Uranium mining

Uranium mining is the process of extraction of uranium ore from the ground. The worldwide production of uranium in 2019 amounted to 53,656 tonnes. Kazakhstan, Canada, and Australia were the top three uranium producers, respectively, and together account for 68% of world production. Other countries producing more than 1,000 tonnes per year included Namibia, Niger, Russia, Uzbekistan, the United States, and China.^[2] Nearly all of the world's mined uranium is used to power nuclear power plants. Historically uranium was also used in applications such as uranium glass or ferrouranium but those applications have declined due to the radioactivity of uranium and are nowadays mostly supplied with a plentiful cheap supply of depleted uranium which is also used in uranium ammunition. In addition to being cheaper, depleted uranium is also less radioactive due to a lower content of short-lived ²³⁴
U and ²³⁵
U than natural uranium.

Uranium is mined by in-situ leaching (57% of world production) or by conventional underground or open-pit mining of ores (43% of production). During in-situ mining, a leaching solution is pumped down drill holes into the uranium ore deposit where it dissolves the ore minerals. The uranium-rich fluid is then pumped back to the surface and processed to extract the uranium compounds from solution. In conventional mining, ores are processed by grinding the ore materials to a uniform particle size and then treating the ore to extract the uranium by chemical leaching.^[3] The milling process commonly yields dry powder-form material consisting of natural uranium, "yellowcake," which is nowadays commonly sold on the uranium market as U₃O₈. While some nuclear power plants - most notably heavy water reactors like the CANDU - can operate with natural uranium (usually in the form of uranium dioxide), the vast majority of commercial nuclear power plants and many research reactors require uranium enrichment, which raises the content of ²³⁵
U from the natural 0.72% to 3-5% (for use in light water reactors) or even higher, depending on the application. Enrichment requires conversion of the yellowcake into uranium hexafluoride and production of the fuel (again usually uranium dioxide, but sometimes uranium carbide, uranium hydride or uranium nitride) from that feedstock.

History

Uranium minerals were noticed by miners for a long time prior to the discovery of uranium in 1789. The uranium mineral pitchblende, also known as uraninite, was reported from the Erzgebirge (Ore Mountains), Saxony, as early as 1565. Other early reports of pitchblende date from 1727 in Jáchymov and 1763 in Schwarzwald.^[4] The suffix "-blende" applied by Ore Mountain miners to the mineral long before the discovery of the element uranium indicates a mineral that looks like it contains some usable metal but (according to then available knowledge) doesn't. Terms for minerals later identified to contain cobalt (c.f. "Kobold" the modern standard German word for goblin) nickel or "Wolfram" (the standard German term for tungsten) were similarly derived from superstitious belief that some sort of "mountain gnome" had somehow "hexed" the minerals to trick (c.f. The German use of the term "blenden" cognate of "blind" for "tricking") the miners. Thus examining old documents about the presence of "worthless" -blende type minerals allowed easier exploration, once the true nature of these ores had been discovered.

In the early 19th century, uranium ore was recovered as a byproduct of mining in Saxony, Bohemia, and Cornwall. The first deliberate mining of radioactive ores took place in Joachimsthal, a silver-mining city now in the Czech Republic and origin of the word T(h)aler and from there dollar. Marie Skłodowska-Curie used pitchblende ore from Joachimsthal to isolate the element radium, a decay product of uranium. This discovery earned her her first Nobel Prize and represents an important step in the history of nuclear physics. Until World War II, uranium was mined primarily for its radium content; some carnotite deposits were mined primarily for the vanadium content. Sources for radium, contained in the uranium ore, were sought for use as luminous paint for watch dials and other instruments, as well as for health-related applications, some of which in retrospect were certainly harmful and some of which must be regarded as nuclear quackery even from a contemporary standpoint. Given that the half life of ²³⁸
U is almost 2.8 million times longer than that of ²²⁶
Ra, tons of uranium had to be processed to derive a few grams of radium, leaving large amounts of uranium with little economic uses. The byproduct uranium was used mostly as a yellow pigment. Ferrouranium started to be used by the Central Powers of World War I as a substitute for materials they could no longer import due to the British naval blockade. At the time both sides of the Ore Mountains were contained in territory controlled by the Central Powers, as the northern flank belonged to the German Empire whereas the southern flank belonged to Austria-Hungary. Given that Uranium was mostly seen as a "waste product" in radium-mining at the time, a plentiful supply was available even without scaling up mining. While radium has legitimate evidence based applications in nuclear medicine, the availability of other radionuclides with more desirable properties has all but eliminated the market for radium.

In the United States, the first radium/uranium ore was discovered in 1871 in gold mines near Central City, Colorado. This district produced about 50 tons of high grade ore between 1871 and 1895. Most American uranium ore before World War II came from vanadium deposits on the Colorado Plateau of Utah and Colorado.

In Cornwall, England, the South Terras Mine near St. Stephen opened for uranium production in 1873, and produced about 175 tons of ore before 1900. Other early uranium mining occurred in Autunois in France's Massif Central (whence the name Autunite for a uranium-bearing mineral once mined in the area), Oberpfalz in Bavaria, and Billingen in Sweden.

The Shinkolobwe deposit in Katanga, Belgian Congo (now Shaba Province, Democratic Republic of the Congo (DRC)), was discovered in 1913, and exploited by the Union Minière du Haut Katanga. Other important deposits mined early in the history of uranium mining include Port Radium, near Great Bear Lake, Canada, discovered in 1931; along with Beira Province, Portugal; Tyuya Muyun, Uzbekistan (whence Tyuyamunite); and Radium Hill, Australia.

Because of the need for the uranium for bomb research during World War II, the Manhattan Project used a variety of sources for the element. The Manhattan Project initially purchased uranium ore from the Belgian Congo, through the Union Minière du Haut Katanga. Later the project contracted with vanadium mining companies in the American Southwest. Purchases were also made from the Eldorado Mining and Refining Limited company in Canada. This company had large stocks of uranium as waste from its radium refining activities.

