Dioxygen monofluoride: Difference between revisions
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'''Dioxygen monofluoride''' is a binary [[inorganic compound]] radical of [[fluorine]] and [[oxygen]] with the chemical formula {{chem2|F2O}}.<ref>{{cite journal |last1=Campbell |first1=G.M. |title=A kinetic study of the equilibrium between dioxygen monofluoride and dioxygen difluoride |journal=Journal of Fluorine Chemistry |date=March 1990 |volume=46 |issue=3 |pages=357–366 |doi=10.1016/S0022-1139(00)82921-8 |url=https://www.sciencedirect.com/science/article/abs/pii/S0022113900829218 |access-date=18 May 2023}}</ref><ref>{{cite book |last1=Ebsworth |first1=E. A. V. |last2=Connor |first2=J. A. |last3=Turner |first3=J. J. |title=The Chemistry of Oxygen: Pergamon Texts in Inorganic Chemistry |date=6 June 2016 |publisher=[[Elsevier]] |isbn=978-1-4831-3789-6 |page=757 |url=https://www.google.ru/books/edition/The_Chemistry_of_Oxygen/GwJPDAAAQBAJ?hl=en&gbpv=1&dq=Dioxygen+monofluoride&pg=PA757&printsec=frontcover |access-date=18 May 2023 |language=en}}</ref> This is one of many known [[oxygen fluoride]]s. |
'''Dioxygen monofluoride''' is a binary [[inorganic compound]] radical of [[fluorine]] and [[oxygen]] with the chemical formula {{chem2|F2O}}.<ref>{{cite book |last1=Sen |first1=K. D. |title=Statistical Complexity: Applications in Electronic Structure |date=27 August 2011 |publisher=[[Springer Science & Business Media]] |isbn=978-90-481-3890-6 |page=199 |url=https://www.google.ru/books/edition/Statistical_Complexity/ijZU4Zn3muIC?hl=en&gbpv=1&dq=Dioxygen+monofluoride&pg=PA199&printsec=frontcover |access-date=18 May 2023 |language=en}}</ref><ref>{{cite journal |last1=Campbell |first1=G.M. |title=A kinetic study of the equilibrium between dioxygen monofluoride and dioxygen difluoride |journal=Journal of Fluorine Chemistry |date=March 1990 |volume=46 |issue=3 |pages=357–366 |doi=10.1016/S0022-1139(00)82921-8 |url=https://www.sciencedirect.com/science/article/abs/pii/S0022113900829218 |access-date=18 May 2023}}</ref><ref>{{cite book |last1=Ebsworth |first1=E. A. V. |last2=Connor |first2=J. A. |last3=Turner |first3=J. J. |title=The Chemistry of Oxygen: Pergamon Texts in Inorganic Chemistry |date=6 June 2016 |publisher=[[Elsevier]] |isbn=978-1-4831-3789-6 |page=757 |url=https://www.google.ru/books/edition/The_Chemistry_of_Oxygen/GwJPDAAAQBAJ?hl=en&gbpv=1&dq=Dioxygen+monofluoride&pg=PA757&printsec=frontcover |access-date=18 May 2023 |language=en}}</ref> This is one of many known [[oxygen fluoride]]s. |
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<ref>{{cite journal |last1=Spratley |first1=Richard D. |last2=Turner |first2=J. J. |last3=Pimentel |first3=George C. |title=Dioxygen Monofluoride: Infrared Spectrum, Vibrational Potential Function, and Bonding |journal=[[The Journal of Chemical Physics]] |date=March 1966 |volume=44 |issue=5 |pages=2063–2068 |doi=10.1063/1.1726981 |url=https://pubs.aip.org/aip/jcp/article/44/5/2063/83490/Dioxygen-Monofluoride-Infrared-Spectrum |access-date=18 May 2023}}</ref><ref>{{cite web |title=Dioxygen monofluoride |url=https://webbook.nist.gov/cgi/formula?ID=C15499237&Mask=800 |publisher=[[NIST]] |access-date=18 May 2023}}</ref> |
<ref>{{cite journal |last1=Spratley |first1=Richard D. |last2=Turner |first2=J. J. |last3=Pimentel |first3=George C. |title=Dioxygen Monofluoride: Infrared Spectrum, Vibrational Potential Function, and Bonding |journal=[[The Journal of Chemical Physics]] |date=March 1966 |volume=44 |issue=5 |pages=2063–2068 |doi=10.1063/1.1726981 |url=https://pubs.aip.org/aip/jcp/article/44/5/2063/83490/Dioxygen-Monofluoride-Infrared-Spectrum |access-date=18 May 2023}}</ref><ref>{{cite web |title=Dioxygen monofluoride |url=https://webbook.nist.gov/cgi/formula?ID=C15499237&Mask=800 |publisher=[[NIST]] |access-date=18 May 2023}}</ref> |
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Names | |
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Other names
(Fluoroperoxy)radical, fluoroperoxyl
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Identifiers | |
3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
F2O | |
Molar mass | 35.00 g/mol |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Dioxygen monofluoride is a binary inorganic compound radical of fluorine and oxygen with the chemical formula F2O.[1][2][3] This is one of many known oxygen fluorides.
Synthesis
Physical properties
Dioxygen monofluoride is a strong oxidizing agent, can be prepared in the coaxial reactor.[6]
References
- ^ Sen, K. D. (27 August 2011). Statistical Complexity: Applications in Electronic Structure. Springer Science & Business Media. p. 199. ISBN 978-90-481-3890-6. Retrieved 18 May 2023.
- ^ Campbell, G.M. (March 1990). "A kinetic study of the equilibrium between dioxygen monofluoride and dioxygen difluoride". Journal of Fluorine Chemistry. 46 (3): 357–366. doi:10.1016/S0022-1139(00)82921-8. Retrieved 18 May 2023.
- ^ Ebsworth, E. A. V.; Connor, J. A.; Turner, J. J. (6 June 2016). The Chemistry of Oxygen: Pergamon Texts in Inorganic Chemistry. Elsevier. p. 757. ISBN 978-1-4831-3789-6. Retrieved 18 May 2023.
- ^ Spratley, Richard D.; Turner, J. J.; Pimentel, George C. (March 1966). "Dioxygen Monofluoride: Infrared Spectrum, Vibrational Potential Function, and Bonding". The Journal of Chemical Physics. 44 (5): 2063–2068. doi:10.1063/1.1726981. Retrieved 18 May 2023.
- ^ "Dioxygen monofluoride". NIST. Retrieved 18 May 2023.
- ^ Council, National Research; Studies, Division on Earth and Life; Resources, Commission on Geosciences, Environment and; Wastes, Molten Salt Panel of the Committee on Remediation of Buried and Tank (26 February 1997). Evaluation of the U.S. Department of Energy's Alternatives for the Removal and Disposition of Molten Salt Reactor Experiment Fluoride Salts. National Academies Press. p. 104. ISBN 978-0-309-17492-3. Retrieved 18 May 2023.
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