Group (periodic table)
In chemistry, a group (also known as a family) is a column of elements in the periodic table of the chemical elements. There are 18 numbered groups in the periodic table, but the f-block columns (between groups 2 and 3) are not numbered. The elements in a group have similar physical or chemical characteristics of the outermost electron shells of their atoms (i.e., the same core charge), as most chemical properties are dominated by the orbital location of the outermost electron. There are three systems of group numbering. The modern numbering group 1 to group 18 is recommended by the International Union of Pure and Applied Chemistry (IUPAC). It replaces two older naming schemes that were mutually confusing. Also, groups may be identified by their topmost element or have a specific name. For example, group 16 is variously described as oxygen group and chalcogen.
CAS and old IUPAC numbering
Two earlier group number systems exist: CAS (Chemical Abstracts Service) and old IUPAC. Both use numerals (Arabic or Roman) and letters A and B. Both systems agree on the numbers. The numbers indicate approximately the highest oxidation number of the elements in that group, and so indicate similar chemistry with other elements with the same numeral. The number proceeds in a linearly increasing fashion for the most part, once on the left of the table, and once on the right (see List of oxidation states of the elements), with some irregularities in the transition metals. However, the two systems use the letters differently. For example, potassium (K) has one valence electron. Therefore, it is located in group 1. Calcium (Ca) is in group 2, for it contains two valence electrons.
In the old IUPAC system the letters A and B were designated to the left (A) and right (B) part of the table, while in the CAS system the letters A and B are designated to main group elements (A) and transition elements (B). The old IUPAC system was frequently used in Europe while the CAS is most common in America. The new IUPAC scheme was developed to replace both systems as they confusingly used the same names to mean different things. The new system simply numbers the groups increasingly from left to right on the standard periodic table. The IUPAC proposal was first circulated in 1985 for public comments, and was later included as part of the 1990 edition of the Nomenclature of Inorganic Chemistry.
Groups in the periodic table
|CAS (US, A-B-A)||IA||IIA||IIIB||IVB||VB||VIB||VIIB||VIIIB||IB||IIB||IIIA||IVA||VA||VIA||VIIA||VIIIA|
|old IUPAC (Europe, A-B)||IA||IIA||IIIA||IVA||VA||VIA||VIIA||VIII||IB||IIB||IIIB||IVB||VB||VIB||VIIB||Group 0|
|Trivial name||Alkali metals||Alkaline earth metals||Coinage metalse||Volatile metalse||Icosagense||Crystallogense||Pnictogens||Chalcogens||Halogens||Noble gases|
|Name by element||Lithium group||Beryllium group||Scandium group||Titanium group||Vanadium group||Chromium group||Manganese group||Iron group||Cobalt group||Nickel group||Copper group||Zinc group||Boron group||Carbon group||Nitrogen group||Oxygen group||Fluorine group||Helium or Neon group|
|Period 1||H c||He|
|Period 6||Cs||Ba||La d||Ce–Lu||Hf||Ta||W||Re||Os||Ir||Pt||Au||Hg||Tl||Pb||Bi||Po||At||Rn|
|Period 7||Fr||Ra||Ac d||Th–Lr||Rf||Db||Sg||Bh||Hs||Mt||Ds||Rg||Cn||Nh||Fl||Mc||Lv||Ts||Og|
|a Current, modern IUPAC group number.|
|b The noble gases were not discovered at the time of Mendeleev's original table. Later (1902), Mendeleev accepted the evidence for their existence, and placed them in a separate "group 0".|
|c Hydrogen (H), while placed in column 1, is not considered to be in the group alkali metals.|
|d Group 3 begins with scandium (Sc) and yttrium (Y) but different sources define the rest of the group as either (1) lutetium (Lu) and lawrencium (Lr), or (2) lanthanum (La) and actinium (Ac), or (3) the whole set of 15 lanthanides and 15 actinides. IUPAC has initiated a project to standardize the definition as either (1) Sc, Y, Lu and Lr, or (2) Sc, Y, La and Ac.|
|e This group name is not recommended by IUPAC.|
|Name by element||Trivial name
|Group 1||IA||IA||lithium family||alkali metals*||Hydrogen resides within this column, but is not considered an alkali metal.|
|Group 2||IIA||IIA||beryllium family||alkaline earth metals*|
|Group 3||IIIA||IIIB||scandium family||Consisting of rare earth elements plus actinides|
|Group 4||IVA||IVB||titanium family|
|Group 5||VA||VB||vanadium family|
|Group 6||VIA||VIB||chromium family|
|Group 7||VIIA||VIIB||manganese family|
|Group 8||VIII||VIIIB||iron family|
|Group 9||VIII||VIIIB||cobalt family|
|Group 10||VIII||VIIIB||nickel family|
|Group 11||IB||IB||copper family||coinage metals|
|Group 12||IIB||IIB||zinc family||volatile metals|
|Group 13||IIIB||IIIA||boron family||triels, icosagens||triels from Greek tri (three, III)|
|Group 14||IVB||IVA||carbon family||tetrels, crystallogens||tetrels from Greek tetra (four, IV)|
|Group 15||VB||VA||nitrogen family||pentels, pnictogens*||pentels from Greek penta (five, V)|
|Group 16||VIB||VIA||oxygen family||chalcogens*|
|Group 17||VIIB||VIIA||fluorine family||halogens*|
|Group 18||Group 0||VIIIA||helium family or neon family||noble gases*, aerogens|
- Fluck, E. (1988). "New Notations in the Periodic Table" (PDF). Pure Appl. Chem. IUPAC. 60 (3): 431–436. doi:10.1351/pac198860030431. Retrieved 24 March 2012.
- Leigh, G. J. Nomenclature of Inorganic Chemistry: Recommendations 1990. Blackwell Science, 1990. ISBN 0-632-02494-1.
- IUPAC (2005). "Nomenclature of inorganic chemistry" (PDF).
- "The constitution of group 3 of the periodic table". IUPAC. 2015-12-18.