The smaller scale German nuclear program likewise tried to acquire uranium, putting the Berlin based Auergesellschaft, which had been taken from previous Jewish-German owners, in charge of acquisition. A substantial amount of uranium from the Belgian Congo (and thus the same source as the one used by the Americans) fell into German hands when the Wehrmacht conquered Belgium. Another important source was mining in the Ore Mountains (mostly on the Czech side, which had been annexed after the Munich treaty of 1938). While incompetence, bad luck, lack of resources and infighting kept the Germans from ever assembling enough uranium and neutron moderator in a single "pile" to achieve criticality, by the end of the war more than enough uranium had been in German hands to theoretically allow for the construction of a crude reactor on the scale of Chicago Pile-1 or the Soviet F-1 (nuclear reactor) if it had all been assembled in a single place. The Haigerloch research reactor (de:Forschungsreaktor Haigerloch) assembled months before the end of the war in Southwestern Germany was an extremely subcritical assembly which lacked both sufficient uranium and sufficient moderator to produce significant amounts of plutonium, let alone heat. A uranium cube thought to have belonged to Werner Heisenberg was analyzed decades later, confirming that the Germans were nowhere near plutonium production.^[5]

American uranium ores mined in Colorado were mixed ores of vanadium and uranium, but because of wartime secrecy, the Manhattan Project would publicly admit only to purchasing the vanadium, and did not pay the uranium miners for the uranium content. In a much later lawsuit, many miners were able to reclaim lost profits from the U.S. government. American ores had much lower uranium concentrations than the ore from the Belgian Congo, but they were pursued vigorously to ensure nuclear self-sufficiency. Similar efforts were undertaken in the Soviet Union, which did not have native stocks of uranium when it started developing its own atomic weapons program.

While the Soviet Republics of Kazakhstan and the RSFSR would later become some of the leading uranium producers in the world, immediately after the end of World War II the availability of large uranium deposits in the USSR wasn't yet known and thus the Soviets developed immense mining operations in their satellite states East Germany and Czechoslovakia which had known uranium deposits in the Ore Mountains. The deliberately opaquely named SDAG Wismut (the German term "Wismut" for Bismuth should give the illusion of prospection for a metal the Soviets definitely weren't after) became the biggest employer in the Saxon Ore Mountains and remote mining towns like Johanngeorgenstadt swelled to ten times their population in a few years. The mining cost immense amounts of money and miners were on the one hand subject to heavier repression and surveillance but on the other hand allowed more generous supply with consumer goods than other East Germans. While production was never able to compete with global uranium market prices, the dual use nature of the mined material as well as the possibility to pay miners in soft currency but sell uranium for hard currency or substitute imports which would've had to be paid for in hard currency tipped the scales in favor of continuing mining operations throughout the Cold War. After German reunification, mining was wound down^[6] and the arduous task of rehabilitating the land impacted by mining was begun.^[7] In the course of this, some remaining deposits had to be mined to reduce the potential harm from material leaching into groundwater, but this has since ceased as well, making the area in which uranium had been discovered two centuries prior entirely devoid of uranium mining.

In the 20th century, the United States was the world's largest uranium producer. Grants Uranium District in northwestern New Mexico was the largest United States uranium producer. The Gas Hills Uranium District was the second largest uranium producer. The famous Lucky Mc Mine is located in the Gas Hills near Riverton, Wyoming. Canada has since surpassed the United States as the cumulative largest producer in the world. In 1990, 55% of world production came from underground mines, but this shrank to 33% by 1999. From 2000, new Canadian mines again increased the proportion of underground mining, and with Olympic Dam it is now 37%. In situ leach (ISL, or ISR) mining has been steadily increasing its share of the total, mainly due to Kazakhstan.^[8] Unlike with coal, particularly lignite, where the biggest producers tend to also be the biggest consumers, the biggest uranium producers, Kazakhstan, Australia and Canada contain only one nation – Canada – who derives a significant proportion of electricity from nuclear power. On the other hand, big users of nuclear power like France, South Korea, India or Japan import most or all of the uranium used in their power plants as they have no or negligible domestic uranium resources. India in particular has been interested in the Thorium fuel cycle for decades, as India has much larger thorium reserves than it does uranium reserves. France historically derived significant shares of its uranium needs from its African colonies and continues to be politically and economically active in those African countries to ensure its uranium supply.

Deposit types

Many different types of uranium deposits have been discovered and mined. There are mainly three types of uranium deposits including unconformity-type deposits, namely paleoplacer deposits and sandstone-type also known as roll front type deposits.

Uranium deposits are classified into 15 categories according to their geological setting and the type of rock in which they are found. This geological classification system is determined by the International Atomic Energy Agency (IAEA).^[9]

Uranium is also contained in seawater but at present prices on the uranium market, costs would have to be lowered by a factor of 3–6 to make its recovery economical.^[10]

Sedimentary

The Mi Vida uranium mine, near Moab, Utah. Note alternating red and white/green sandstone. This type of uranium deposit is easier and cheaper to mine than the other types because the uranium is found not far from the surface of the crust.

Uranium deposits in sedimentary rocks include those in sandstone (in Canada and the western US),^[11] Precambrian unconformities (in Canada),^[11] phosphate,^[11] Precambrian quartz-pebble conglomerate, collapse breccia pipes (see Arizona breccia pipe uranium mineralization), and calcrete

Sandstone uranium deposits are generally of two types. Roll-front type deposits occur at the boundary between the up dip and oxidized part of a sandstone body and the deeper down dip reduced part of a sandstone body. Peneconcordant sandstone uranium deposits, also called Colorado Plateau-type deposits, most often occur within generally oxidized sandstone bodies, often in localized reduced zones, such as in association with carbonized wood in the sandstone.

Precambrian quartz-pebble conglomerate-type uranium deposits occur only in rocks older than two billion years old. The conglomerates also contain pyrite. These deposits have been mined in the Blind River-Elliot Lake district of Ontario, Canada, and from the gold-bearing Witwatersrand conglomerates of South Africa.

Unconformity-type deposits make up about 33% of the World Outside Centrally Planned Economies Areas (WOCA)'s uranium deposits.^[12]

Igneous or hydrothermal

Hydrothermal uranium deposits encompass the vein-type uranium ores. Vein-type hydrothermal uranium deposits represent epigenetic concentrations of uranium minerals that typically fill breccias, fractures, and shear zones.^[13] Many studies have sought to identify the source of uranium with hydrothermal vein-type deposits and the potential sources still remains a mystery, but are thought to include preexisting rocks that have been broken down by weathering and force that come from areas of long-term sediment build up.^[13] The South Chine Block is an example of a region that has been relying on vein-type hydrothermal uranium deposit demand for the past half century.^[13] Igneous deposits include nepheline syenite intrusives at Ilimaussaq, Greenland; the disseminated uranium deposit at Rossing, Namibia; uranium-bearing pegmatites, and the Aurora crater lake deposit of the McDermitt Caldera in Oregon. Disseminated deposits are also found in the states of Washington and Alaska in the US.^[14]^[15]

Breccia

Breccia uranium deposits are found in rocks that have been broken due to tectonic fracturing, or weathering. Breccia uranium deposits are most common in India, Australia and the United States.^[16] A large mass of breccia is called a breccia pipe or chimney and is composed of the rock forming an irregular and almost cylinder like shape. The origin of breccia pipe is uncertain but it is thought that they form on intersections and faults. When the formations are found solid in ground host rock called rock flour, it usually is often a site for copper or uranium mining. Copper Creek, Arizona is home to approximately 500 mineralized breccia pipes and Cripple Creek, Colorado also is a site that contains breccia pipe ore deposits that is associated with a volcanic pipe.

