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Extended periodic table

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There are currently seven periods in the periodic table of chemical elements, culminating with atomic number 118. If further elements with higher atomic numbers than this are discovered, they will be placed in additional periods, laid out (as with the existing periods) to illustrate periodically recurring trends in the properties of the elements concerned. Any additional periods are expected to contain a larger number of elements than the seventh period, as they are calculated to have an additional so-called g-block, containing 18 elements with partially filled g-orbitals in each period. An eight-period table containing this block was suggested by Glenn T. Seaborg in 1969.[1][2]

No elements in this region have been synthesized or discovered in nature.[3] The first element of the g-block may have atomic number 121, and thus would have the systematic name unbiunium. Elements in this region are likely to be highly unstable with respect to radioactive decay, and have extremely short half lives, although element 126 is hypothesized to be within an island of stability that is resistant to fission but not to alpha decay. It is not clear how many elements beyond the expected island of stability are physically possible, if period 8 is complete, or if there is a period 9.

According to the orbital approximation in quantum mechanical descriptions of atomic structure, the g-block would correspond to elements with partially filled g-orbitals. However, spin-orbit coupling effects reduce the validity of the orbital approximation substantially for elements of high atomic number.

Extended periodic table, including the g-block

It is unknown how far the periodic table might extend beyond the known 118 elements. Glenn T. Seaborg suggested that the highest possible element may be under Z=130.[4] However, Walter Greiner predicts that there may not be a highest possible element.[5] (See also extended periodic table (large version).)

Template:Wide template Template:Element color legend/spdfg blocks

All of these hypothetical undiscovered elements are named by the International Union of Pure and Applied Chemistry (IUPAC) systematic element name standard which creates a generic name for use until the element has been discovered, confirmed, and an official name approved.

As of April 2011, synthesis has been attempted for only ununennium, unbinilium, unbibium, unbiquadium, unbihexium, and unbiseptium. (Z = 119, 120, 122, 124, 126, and 127)

The positioning of the g-block in the table (to the left of the f-block, to the right, or in between) is speculative. The positions shown in the table above correspond to the assumption that the Madelung rule will continue to hold for higher atomic numbers; this assumption may or may not be true. At element 118, the orbitals 1s, 2s, 2p, 3s, 3p, 3d, 4s, 4p, 4d, 4f, 5s, 5p, 5d, 5f, 6s, 6p, 6d, 7s and 7p are assumed to be filled, with the remaining orbitals unfilled. The orbitals of the eighth period are predicted to be filled in the order 8s, 5g, 6f, 7d, 8p. However, after approximately element 120, the proximity of the electron shells makes placement in a simple table problematic.

Pyykkö model

Not all models show the higher elements following the pattern established by lighter elements. Pekka Pyykkö, for example, used computer modeling to calculate the positions of elements up to Z=172, and found that several were displaced from the Madelung energy-ordering rule.[6] He predicts that the orbital shells will fill up in this order:

  • 8s,
  • 5g,
  • the first two spaces of 8p,
  • 6f,
  • 7d,
  • 9s,
  • the first two spaces of 9p,
  • the rest of 8p.

He also suggests that period 8 be split into three parts:

  • 8a, containing 8s,
  • 8b, containing the first two elements of 8p,
  • 8c, containing 7d and the rest of 8p.[7]

Fricke et al. also predicted the extended periodic table up to 172[8]. The contrast to Pyykkö model is that they have one very long row from E119 onwards. Template:Wide template

The compact version.[7]

This figure reprinted by permission from P. Pyykkö,PCCP 2011, 13, 161. @RSC.
This figure reprinted by permission from P. Pyykkö,PCCP 2011, 13, 161. @RSC.


