Melezitose: Difference between revisions

Melezitose
Names
	IUPAC name (2R,3R,4S,5S,6R)-2-[[(2S,3S,4R,5R)-4-Hydroxy-2,5-bis(hydroxymethyl)-3-[[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)-2-tetrahydropyranyl]oxy]-2-tetrahydrofuranyl]oxy]-6-(hydroxymethyl)tetrahydropyran-3,4,5-triol
	Other names Melicitose
Identifiers
CAS Number	597-12-6 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:6731 ;
ChEMBL	ChEMBL386007 ;
ChemSpider	83787 ;
ECHA InfoCard	100.008.997
PubChem CID	92817;
CompTox Dashboard (EPA)	DTXSID20883458 ;
	InChI InChI=1S/C18H32O16/c19-1-5-8(23)11(26)13(28)16(30-5)32-15-10(25)7(3-21)33-18(15,4-22)34-17-14(29)12(27)9(24)6(2-20)31-17/h5-17,19-29H,1-4H2/t5-,6-,7-,8-,9-,10-,11+,12+,13-,14-,15+,16-,17-,18+/m1/s1 Key: QWIZNVHXZXRPDR-WSCXOGSTSA-N ; InChI=1/C18H32O16/c19-1-5-8(23)11(26)13(28)16(30-5)32-15-10(25)7(3-21)33-18(15,4-22)34-17-14(29)12(27)9(24)6(2-20)31-17/h5-17,19-29H,1-4H2/t5-,6-,7-,8-,9-,10-,11+,12+,13-,14-,15+,16-,17-,18+/m1/s1 Key: QWIZNVHXZXRPDR-WSCXOGSTBR;
	SMILES O1[C@H](CO)[C@@H](O)[C@H](O)[C@@H](O)[C@H]1O[C@@]3(O[C@@H]([C@@H](O)[C@@H]3O[C@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)CO)CO;
Properties
Chemical formula	C18H32O16
Molar mass	504.438 g·mol−1
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

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Revision as of 18:35, 11 July 2018

Melezitose, also spelled melicitose, is a nonreducing trisaccharide sugar that is produced by many plant sap eating insects, including aphids such as Cinara pilicornis by an enzyme reaction. This is beneficial to the insects, as it reduces the stress of osmosis by reducing their own water potential. The melezitose is part of the honeydew which acts as an attractant for ants and also as a food for bees.^[1] This is useful to the lice as they have a symbiotic relationship with ants. Melezitose can be partially hydrolyzed to glucose and turanose the latter of which is an isomer of sucrose.

References

^ Fischer, M. K; Shingleton, A. W (2001). "Host plant and ants influence the honeydew sugar composition of aphids". Functional Ecology. 15 (4): 544. doi:10.1046/j.0269-8463.2001.00550.x.

[1] Fischer, M. K; Shingleton, A. W (2001). "Host plant and ants influence the honeydew sugar composition of aphids". Functional Ecology. 15 (4): 544. doi:10.1046/j.0269-8463.2001.00550.x.

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+[[File:2018-07-11 - Melezitose - 3252.jpg|thumb|left|[[Honeycomb]] filled with Melezitose]]
 '''Melezitose''', also spelled '''melicitose''', is a nonreducing [[trisaccharide]] [[sugar]] that is produced by many [[plant sap]] eating insects, including [[aphid]]s such as ''[[Cinara pilicornis]]'' by an enzyme reaction. This is beneficial to the [[insects]], as it reduces the stress of [[osmosis]] by reducing their own water potential. The melezitose is part of the [[Honeydew (secretion)|honeydew]] which acts as an attractant for [[ants]] and also as a food for [[bee]]s.<ref>{{cite journal | doi = 10.1046/j.0269-8463.2001.00550.x| title = Host plant and ants influence the honeydew sugar composition of aphids| journal = Functional Ecology| volume = 15| issue = 4| pages = 544| year = 2001| last1 = Fischer| first1 = M. K| last2 = Shingleton| first2 = A. W}}</ref> This is useful to the lice as they have a symbiotic relationship with ants.  Melezitose can be partially [[hydrolysis|hydrolyzed]] to [[glucose]] and [[turanose]] the latter of which is an [[isomer]] of [[sucrose]].
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 ==References==
 {{reflist}}