Olympic Dam mine, the world's largest uranium deposit, was discovered by Western Mining Corporation in 1975 and is owned by BHP.^[17]

Exploration

Uranium prospecting is similar to other forms of mineral exploration with the exception of some specialized instruments for detecting the presence of radioactive isotopes.

The Geiger counter was the original radiation detector, recording the total count rate from all energy levels of radiation. Ionization chambers and Geiger counters were first adapted for field use in the 1930s. The first transportable Geiger–Müller counter (weighing 25 kg) was constructed at the University of British Columbia in 1932. H.V. Ellsworth of the GSC built a lighter weight, more practical unit in 1934. Subsequent models were the principal instruments used for uranium prospecting for many years, until geiger counters were replaced by scintillation counters.

The use of airborne detectors to prospect for radioactive minerals was first proposed by G.C. Ridland, a geophysicist working at Port Radium in 1943. In 1947, the earliest recorded trial of airborne radiation detectors (ionization chambers and Geiger counters) was conducted by Eldorado Mining and Refining Limited. (a Canadian Crown Corporation since sold to become Cameco Corporation). The first patent for a portable gamma-ray spectrometer was filed by Professors Pringle, Roulston & Brownell of the University of Manitoba in 1949, the same year as they tested the first portable scintillation counter on the ground and in the air in northern Saskatchewan.

Airborne gamma-ray spectrometry is now the accepted leading technique for uranium prospecting with worldwide applications for geological mapping, mineral exploration & environmental monitoring. Airborne gamma-ray spectrometry used specifically for uranium measurement and prospecting must account for a number of factors like the distance between the source and the detector and the scattering of radiation through the minerals, surrounding earth and even in the air. In Australia, a Weathering Intensity Index has been developed to help prospectors based on the Shuttle Radar Topography Mission (SRTM) elevation and airborne gamma-ray spectrometry images.^[18]

A deposit of uranium, discovered by geophysical techniques, is evaluated and sampled to determine the amounts of uranium materials that are extractable at specified costs from the deposit. Uranium reserves are the amounts of ore that are estimated to be recoverable at stated costs. As prices rise or technology allows for lower cost of recovery of known, previously uneconomic, deposits, reserves increase. For uranium this effect is particularly pronounced as the biggest currently uneconomic reserve – uranium extraction from seawater – is bigger than all known land based resources of uranium combined.^[19]^[20]^[21]

Mining techniques

As with other types of hard rock mining there are several methods of extraction. In 2016, the percentage of the mined uranium produced by each mining method was: in-situ leach (49.7 percent), underground mining (30.8 percent), open pit (12.9 percent), heap leaching (0.4 percent), co-product/by-product (6.1%). The remaining 0,1% was derived as miscellaneous recovery.^[22]

Open pit

In open pit mining, overburden is removed by drilling and blasting to expose the ore body, which is then mined by blasting and excavation using loaders and dump trucks. Workers spend much time in enclosed cabins thus limiting exposure to radiation. Water is extensively used to suppress airborne dust levels. Groundwater is an issue in all types of mining, but in open pit mining, the usual way of dealing with it - i.e. when the target mineral is found below the natural water table - is to lower the water table by pumping off the water. The ground may settle considerably when groundwater is removed and may again move unpredictably when groundwater is allowed to rise again after mining is concluded. Land reclamation after mining takes different routes, depending on the amount of material removed. Due to the high energy density of uranium, it is often sufficient to fill in the former mine with the overburden, but in case of a mass deficit exceeding the height difference between the previous surface level and the natural water table, artificial lakes develop when groundwater removal ceases. If sulfites, sulfides or sulfates are present in the now-exposed rocks acid mine drainage can be a concern for those newly developing bodies of water. Mining companies are now required by law to establish a fund for future reclamation while mining is ongoing and those funds are usually deposited in such a way as to be unaffected by bankruptcy of the mining company.

Underground

If the uranium is too far below the surface for open pit mining, an underground mine might be used with tunnels and shafts dug to access and remove uranium ore.

Underground uranium mining is in principle no different from any other hard rock mining and other ores are often mined in association (e.g., copper, gold, silver). Once the ore body has been identified a shaft is sunk in the vicinity of the ore veins, and crosscuts are driven horizontally to the veins at various levels, usually every 100 to 150 metres. Similar tunnels, known as drifts, are driven along the ore veins from the crosscut. To extract the ore, the next step is to drive tunnels, known as raises when driven upwards and winzes when driven downwards, through the deposit from level to level. Raises are subsequently used to develop the stopes where the ore is mined from the veins.

The stope, which is the workshop of the mine, is the excavation from which the ore is extracted. Three methods of stope mining are commonly used. In the "cut and fill" or "open stoping" method, the space remaining following removal of ore after blasting is filled with waste rock and cement. In the "shrinkage" method, only sufficient broken ore is removed via the chutes below to allow miners working from the top of the pile to drill and blast the next layer to be broken off, eventually leaving a large hole. The method known as "room and pillar" is used for thinner, flatter ore bodies. In this method the ore body is first divided into blocks by intersecting drives, removing ore while so doing, and then systematically removing the blocks, leaving enough ore for roof support.

The health effects discovered from radon exposure in unventilated uranium mining prompted the switch away from uranium mining via tunnel mining towards open cut and in-situ leaching technology, a method of extraction that does not produce the same occupational hazards, or mine tailings, as conventional mining.

With regulations in place to ensure the use of high volume ventilation technology if any confined space uranium mining is occurring, occupational exposure and mining deaths can be largely eliminated.^[23]^[24] The Olympic Dam and Canadian underground mines are ventilated with powerful fans with radon levels being kept at a very low to practically "safe level" in uranium mines. Naturally occurring radon in other, non-uranium mines, also may need control by ventilation.^[25]

Heap leaching

Heap leaching is an extraction process by which chemicals (usually sulfuric acid) are used to extract the economic element from ore which has been mined and placed in piles on the surface. Heap leaching is generally economically feasible only for oxide ore deposits. Oxidation of sulfide deposits occurs during the geological process called weathering. Therefore, oxide ore deposits are typically found close to the surface. If there are no other economic elements within the ore a mine might choose to extract the uranium using a leaching agent, usually a low molar sulfuric acid.

