose present will color red. Benedict's test and Fehling's test is also done to indicate the presence of starch.

Safety

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In the US, the Occupational Safety and Health Administration (OSHA) has set the legal limit (Permissible exposure limit) for starch exposure in the workplace as 15 mg/m3 total exposure and 5 mg/m3 respiratory exposure over an eight-hour workday. The National Institute for Occupational Safety and Health (NIOSH) has set a Recommended exposure limit (REL) of 10 mg/m3 total exposure and 5 mg/m3 respiratory exposure over an eight-hour workday.[71]

See also

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References

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  1. ^ Whistler RL, BeMiller JN, Paschall EF (2 December 2012). Starch: Chemistry and Technology. Elsevier Science. p. 219. ISBN 9780323139502. OCLC 819646427. Archived from the original on 14 May 2022. Retrieved 13 May 2022. Starch has variable density depending on botanical origin, prior treatment, and method of measurement
  2. ^ CRC Handbook of Chemistry and Physics, 49th edition, 1968-1969, p. D-188.
  3. ^ NIOSH Pocket Guide to Chemical Hazards. "#0567". National Institute for Occupational Safety and Health (NIOSH).
  4. ^ Brown WH, Poon T (2005). Introduction to organic chemistry (3rd ed.). Wiley. p. 604. ISBN 978-0-471-44451-0.
  5. ^ New Shorter Oxford Dictionary, Oxford, 1993
  6. ^ Revedin A, Aranguren B, Becattini R, Longo L, Marconi E, Lippi MM, Skakun N, Sinitsyn A, et al. (2010). "Thirty thousand-year-old evidence of plant food processing". Proceedings of the National Academy of Sciences. 107 (44): 18815–9. Bibcode:2010PNAS..10718815R. doi:10.1073/pnas.1006993107. PMC 2973873. PMID 20956317.
  7. ^ "Porridge was eaten 100,000 years ago". The Telegraph. 18 Dec 2009. Archived from the original on 2022-01-11.
  8. ^ Pliny the Elder, The Natural History (Pliny), Book XIII, Chapter 26, The paste used in preparation of paper Archived 2022-05-14 at the Wayback Machine
  9. ^ Pliny the Elder, The Natural History (Pliny), Book XIII, Chapter 17, [1] Archived 2021-02-06 at the Wayback Machine
  10. ^ Hunter D (1947). Papermaking. DoverPublications. p. 194. ISBN 978-0-486-23619-3.
  11. ^ Garlick K (1986). "A Brief Review of the History of Sizing and Resizing Practices". The Book and Paper Group Annual. Vol. 5. Book and Paper Group of the American Institute for Conservation of Historic and Artistic Works.
  12. ^ "History of starching fabric, Laundry starch: from medieval luxury to Victorian mass market". Old & Interesting. 21 July 2010. Retrieved 30 March 2024.
  13. ^ Zobel H (1988). "Molecules to granules: a comprehensive starch review". Starch/Starke. 40 (2): 44–50. doi:10.1002/star.19880400203.
  14. ^ Bailey E, Long W (Jan 14, 1916 – Jan 13, 1917). "On the occurrence of starch in green fruits". Transactions of the Kansas Academy of Science. 28: 153–155. doi:10.2307/3624346. JSTOR 3624346.
  15. ^ Dauvillée D, Deschamps P, Ral JP, Plancke C, Putaux JL, Devassine J, Durand-Terrasson A, Devin A, Ball SG (2009). "Genetic dissection of floridean starch synthesis in the cytosol of the model dinoflagellate Crypthecodinium cohnii". Proceedings of the National Academy of Sciences of the United States of America. 106 (50): 21126–21130. Bibcode:2009PNAS..10621126D. doi:10.1073/pnas.0907424106. PMC 2795531. PMID 19940244.
  16. ^ Blennow A, Engelsen SB (10 Feb 2010). "Helix-breaking news: fighting crystalline starch energy deposits in the cell". Trends in Plant Science. 15 (4): 236–40. Bibcode:2010TPS....15..236B. doi:10.1016/j.tplants.2010.01.009. PMID 20149714.