End of the periodic table

The number of physically possible elements is unknown. A low estimate is that the periodic table may end soon after the island of stability,[4] which is expected to center around Z = 126, as the extension of the periodic and nuclides tables is restricted by the proton and the neutron drip lines;[9] however, some, such as Walter Greiner, predict that there may not be an end to the periodic table at all.[5] Other predictions of an end to the periodic table include Z = 128 (John Emsley) and Z = 155 (Albert Khazan).[10]

Although Richard Feynman noted[11] that a simplistic interpretation of the relativistic Dirac equation runs into problems with electron orbitals at Z > 1/α ≈ 137[why?], suggesting that neutral atoms cannot exist beyond untriseptium, and that a periodic table of elements based on electron orbitals therefore breaks down at this point, a more rigorous analysis[according to whom?] calculates the limit to be Z ≈ 173, but also that this limit would not actually spell the end of the periodic table.[5]

Bohr model

The Bohr model exhibits difficulty for atoms with atomic number greater than 137, for the speed of an electron in a 1s electron orbital, v, is given by

where Z is the atomic number, and α is the fine structure constant, a measure of the strength of electromagnetic interactions.[12] Under this approximation, any element with an atomic number of greater than 137 would require 1s electrons to be traveling faster than c, the speed of light. Hence the non-relativistic Bohr model is clearly inaccurate when applied to such an element.

Relativistic Dirac equation

The relativistic Dirac equation has problems for Z > 137, for the ground state energy is

where m is the rest mass of the electron. Although for Z > 137, the wave function of the Dirac ground state is oscillatory, rather than bound, and there is no gap between the positive and negative energy spectra, as in the Klein paradox,[13] more accurate calculations taking into account the effects of the finite size of the nucleus indicate that the binding energy first exceeds 2mc2 for Z > Zcr ≈ 173. For Z > Zcr, if the innermost orbital (1s) is not filled, the electric field of the nucleus will pull an electron out of the vacuum, resulting in the spontaneous emission of a positron;[14] however, this does not happen if the innermost orbital is filled, so that Z = 173 does not constitute a limit to the periodic table.[5]

See also

References

  1. ^ Seaborg, Glenn (August 26, 1996). "An Early History of LBNL".
  2. ^ Frazier, K. (1978). "Superheavy Elements". Science News. 113 (15): 236–238. doi:10.2307/3963006. JSTOR 3963006.
  3. ^ Element 122 was claimed to exist naturally in April 2008, but this claim was widely believed to be erroneous. "Heaviest element claim criticised". Rsc.org. 2008-05-02. Retrieved 2010-03-16.
  4. ^ a b Seaborg (ca. 2006). "transuranium element (chemical element)". Encyclopædia Britannica. Retrieved 2010-03-16. {{cite web}}: Check date values in: |date= (help)
  5. ^ a b c d Philip Ball (November 2010). "Would element 137 really spell the end of the periodic table? Philip Ball examines the evidence". Chemistry World. Royal Society of Chemistry. Retrieved 2012-09-30.
  6. ^ "Extended elements: new periodic table". 2010.
  7. ^ a b Pyykkö, Pekka (2011). "A suggested periodic table up to Z≤ 172, based on Dirac–Fock calculations on atoms and ions". Physical Chemistry Chemical Physics. 13 (1): 161–8. Bibcode:2011PCCP...13..161P. doi:10.1039/c0cp01575j. PMID 20967377.
  8. ^ Fricke, B; Greiner, W; Waber, J.T (1971). "The continuation of the periodic table up to Z = 172. The chemistry of superheavy elements". Theoretica chimica acta. 21 (3): 235–260. doi:10.1007/BF01172015.
  9. ^ Cwiok, S.; Heenen, P.-H.; Nazarewicz, W. (2005). "Shape coexistence and triaxiality in the superheavy nuclei". Nature. 433 (7027): 705. Bibcode:2005Natur.433..705C. doi:10.1038/nature03336. PMID 15716943. {{cite journal}}: More than one of |pages= and |page= specified (help)
  10. ^ Emsley, John (2011). Nature's Building Blocks: An A-Z Guide to the Elements (New ed.). New York, NY: Oxford University Press. p. 593. ISBN 978-0-19-960563-7.
  11. ^ Elert, G. "Atomic Models". The Physics Hypertextbook. Retrieved 2009-10-09.
  12. ^ Eisberg, R.; Resnick, R. (1985). Quantum Physics of Atoms, Molecules, Solids, Nuclei and Particles. Wiley.
  13. ^ Bjorken, J. D.; Drell, S. D. (1964). Relativistic Quantum Mechanics. McGraw-Hill.
  14. ^ Greiner, W.; Schramm, S. (2008). "American Journal of Physics". 76: 509. {{cite journal}}: Cite journal requires |journal= (help), and references therein.
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