If the economic and geological conditions are right, the mining company will level large areas of land with a small gradient, layering it with thick plastic (usually HDPE or LLDPE), sometimes with clay, silt or sand beneath the plastic liner. The extracted ore will typically be run through a crusher and placed in heaps atop the plastic. The leaching agent will then be sprayed on the ore for 30–90 days. As the leaching agent filters through the heap, the uranium will break its bonds with the oxide rock and enter the solution. The solution will then filter along the gradient into collecting pools which will then be pumped to on-site plants for further processing. Only some of the uranium (commonly about 70%) is actually extracted.

The uranium concentrations within the solution are very important for the efficient separation of pure uranium from the acid. As different heaps will yield different concentrations, the solution is pumped to a mixing plant that is carefully monitored. The properly balanced solution is then pumped into a processing plant where the uranium is separated from the sulfuric acid.

Heap leach is significantly cheaper than traditional milling processes. The low costs allow for lower grade ore to be economically feasible (given that it is the right type of ore body). Environmental law requires that the surrounding ground water is continually monitored for possible contamination. The mine will also have to have continued monitoring even after the shutdown of the mine. In the past mining companies would sometimes go bankrupt, leaving the responsibility of mine reclamation to the public. Recent additions to the mining law require that companies set aside the money for reclamation before the beginning of the project. The money will be held by the public to insure adherence to environmental standards if the company were to ever go bankrupt.^[26]

In-situ leaching

In-situ leaching (ISL), also known as solution mining, or in-situ recovery (ISR) in North America, involves leaving the ore where it is in the ground, and recovering the minerals from it by dissolving them and pumping the pregnant solution to the surface where the minerals can be recovered. Consequently, there is little surface disturbance and no tailings or waste rock generated. However, the orebody needs to be permeable to the liquids used, and located so that they do not contaminate ground water away from the orebody.

Uranium ISL uses the native groundwater in the orebody which is fortified with a complexing agent and in most cases an oxidant. It is then pumped through the underground orebody to recover the minerals in it by leaching. Once the pregnant solution is returned to the surface, the uranium is recovered in much the same way as in any other uranium plant (mill).

In Australian ISL mines (Beverley, Four Mile and Honeymoon Mine) the oxidant used is hydrogen peroxide and the complexing agent sulfuric acid. Kazakh ISL mines generally do not employ an oxidant but use much higher acid concentrations in the circulating solutions. ISL mines in the USA use an alkali leach due to the presence of significant quantities of acid-consuming minerals such as gypsum and limestone in the host aquifers. Any more than a few percent carbonate minerals means that alkali leach must be used in preference to the more efficient acid leach.

The Australian government has published a best practice guide for in situ leach mining of uranium, which is being revised to take account of international differences.^[27]

Seawater recovery

The uranium concentration in sea water is low, approximately 3.3 parts per billion or 3.3 micrograms per liter of seawater.^[28] But the quantity of this resource is gigantic and some scientists believe this resource is practically limitless with respect to world-wide demand. That is to say, if even a portion of the uranium in seawater could be used the entire world's nuclear power generation fuel could be provided over a long time period.^[29] Some anti-nuclear proponents claim this statistic is exaggerated.^[30] Although research and development for recovery of this low-concentration element by inorganic adsorbents such as titanium oxide compounds has occurred since the 1960s in the United Kingdom, France, Germany, and Japan, this research was halted due to low recovery efficiency.

At the Takasaki Radiation Chemistry Research Establishment of the Japan Atomic Energy Research Institute (JAERI Takasaki Research Establishment), research and development has continued culminating in the production of adsorbent by irradiation of polymer fiber. Adsorbents have been synthesized that have a functional group (amidoxime group) that selectively adsorbs heavy metals, and the performance of such adsorbents has been improved. Uranium adsorption capacity of the polymer fiber adsorbent is high, approximately tenfold greater in comparison to the conventional titanium oxide adsorbent.

One method of extracting uranium from seawater is using a uranium-specific nonwoven fabric as an adsorbent. The total amount of uranium recovered from three collection boxes containing 350 kg of fabric was >1 kg of yellowcake after 240 days of submersion in the ocean.^[31] The experiment by Seko et al. was repeated by Tamada et al. in 2006. They found that the cost varied from ¥15,000 to ¥88,000 depending on assumptions and "The lowest cost attainable now is ¥25,000 with 4g-U/kg-adsorbent used in the sea area of Okinawa, with 18 repetitionuses [sic]." With the May, 2008 exchange rate, this was about $240/kg-U.^[32]

In 2012, ORNL researchers announced the successful development of a new adsorbent material dubbed "HiCap", which vastly outperforms previous best adsorbents, which perform surface retention of solid or gas molecules, atoms or ions.^[33] "We have shown that our adsorbents can extract five to seven times more uranium at uptake rates seven times faster than the world's best adsorbents," said Chris Janke, one of the inventors and a member of ORNL's Materials Science and Technology Division. HiCap also effectively removes toxic metals from water, according to results verified by researchers at Pacific Northwest National Laboratory.^[34]^[35]

In 2012 it was estimated that this fuel source could be extracted at 10 times the current price of uranium.^[36] In 2014, with the advances made in the efficiency of seawater uranium extraction, it was suggested that it would be economically competitive to produce fuel for light water reactors from seawater if the process was implemented at large scale.^[37] Uranium extracted on an industrial scale from seawater would constantly be replenished by both river erosion of rocks and the natural process of uranium dissolved from the surface area of the ocean floor, both of which maintain the solubility equilibria of seawater concentration at a stable level.^[38] Some commentators have argued that this strengthens the case for nuclear power to be considered a renewable energy.^[39]

Co-product/by-product

Uranium can be recovered as a by-product along with other co-products such as molybdenum, vanadium, nickel, zinc and petroleum products. Uranium is also often found in phosphate minerals, where it has to be removed because phosphate is mostly used for fertilizers. Phosphogypsum is a waste product from phosphate mining that can contain significant amounts of uranium and radium. Coal fly ash also contains significant amounts of uranium and has been suggested as a source for uranium extraction.