  17. ^ Zeeman SC, Kossmann J, Smith AM (June 2, 2010). "Starch: Its Metabolism, Evolution, and Biotechnological Modification in Plants". Annual Review of Plant Biology. 61 (1): 209–234. doi:10.1146/annurev-arplant-042809-112301. PMID 20192737.
  18. ^ a b Rosicka-Kaczmarek J, Kwasniewska-Karolak I, Nebesny E, Komisarczyk A (2018). "The Functionality of Wheat Starch". Starch in Food. Duxford, United Kingdom: Woodhead Publishing. p. 331. ISBN 978-0-08-100868-3. Archived from the original on 2022-02-27. Retrieved 2022-02-27.
  19. ^ Nelson, D. (2013) Lehninger Principles of Biochemistry, 6th ed., W.H. Freeman and Company (p. 819)
  20. ^ Bürgy L, Eicke S, Kopp C, Jenny C, Lu KJ, Escrig S, Meibom A, Zeeman SC (2021-11-26). "Coalescence and directed anisotropic growth of starch granule initials in subdomains of Arabidopsis thaliana chloroplasts". Nature Communications. 12 (1): 6944. Bibcode:2021NatCo..12.6944B. doi:10.1038/s41467-021-27151-5. ISSN 2041-1723. PMC 8626487. PMID 34836943.
  21. ^ Sharma M, Abt MR, Eicke S, Ilse TE, Liu C, Lucas MS, Pfister B, Zeeman SC (2024-01-16). "MFP1 defines the subchloroplast location of starch granule initiation". Proceedings of the National Academy of Sciences. 121 (3): e2309666121. Bibcode:2024PNAS..12109666S. doi:10.1073/pnas.2309666121. ISSN 0027-8424. PMC 10801857. PMID 38190535.
  22. ^ Seung D, Boudet J, Monroe J, Schreier TB, David LC, Abt M, Lu KJ, Zanella M, Zeeman SC (July 2017). "Homologs of PROTEIN TARGETING TO STARCH Control Starch Granule Initiation in Arabidopsis Leaves". The Plant Cell. 29 (7): 1657–1677. doi:10.1105/tpc.17.00222. ISSN 1040-4651. PMC 5559754. PMID 28684429.
  23. ^ Seung D, Schreier TB, Bürgy L, Eicke S, Zeeman SC (July 2018). "Two Plastidial Coiled-Coil Proteins Are Essential for Normal Starch Granule Initiation in Arabidopsis". The Plant Cell. 30 (7): 1523–1542. doi:10.1105/tpc.18.00219. ISSN 1040-4651. PMC 6096604. PMID 29866647.
  24. ^ Vandromme C, Spriet C, Dauvillée D, Courseaux A, Putaux JL, Wychowski A, Krzewinski F, Facon M, D'Hulst C, Wattebled F (January 2019). "PII1: a protein involved in starch initiation that determines granule number and size in Arabidopsis chloroplast". New Phytologist. 221 (1): 356–370. Bibcode:2019NewPh.221..356V. doi:10.1111/nph.15356. ISSN 0028-646X. PMID 30055112.
  25. ^ Abt MR, Pfister B, Sharma M, Eicke S, Bürgy L, Neale I, Seung D, Zeeman SC (August 2020). "STARCH SYNTHASE5, a Noncanonical Starch Synthase-Like Protein, Promotes Starch Granule Initiation in Arabidopsis". The Plant Cell. 32 (8): 2543–2565. doi:10.1105/tpc.19.00946. ISSN 1040-4651. PMC 7401018. PMID 32471861.
  26. ^ Liu C, Pfister B, Osman R, Ritter M, Heutinck A, Sharma M, Eicke S, Fischer-Stettler M, Seung D, Bompard C, Abt MR, Zeeman SC (2023-05-26). "LIKE EARLY STARVATION 1 and EARLY STARVATION 1 promote and stabilize amylopectin phase transition in starch biosynthesis". Science Advances. 9 (21): eadg7448. Bibcode:2023SciA....9G7448L. doi:10.1126/sciadv.adg7448. ISSN 2375-2548. PMC 10219597. PMID 37235646.
