Sodium iodate

Sodium iodate
Names
	Other names Iodic acid, sodium salt
Identifiers
CAS Number	7681-55-2 ;
3D model (JSmol)	Interactive image;
ChemSpider	22760 ;
ECHA InfoCard	100.028.793
EC Number	231-672-5;
PubChem CID	23675764;
RTECS number	NN1400000;
CompTox Dashboard (EPA)	DTXSID90858754 ;
	InChI InChI=1S/HIO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 Key: WTCBONOLBHEDIL-UHFFFAOYSA-M ; InChI=1/HIO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 Key: WTCBONOLBHEDIL-REWHXWOFAB;
	SMILES [Na+].[O-]I(=O)=O;
Properties
Chemical formula	INaO3
Molar mass	197.891 g·mol−1
Appearance	White orthorhombic crystals
Odor	Odorless
Density	4.28 g/cm3
Melting point	425 °C (797 °F; 698 K) ; (anhydrous) decomposes; 19.85 °C (67.73 °F; 293.00 K); (pentahydrate)
Solubility in water	2.5 g/100 mL (0 °C); 8.98 g/100 mL (20 °C); 9.47 g/100 mL (25 °C); 32.59 g/100 mL (100 °C)
Solubility	Soluble in acetic acid; Insoluble in alcohol
Solubility in dimethylformamide	0.5 g/kg
Magnetic susceptibility (χ)	−53.0·10−6 cm3/mol
Structure
Crystal structure	Orthorhombic
Thermochemistry
Heat capacity (C)	125.5 J/mol·K
Std molar; entropy (S⦵298)	135 J/mol·K
Std enthalpy of; formation (ΔfH⦵298)	−490.4 kJ/mol
Gibbs free energy (ΔfG⦵)	35.1 kJ/mol
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H272, H302, H317, H334
Precautionary statements	P220, P261, P280, P342+P311
NFPA 704 (fire diamond)	1 0 1 OX
	Lethal dose or concentration (LD, LC):
LD50 (median dose)	108 mg/kg (mice, intravenous)
Related compounds
Other anions	Sodium iodide; Sodium periodate; Sodium bromate; Sodium chlorate
Other cations	Potassium iodate; Silver iodate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Sodium iodate (Na I O₃) is the sodium salt of iodic acid. Sodium iodate is an oxidizing agent, and as such it can cause fires upon contact with combustible materials or reducing agents.

Preparation

It can be prepared by reacting a sodium-containing base such as sodium hydroxide with iodic acid, for example:

HIO₃ + NaOH → NaIO₃ + H₂O

It can also be prepared by adding iodine to a hot, concentrated solution of sodium hydroxide or its carbonate:

3 I₂ + 6 NaOH → NaIO₃ + 5 NaI + 3 H₂O

Reactions

Sodium iodate can be oxidized to sodium periodate in water solutions by hypochlorites or other strong oxidizing agents:

NaIO 3 + NaOCl \to NaIO 4 + NaCl

Safety

Conditions/substances to avoid are: heat, shock, friction, combustible materials, reducing materials, aluminium, organic compounds, carbon, hydrogen peroxide, sulfides.

References

^ ^a ^b ^c ^d ^e ^f ^g http://chemister.ru/Database/properties-en.php?dbid=1&id=759
^ Seidell, Atherton; Linke, William F. (1919). Solubilities of Inorganic and Organic Compounds (2nd ed.). D. Van Nostrand Company.
Results here are multiplied by water's density at temperature of solution for unit conversion.
^ Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, Florida: CRC Press. pp. 4–85. ISBN 0-8493-0594-2.
^ ^a ^b ^c Sigma-Aldrich Co., Sodium iodate. Retrieved on 2014-05-25.

[chemister-1] ^ ^a ^b ^c ^d ^e ^f ^g http://chemister.ru/Database/properties-en.php?dbid=1&id=759

[sioc-2] Seidell, Atherton; Linke, William F. (1919). Solubilities of Inorganic and Organic Compounds (2nd ed.). D. Van Nostrand Company.
Results here are multiplied by water's density at temperature of solution for unit conversion.

[3] Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, Florida: CRC Press. pp. 4–85. ISBN 0-8493-0594-2.

[sigma-4] Sigma-Aldrich Co., Sodium iodate. Retrieved on 2014-05-25.

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