Prices

Generally speaking, in the case of nuclear energy the cost of fuel has the lowest share in total energy costs of all fuel consuming energy forms (i.e. Fossil fuels, biomass and nuclear). Furthermore, given the immense energy density of nuclear fuel (particularly in the form of enriched uranium or high grade plutonium), it is easy to stockpile amounts of fuel material to last several years at constant consumption. Power plants that do not have online refuelling capabilities, as is the case for the vast majority of commercial power plants in operation, will refuel as seldom as possible to avoid costly downtime and usually plan refuelling shutdowns long in advance so as to allow maintenance and inspection to use the scheduled downtime as well. As such power plant operators tend to have long-term contracts with fuel suppliers that are – if at all – only minorly affected by the fluctuations of uranium prices. The effect on electricity price for end consumers is negligible even in countries like France, which derive a majority of their electric energy from nuclear power. Nonetheless, short term price developments like the 2007 uranium bubble, can have drastic effects on mining companies, prospection and the economic calculations as to whether a certain deposit is worthwhile for commercial purposes.

Since 1981 uranium prices and quantities in the US are reported by the Department of Energy.^[40]^[41] The import price dropped from 32.90 US$/lb-U₃O₈ in 1981 down to 12.55 in 1990 and to below 10 US$/lb-U₃O₈ in the year 2000. Prices paid for uranium during the 1970s were higher, 43 US$/lb-U₃O₈ is reported as the selling price for Australian uranium in 1978 by the Nuclear Information Centre. Uranium prices reached an all-time low in 2001, costing US$7/lb, but in April 2007 the price of Uranium on the spot market rose to US$113.00/lb,^[42] a high point of the uranium bubble of 2007. This was very close to the all time high (adjusted for inflation) in 1977.^[43]

Following the 2011 Fukushima nuclear disaster, the global uranium sector remained depressed with the uranium price falling more than 50%, declining share values, and reduced profitability of uranium producers since March 2011 and into 2014. As a result, uranium companies worldwide are reducing costs, and limiting operations.^[44]^{[unreliable source?]} As an example, Westwater Resources (previously Uranium Resources), has had to cease all uranium operations due to unfavorable prices. Since then, Westwater has tried branching out into other markets, namely lithium and graphite.^[45]

As of July 2014, the price of uranium concentrate remained near a five-year low, the uranium price having fallen more than 50% from the peak spot price in January 2011, reflecting the loss of Japanese demand following the 2011 Fukushima nuclear disaster.^[46] As a result of continued low prices, in February 2014 mining company Cameco deferred plans to expand production from existing Canadian mines, although it continued work to open a new mine at Cigar Lake.^[47] Also in February 2014, Paladin energy suspended operations at its mine in Malawi, saying that the high-cost operation was losing money at current prices.^[48]

Effect of uranium price on mining and nuclear power plants

In general short term fluctuations in the price of uranium are of more concern to operators and owners of mines and potentially lucrative deposits than to power plant operators. Due to its high energy density, uranium is easy to stockpile in the form of strategic reserves and thus a short term increase in prices can be compensated by accessing those reserves.^[49] Furthermore, many countries have de facto reserves in the form of reprocessed uranium^[50] or depleted uranium which still contain a share of fissile material that can make re-enrichment worthwhile if market conditions call for it.^[51] Nuclear reprocessing of spent fuel is - as of the 2020s - done commercially primarily to use the fissile material still contained in spent fuel. The commonly employed PUREX process recovers uranium and plutonium which can then be converted into MOX-fuel for use in the same light water reactors that produced the spent fuel. Whether reprocessing is economical is subject to much debate and depends in part on assumptions as to the price of uranium and the cost of disposal via deep geological repository or nuclear transmutation.^[52]^[53]^[54] Reactors that can run on natural uranium consume less mined uranium per unit of power produced but can have higher capital costs to build due to the need for heavy water as moderator.^[55] Furthermore they need to be capable of online refueling because the burnup achievable with natural uranium is lower than that achievable with enriched uranium - having to shut down the entire reactor for every refueling would quickly make such a reactor uneconomic.^[56] Breeder reactors also become more economical as uranium prices rise and it was among other things a decline in uranium prices in the 1970s that led to a decline in interest in breeder reactor technology.^[57]^[58] The thorium fuel cycle is a further alternative if and when uranium prices remain at a sustained high level and consequently interest in this alternative to current "mainstream" light water reactor technology is dependent in no small part on uranium prices.^[59]

Politics

In the beginning of the Cold War, to ensure adequate supplies of uranium for national defense, the United States Congress passed the U.S. Atomic Energy Act of 1946, creating the Atomic Energy Commission (AEC) which had the power to withdraw prospective uranium mining land from public purchase, and also to manipulate the price of uranium to meet national needs. By setting a high price for uranium ore, the AEC created a uranium "boom" in the early 1950s, which attracted many prospectors to the Four Corners region of the country. Moab, Utah became known as the Uranium-capital of the world,^{[citation needed]} when geologist Charles Steen discovered such an ore in 1952, even though American ore sources were considerably less potent than those in the Belgian Congo or South Africa.

In the 1950s methods for extracting diluted uranium and thorium, found in abundance in granite or seawater, were pursued.^[60] Scientists speculated that, used in a breeder reactor, these materials would potentially provide limitless source of energy.

American military requirements declined in the 1960s, and the government completed its uranium procurement program by the end of 1970. Simultaneously, a new market emerged: commercial nuclear power plants. In the U.S. this market virtually collapsed by the end of the 1970s as a result of industrial strains caused by the energy crisis, popular opposition, and finally the Three Mile Island nuclear accident in 1979, all of which led to a de facto moratorium on the development of new nuclear reactor power stations.