  27. ^ Pfister B, Zeeman SC (July 2016). "Formation of starch in plant cells". Cellular and Molecular Life Sciences. 73 (14): 2781–2807. doi:10.1007/s00018-016-2250-x. ISSN 1420-682X. PMC 4919380. PMID 27166931.
  28. ^ Smith AM (2001). "The Biosynthesis of Starch Granules". Biomacromolecules. 2 (2): 335–41. doi:10.1021/bm000133c. PMID 11749190.
  29. ^ a b Smith AM, Zeeman SC, Smith SM (2005). "Starch Degradation" (PDF). Annual Review of Plant Biology. 56: 73–98. doi:10.1146/annurev.arplant.56.032604.144257. PMID 15862090. Archived from the original (PDF) on 2015-04-12. Retrieved 2014-02-13.
  30. ^ Weise SE, Weber AP, Sharkey TD (2004). "Maltose is the major form of carbon exported from the chloroplast at night". Planta. 218 (3): 474–82. Bibcode:2004Plant.218..474W. doi:10.1007/s00425-003-1128-y. PMID 14566561. S2CID 21921851.
  31. ^ Weber A, Servaites JC, Geiger DR, et al. (May 2000). "Identification, purification, and molecular cloning of a putative plastidic glucose translocator". Plant Cell. 12 (5): 787–802. doi:10.1105/tpc.12.5.787. PMC 139927. PMID 10810150.
  32. ^ "Starch Europe, AAF position on competitiveness, visited march 3 2019". Archived from the original on 2019-03-06. Retrieved 2019-03-03.
  33. ^ a b "NNFCC Renewable Chemicals Factsheet: Starch". Archived from the original on 2021-03-13. Retrieved 2011-05-25.
  34. ^ International Starch Institute Denmark, Starch production volume Archived 2021-03-13 at the Wayback Machine
  35. ^ "Starch Europe, Industry, visited march 3 2019". Archived from the original on 2019-03-06. Retrieved 2019-03-03.
  36. ^ "CRA, Industry overview 2017, visited on march 3 2019" (PDF). Archived (PDF) from the original on 2019-03-06. Retrieved 2019-03-03.
  37. ^ "Starch Europe, Updated position on the EU-US Transatlantic Trade and Investment Partnership, visited on march 3 2019". Archived from the original on 2019-03-06. Retrieved 2019-03-03.
  38. ^ Hemsley + Hemsley. "Arrowroot recipes". BBC Food. Archived from the original on 3 August 2017. Retrieved 13 August 2017.
  39. ^ Van Der Maarel MJ, Van Der Veen B, Uitdehaag JC, Leemhuis H, Dijkhuizen L (2002). "Properties and applications of starch-converting enzymes of the α-amylase family" (PDF). Journal of Biotechnology. 94 (2): 137–155. doi:10.1016/S0168-1656(01)00407-2. PMID 11796168. S2CID 32090939.
  40. ^ PhD JE (2013-11-18). Introduction to Polymer Chemistry: A Biobased Approach. DEStech Publications, Inc. p. 138. ISBN 9781605950303. Archived from the original on 2022-05-14. Retrieved 2022-01-03.
  41. ^ Anne-Charlotte Eliasson (2004). Starch in food: Structure, function and applications. Woodhead Publishing. ISBN 978-0-8493-2555-7.
  42. ^ Liu J, Huang S, Chao C, Yu J, Copeland L, Wang S (2022). "Changes of starch during thermal processing of foods: current status and future directions". Trends in Food Science & Technology. 119: 320–337. doi:10.1016/j.tifs.2021.12.011. S2CID 245211899. Archived from the original on 2022-05-14. Retrieved 2022-02-27.
  43. ^ Walter J, Ley R (October 2011). "The Human Gut Microbiome: Ecology and Recent Evolutionary Changes". Annual Review of Microbiology. 65 (1): 422–429. doi:10.1146/annurev-micro-090110-102830. PMID 21682646. Archived from the original on 2020-10-21. Retrieved 2020-10-13.
  44. ^ Lindeboom N, Chang PR, Tyler RT (1 Apr 2004). "Analytical, biochemical and physicochemical aspoects of starch granule size, with emphasis on small granule starches: a review". Starch-Stärke. 56 (3–4): 89–99. doi:10.1002/star.200300218.
  45. ^ Englyst HN, Kingman S, Cummings JH (October 1992). "Classification and measurement of nutritionally important starch fractions". European Journal of Clinical Nutrition. 46 (Suppl 2): S33-50. PMID 1330528.
  46. ^ Lockyer S, Nugent A (5 Jan 2017). "Health effects of resistant starch". Nutrition Bulletin. 42 (1): 10–41. doi:10.1111/nbu.12244.
  47. ^ Englyst H, Kingman S, Cummings J (Oct 1992). "Classification and measurement of nutritionally important starch fractions". European Journal of Clinical Nutrition. 46 (Suppl. 2): S33-50. PMID 1330528.
  48. ^ Ames JM (August 1998). "Applications of the Maillard reaction in the food industry". Food Chemistry. 62 (4): 431–439. doi:10.1016/S0308-8146(98)00078-8. Archived from the original on 2022-02-27. Retrieved 2022-02-27.
  49. ^ Kellow NJ, Coughlan MT (November 2015). "Effect of diet-derived advanced glycation end products on inflammation". Nutrition Reviews. 73 (11): 737–759. doi:10.1093/nutrit/nuv030. PMID 26377870. Archived from the original on 2022-02-27. Retrieved 2022-02-27.
  50. ^ Snelson M, Coughlan MT (Jan 22, 2019). "Dietary advanced glycation end products: digestion, metabolism and modulation of gut microbial ecology". Nutrients. 11 (2): 215. doi:10.3390/nu11020215. PMC 6413015. PMID 30678161.
  51. ^ Snelson M, Lucut E, Coughlan MT (2022). "The role of AGE-RAGE signaling as a modulator of gut permeability in diabetes". International Journal of Molecular Sciences. 23 (3): 1766. doi:10.3390/ijms23031766. PMC 8836043. PMID 35163688.
  52. ^ "Beverage daily: 'Sugar is much, much bigger': Rocketing HFCS prices don't spook Coke CEO". 30 July 2012. Archived from the original on 2013-03-30. Retrieved 2013-03-23.
  53. ^ Ophardt, Charles. "Sweetners – Introduction". Elmhurst College. Archived from the original on 2010-09-23. Retrieved 2010-10-23.
  54. ^ White JS (December 2, 2008). "HFCS: How Sweet It Is". Archived from the original on July 11, 2011. Retrieved October 23, 2010.
  55. ^ Modified Starches Archived 2018-03-29 at the Wayback Machine. CODEX ALIMENTARIUS published in FNP 52 Add 9 (2001)
  56. ^ "Database on Food Additives EU, visited December 6 2020". Archived from the original on 2021-08-17. Retrieved 2020-12-06.
  57. ^ Jelkmann M, Bonengel S, Menzel C, Markovic S, Bernkop-Schnürch A (2018). "New perspectives of starch: Synthesis and in vitro assessment of novel thiolated mucoadhesive derivatives". Int J Pharm. 546 (1–2): 70–77. doi:10.1016/j.ijpharm.2018.05.028. PMID 29758345. S2CID 44071363.
  58. ^ Rashed AA, Saparuddin F, Rathi DN, Nasir NN, Lokman EF (2022). "Effects of resistant starch interventions on metabolic biomarkers in pre-diabetes and diabetes adults". Frontiers in Nutrition. 8: 793414. doi:10.3389/fnut.2021.793414. PMC 8790517. PMID 35096939.