In Europe a mixed situation exists. Considerable nuclear power capacities have been developed, notably in Belgium, Finland, France, Germany, Spain, Sweden, Switzerland, and the UK. In many countries development of nuclear power has been stopped and phased out by legal actions. In Italy the use of nuclear power was barred by a referendum in 1987; this is now under revision.^[61] Ireland in 2008 also had no plans to change its non-nuclear stance.^[62]

The years 1976 and 1977 saw uranium mining become a major political issue in Australia, with the Ranger Inquiry (Fox) report opening up a public debate about uranium mining.^[63] The Movement Against Uranium Mining group was formed in 1976, and many protests and demonstrations against uranium mining were held.^[63]^[64] Concerns relate to the health risks and environmental damage from uranium mining. Notable Australian anti-uranium activists have included Kevin Buzzacott, Jacqui Katona, Yvonne Margarula, and Jillian Marsh.^[65]^[66]^[67]

The World Uranium Hearing was held in Salzburg, Austria in September 1992. Anti-nuclear speakers from all continents, including indigenous speakers and scientists, testified to the health and environmental problems of uranium mining and processing, nuclear power, nuclear weapons, nuclear tests, and radioactive waste disposal.^[68] People who spoke at the 1992 Hearing include: Thomas Banyacya, Katsumi Furitsu, Manuel Pino and Floyd Red Crow Westerman. They highlighted the threat of radioactive contamination to all peoples, especially indigenous communities and said that their survival requires self-determination and emphasis on spiritual and cultural values. Increased renewable energy commercialization was advocated.^[69]

The Kingdom of Saudi Arabia with the help of China has built an extraction facility to obtain uranium yellowcake from uranium ore. According to Western officials with information regarding the extraction site, the process is conducted by the oil-rich kingdom to champion nuclear technology. However, Saudi Energy Minister denied having built a uranium ore facility and claimed that the extraction of minerals is a fundamental part of the kingdom’s strategy to diversify its economy.^[70]

Despite sanctions on Russia some countries still buy its uranium in 2022,^[71] and some argue the EU should stop.^[72] As of 2022^[update] S & P Global say non-Russian miners await more certainty before deciding whether to invest in new mines.^[73]

Health risks

Uranium ore emits radon gas. The health effects of high exposure to radon are a particular problem in the mining of uranium; significant excess lung cancer deaths have been identified in epidemiological studies of uranium miners employed in the 1940s and 1950s.^[74]^[75]^[76]

The first major studies with radon and health occurred in the context of uranium mining, first in the Joachimsthal region of Bohemia and then in the Southwestern United States during the early Cold War. Because radon is a product of the radioactive decay of uranium, underground uranium mines may have high concentrations of radon. Many uranium miners in the Four Corners region contracted lung cancer and other pathologies as a result of high levels of exposure to radon in the mid-1950s. The increased incidence of lung cancer was particularly pronounced among Native American and Mormon miners, because those groups normally have low rates of lung cancer.^[77] This is in part due to the religious prohibition on smoking in Mormonism.^[78]^[79] Safety standards requiring expensive ventilation were not widely implemented or policed during this period.^[80] While radon exposure is the main source of lung cancer in non-smokers who aren't exposed to asbestos, there is evidence that the combination of smoking and radon exposure increases the risk above the combined risks of either harmful substance.^[81]^[82]

In studies of uranium miners, workers exposed to radon levels of 50 to 150 picocuries of radon per liter of air (2000–6000 Bq/m³) for about 10 years have shown an increased frequency of lung cancer.^[83] Statistically significant excesses in lung cancer deaths were present after cumulative exposures of less than 50 WLM.^[83] There is unexplained heterogeneity in these results (whose confidence interval do not always overlap).^[84] The size of the radon-related increase in lung cancer risk varied by more than an order of magnitude between the different studies.^[85]

Since that time, ventilation and other measures have been used to reduce radon levels in most affected mines that continue to operate. In recent years, the average annual exposure of uranium miners has fallen to levels similar to the concentrations inhaled in some homes. This has reduced the risk of occupationally induced cancer from radon, although it still remains an issue both for those who are currently employed in affected mines and for those who have been employed in the past.^[85] The power to detect any excess risks in miners nowadays is likely to be small, exposures being much smaller than in the early years of mining.^[86] Coal mining in addition to other health risks can also expose miners to radon as Uranium (and its decay product radon) are often found in and near coal deposits and can accumulate underground as radon is denser than air.^[87]^[88]

In the USA, the Radiation Exposure Compensation Act provides compensation to sufferers of various health problems linked to radiation exposure, or to their surviving relatives. Uranium miners, uranium mill workers and uranium transport workers have been compensated under the scheme.

United States clean-up efforts

Despite efforts made in cleaning up uranium sites, significant problems stemming from the legacy of uranium development still exist today on the territory of the Navajo Nation and in the states of Utah, Colorado, New Mexico, and Arizona. Hundreds of abandoned mines have not been cleaned up and present environmental and health risks in many communities.^[89] At the request of the U.S. House Committee on Oversight and Government Reform in October 2007, and in consultation with the Navajo Nation, the Environmental Protection Agency (EPA), along with the Bureau of Indian Affairs (BIA), the Nuclear Regulatory Commission (NRC), the Department of Energy (DOE), and the Indian Health Service (IHS), developed a coordinated Five-Year Plan to address uranium contamination.^[90] Similar interagency coordination efforts are beginning in the State of New Mexico as well. In 1978, Congress passed the Uranium Mill Tailings Radiation Control Act (UMTRCA), a measure designed to assist in the cleanup of 22 inactive ore-processing sites throughout the southwest. This also included constructing 19 disposal sites for the tailings, which contain a total of 40 million cubic yards of low-level radioactive material.^[91] The Environmental Protection Agency estimates that there are 4000 mines with documented uranium production, and another 15,000 locations with uranium occurrences in 14 western states,^[92] most found in the Four Corners area and Wyoming.^[93]

The Uranium Mill Tailings Radiation Control Act is a United States environmental law that amended the Atomic Energy Act of 1954 and gave the Environmental Protection Agency the authority to establish health and environmental standards for the stabilization, restoration, and disposal of uranium mill tailings. Title 1 of the Act required the EPA to set environmental protection standards consistent with the Resource Conservation and Recovery Act, including groundwater protection limits; the Department of Energy to implement EPA standards and provide perpetual care for some sites; and the Nuclear Regulatory Commission to review cleanups and license sites to states or the DOE for perpetual care.^[94] Title 1 established a uranium mill remedial action program jointly funded by the federal government and the state.^[95] Title 1 of the Act also designated 22 inactive uranium mill sites for remediation, resulting in the containment of 40 million cubic yards of low-level radioactive material in UMTRCA Title 1 holding cells.^[96]

Demand

The world demand for uranium in 1996 was over 68 kilotonnes (150×10^⁶ lb) per year,^[98] and that number had been expected to increase to between 80 kilotonnes (180×10^⁶ lb) and 100 kilotonnes (220×10^⁶ lb) per year by 2025 due to the number of new nuclear power plants coming on line.^[99] However following the shutdown of many nuclear power plants after the Fukushima Daiichi nuclear disaster in 2011, demand had fallen to about 60 kilotonnes (130×10^⁶ lb) in 2015 and rose to 62.8 kilotonnes (138×10^⁶ lb) in 2017, with future forecasts uncertain.^[100]

According to Cameco Corporation, the demand for uranium is directly linked to the amount of electricity generated by nuclear power plants. Reactor capacity is growing slowly, reactors are being run more productively, with higher capacity factors, and reactor power levels. Improved reactor performance translates into greater uranium consumption.^[101]

Nuclear power stations of 1000 megawatt electrical generation capacity require around 200 tonnes (440×10^³ lb) of natural uranium per year. For example, the United States has 103 operating reactors with an average generation capacity of 950 MWe demanded over 22 kilotonnes (49×10^⁶ lb) of natural uranium in 2005.^[102] As the number of nuclear power plants increase, so does the demand for uranium.

Another factor to consider is population growth. Electricity consumption is determined in part by economic and population growth. According to data from the CIA's World Factbook, the world population currently (July 2020 est.) is more than 7.7 billion and it is increasing by 1.167% per year. This means a growth of about 211,000 persons every day.^[103] According to the UN, by 2050 it is estimated that the Earth's population will be 9.07 billion.^[104] 62% of the people will live in Africa, Southern Asia and Eastern Asia.^[105] The largest energy-consuming class in the history of earth is being produced in world's most populated countries, China and India. Both plan massive nuclear energy expansion programs. China intends to build 32 nuclear plants with 40,000 MWe capacity by 2020.^[106] According to the World Nuclear Association, India plans on bringing 20,000 MWe nuclear capacity on line by 2020, and aims to supply 25% of electricity from nuclear power by 2050.^[107] The World Nuclear Association believes nuclear energy could reduce the fossil fuel burden of generating the new demand for electricity.^[108]

As more fossil fuels are used to supply the growing energy needs of an increasing population, the more greenhouse gases are produced. Some proponents of nuclear power believe that building more nuclear power plants can reduce greenhouse emissions.^[109] For example, the Swedish utility Vattenfall studied the full life cycle emissions of different ways to produce electricity, and concluded that nuclear power produced 3.3 g/kWh of carbon dioxide, compared to 400.0 for natural gas and 700.0 for coal.^[110] Another study however shows this figure to be 84–130 g of CO₂/kWh, with the figure rising dramatically as less concentrated ores are used in the future. It uses a wider scope for consideration than other studies including dismantling and disposal of the power station. The study assumes diesel oil for the thermal parts of the uranium extraction process.^[111]

As some countries are not able to supply their own needs of uranium economically, countries have resorted to importing uranium ore from elsewhere. For example, owners of U.S. nuclear power reactors bought 67 million pounds (30 kt) of natural uranium in 2006. Out of that 84%, or 56 million pounds (25 kt), were imported from foreign suppliers, according to the Energy Department.^[112]

Because of the improvements in gas centrifuge technology in the 2000s, replacing former gaseous diffusion plants, cheaper separative work units have enabled the economic production of more enriched uranium from a given amount of natural uranium, by re-enriching tails ultimately leaving a depleted uranium tail of lower enrichment. This has somewhat lowered the demand for natural uranium.^[100]

As nuclear power plants take a long time to build and refuelling is undertaken at sporadic, predictable intervals, uranium demand is rather predictable in the short term. It is also less dependent on short-term economic boom-bust cycles as nuclear power has one of strongest fixed costs to variable costs ratios (i.e. The marginal costs of running, rather than leaving idle an already constructed power plant are very low, compared to the capital costs of construction) and it is thus nearly never advisable to leave a nuclear power plant idle for economic reasons. However, nuclear policy can lead to short term fluctuations in demand, as evidenced by the German nuclear phaseout, which was decided upon by the government of Gerhard Schröder (1998-2005) reversed during the second Merkel cabinet (2009-2013) only for a reversal of that reversal to occur as a consequence of the Fukushima nuclear accident, which also led to the temporary shutdown of several German nuclear power plants.

Resources

Uranium-235, the fissile isotope of uranium used in nuclear reactors, makes up about 0.7% of uranium from ore. It is the only naturally occurring isotope capable of directly generating nuclear power, and is a finite, non-renewable resource. While Uranium-235 can be "bred" from ²³⁴
U, a natural decay product of ²³⁸
U present at 55 ppm in all natural uranium samples, Uranium-235 is ultimately a finite non-renewable resource.^[113]^[114] Due to the currently low price of uranium, the majority of commercial light water reactors operate on a "once through fuel cycle" which leaves virtually all the energy contained in the original ²³⁸
U - which makes up over 99% of natural uranium - unused. Nuclear reprocessing is a technology currently used at industrial scale in France, Russia and Japan, which can recover part of that energy by producing MOX fuel or Remix Fuel for use in conventional power generating light water reactors. However, at current uranium prices, this is widely deemed uneconomical if only the "input" side is considered.

Advances in breeder reactor technology could allow the current reserves of uranium to provide power for humanity for billions of years, thus making nuclear power a sustainable energy.^[115] However, in 2010 the International Panel on Fissile Materials said "After six decades and the expenditure of the equivalent of tens of billions of dollars, the promise of breeder reactors remains largely unfulfilled and efforts to commercialize them have been steadily cut back in most countries."^[116] But in 2016, the Russian BN-800 fast-neutron breeder reactor started producing commercially at full power (800 MWe), joining the previous BN-600. As of 2020^[update], the Chinese CFR-600 is under construction after the success of the China Experimental Fast Reactor, based on the BN-800. These reactors are currently generating mostly electricity rather than new fuel because the abundance and low price of mined and reprocessed uranium oxide makes breeding uneconomical, but they can switch to breed new fuel and close the cycle as needed.

Some argue that if the nuclear fuel cycle can be closed, uranium could become equivalent to renewable energy sources as concerns its availability.^[117] Breeding and nuclear reprocessing potentially would allow the extraction of the largest amount of energy from natural uranium. However, only a small amount of uranium is currently being bred into plutonium and only a small amount of fissile uranium and plutonium is being recovered from nuclear waste worldwide. Furthermore, the technologies to eliminate the waste in the nuclear fuel cycle do not yet exist.^[118] Since the nuclear fuel cycle is effectively not closed, Hubbert peak theory may be applicable.