  59. ^ Balentine D. "Letter announcing decision for a health claim for high-amylose maize starch (containing type-2 resistant starch) and reduced risk of type 2 diabetes mellitus (Docket Number FDA-2015-Q-2352". U.S. Food & Drug Administration. United States Government. Archived from the original on 20 December 2016. Retrieved 19 December 2016.
  60. ^ Vahdat M, Hosseini SA, Khalatbari Mohseni G, Heshmati J, Rahimlou M (15 Apr 2020). "Effects of resistant starch interventions on circulating inflammatory biomarkers: a systematic review and meta-analysis of randomized controlled trials". Nutrition Journal. 19 (1): Article 33. doi:10.1186/s12937-020-00548-6. PMC 7158011. PMID 32293469.
  61. ^ Lu J, Ma B, Qiu X, Sun Z, Xiong K (30 Dec 2021). "Effects of resistant starch supplementation on oxidative stress and inflammation biomarkers: a systematic review and meta-analysis of randomized controlled trials". Asia Pac J Clin Nutr. 30 (4): 614–623. doi:10.6133/apjcn.202112_30(4).0008. PMID 34967190. Archived from the original on 27 February 2022. Retrieved 27 February 2022.
  62. ^ Nugent AP (2005). "Health properties of resistant starch". Nutrition Bulletin. 30: 27–54. doi:10.1111/j.1467-3010.2005.00481.x.
  63. ^ Higgins JA (2012). "Whole Grains, Legumes, and the Subsequent Meal Effect: Implications for Blood Glucose Control and the Role of Fermentation". Journal of Nutrition and Metabolism. 2012: 829238. doi:10.1155/2012/829238. PMC 3205742. PMID 22132324.
  64. ^ "World-first artificial synthesis of starch from CO2 outperforms nature". New Atlas. 28 September 2021. Archived from the original on 18 October 2021. Retrieved 18 October 2021.
  65. ^ Cai T, Sun H, Qiao J, Zhu L, Zhang F, Zhang J, Tang Z, Wei X, Yang J, Yuan Q, Wang W, Yang X, Chu H, Wang Q, You C, Ma H, Sun Y, Li Y, Li C, Jiang H, Wang Q, Ma Y (24 September 2021). "Cell-free chemoenzymatic starch synthesis from carbon dioxide". Science. 373 (6562): 1523–1527. Bibcode:2021Sci...373.1523C. doi:10.1126/science.abh4049. PMID 34554807. S2CID 237615280.
  66. ^ "Stuck on Starch: A new wood adhesive". US Department of Agriculture. 2000. Archived from the original on 2010-04-13. Retrieved 2011-01-14.
  67. ^ "Spray Powder". Russell-Webb. Archived from the original on 2007-08-09. Retrieved 2007-07-05.
  68. ^ "American coalition for ethanol, Ethanol facilities". Archived from the original on 2011-06-25. Retrieved 2011-06-02.
  69. ^ You C, Chen H, Myung S, Sathitsuksanoh N, Ma H, Zhang XZ, Li J, Zhang YH (April 15, 2013). "Enzymatic transformation of nonfood biomass to starch". Proceedings of the National Academy of Sciences. 110 (18): 7182–7187. Bibcode:2013PNAS..110.7182Y. doi:10.1073/pnas.1302420110. PMC 3645547. PMID 23589840.
  70. ^ Madhu S, Evans HA, Doan-Nguyen VV, Labram JG, Wu G, Chabinyc ML, Seshadri R, Wudl F (4 July 2016). "Infinite Polyiodide Chains in the Pyrroloperylene-Iodine Complex: Insights into the Starch-Iodine and Perylene-Iodine Complexes". Angewandte Chemie International Edition. 55 (28): 8032–8035. doi:10.1002/anie.201601585. PMID 27239781.
  71. ^ "CDC – NIOSH Pocket Guide to Chemical Hazards – Starch". CDC.gov. Archived from the original on 2015-09-24. Retrieved 2015-11-21.
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