The CANDU reactor which was designed to be fueled with natural uranium is capable of using spent fuel from Light Water Reactors as fuel, since it contains more fissile material than natural uranium. Research into "DUPIC" - direct use of PWR spent fuel in CANDU type reactors - is ongoing and could increase the usability of fuel without the need for reprocessing.^[119]

Reserves

Reserves are the most readily available resources. Resources that are known to exist and easy to mine are called "Known conventional resources". Resources that are thought to exist but have not been mined are classified under "Undiscovered conventional resources".^[120]

The known uranium resources represent a higher level of assured resources than is normal for most minerals. Further exploration and higher prices will certainly, on the basis of present geological knowledge, yield further resources as present ones are used up. There was very little uranium exploration between 1985 and 2005, so the significant increase in exploration effort that we are now seeing could readily double the known economic resources. On the basis of analogies with other metal minerals, a doubling of price from price levels in 2007 could be expected to create about a tenfold increase in measured resources, over time.^[121]

Known conventional resources

Known conventional resources are "Reasonably Assured Resources" and "Estimated Additional Resources-I".^[120]

In 2006, about 4 million tons of conventional resources were thought to be sufficient at current consumption rates for about six decades (4.06 million tonnes at 65,000 tonnes per year).^[122] In 2011, this was estimated to be 7 million tonnes. Exploration for uranium has increased. From 1981 to 2007, annual exploration expenditures grew modestly, from 4 million US$ to 7 million US$. This skyrocketed to US$11 million in 2011.^[123] Consumption of uranium runs at around 75 000 t a year. This is less than production, and requires draw down of existing stocks.

About 96% of the global uranium reserves are found in these ten countries: Australia, Canada, Kazakhstan, South Africa, Brazil, Namibia, Uzbekistan, the United States, Niger, and Russia.^[124] The world's largest deposits of uranium are found in three countries. Australia has just over 30% of the world's reasonably assured resources and inferred resources of uranium – about 1.673 megatonnes (3.69×10^⁹ lb).^[125] Kazakhstan has about 12% of the world's reserves, or about 651 kilotonnes (1.4×10^⁹ lb).^[126] And Canada has 485 kilotonnes (1,100×10^⁶ lb) of uranium, representing about 9%.^[125]

Several countries in Europe no longer mine uranium (East Germany (1990), France (2001), Spain (2002) and Sweden (1969)); they were not major producers.^[127]

Undiscovered conventional resources

Undiscovered conventional resources can be broken up into two classifications "Estimated Additional Resources-II" and "Speculative Resources".^[120]

It will take a significant exploration and development effort to locate the remaining deposits and begin mining them. However, since the entire earth's geography has not been explored for uranium at this time, there is still the potential to discover exploitable resources.^[128] The OECD Redbook cites areas still open to exploration throughout the world. Many countries are conducting complete aeromagnetic gradiometer radiometric surveys to get an estimate the size of their undiscovered mineral resources. Combined with a gamma-ray survey, these methods can locate undiscovered uranium and thorium deposits.^[129] The U.S. Department of Energy conducted the first and only national uranium assessment in 1980 – the National Uranium Resource Evaluation (NURE) program.^[130]

Secondary resources

Secondary resources are essentially recovered uranium from other sources such as nuclear weapons, inventories, reprocessing and re-enrichment. Since secondary resources have exceedingly low discovery costs and very low production costs, they may have displaced a significant portion of primary production. Secondary uranium was and is available essentially instantly. However, new primary production will not be. Essentially, secondary supply is a "one-time" finite supply, with the exception of the re-processed fuel.^[131]

Uranium mining activity is cyclical, in 2009 80% of the requirements of power utilities were supplied by mines, in 2017 this had risen to 93%.^[132]^[133] The balance comes from inventories held by utilities and other fuel cycle companies, inventories held by governments, used reactor fuel that has been reprocessed, recycled materials from military nuclear programs and uranium in depleted uranium stockpiles.^[134]

The plutonium from dismantled cold war nuclear weapon stockpiles was a major source of nuclear fuel under the "Megatons to Megawatts" program which ended in December 2013. The industry developed new uranium mines, especially in Kazakhstan which now attributes to 31% of the world supply.^[132]^[133]

Inventories

Inventories are kept by a variety of organizations – government, commercial and others.^[135]^[136]

The US DOE keeps inventories for security of supply in order to cover for emergencies where uranium is not available at any price.^[137]

Decommissioning nuclear weapons

Both the US and Russia have committed to recycle their nuclear weapons into fuel for electricity production. This program is known as the Megatons to Megawatts Program.^[138] Down blending 500 tonnes (1,100×10^³ lb) of Russian weapons high enriched uranium (HEU) will result in about 15 kilotonnes (33,000×10^³ lb) of low enriched uranium (LEU) over 20 years. This is equivalent to about 152 kilotonnes (340×10^⁶ lb) of natural U, or just over twice annual world demand. Since 2000, 30 tonnes (66×10^³ lb) of military HEU is displacing about 10.6 kilotonnes (23×10^⁶ lb) of uranium oxide mine production per year which represents some 13% of world reactor requirements.^[139]

Plutonium recovered from nuclear weapons or other sources can be blended with uranium fuel to produce a mixed-oxide fuel. In June 2000, the US and Russia agreed to dispose of 34 kilotonnes (75×10^⁶ lb) each of weapons-grade plutonium by 2014. The US undertook to pursue a self-funded dual track program (immobilization and MOX). The G-7 nations provided US$1 billion to set up Russia's program. The latter was initially MOX specifically designed for VVER reactors, the Russian version of the Pressurized Water Reactor (PWR), the high cost being because this was not part of Russia's fuel cycle policy. This MOX fuel for both countries is equivalent to about 12 kilotonnes (26×10^⁶ lb) of natural uranium.^[140] The U.S. also has commitments to dispose of 151 tonnes (330×10^³ lb) of non-waste HEU.^[141]

The Megatons to Megawatts program came to an end in 2013.^[138]^{[failed verification]}

Reprocessing and recycling

Nuclear reprocessing, sometimes called recycling, is one method of mitigating the eventual peak of uranium production. It is most useful as part of a nuclear fuel cycle utilizing fast-neutron reactors since reprocessed uranium and reactor-grade plutonium both have isotopic compositions not optimal for use in today's thermal-neutron reactors. Although reprocessing of nuclear fuel is done in a few countries (France, United Kingdom, and Japan) the United States President banned reprocessing in the late 1970s due to the high costs and the risk of nuclear proliferation via plutonium. In 2005, U.S. legislators proposed a program to reprocess the spent fuel that has accumulated at power plants. At present prices, such a program is significantly more expensive than disposing spent fuel and mining fresh uranium.^[142]

Currently, there are eleven reprocessing plants in the world. Of these, two are large-scale commercially operated plants for the reprocessing of spent fuel elements from light water reactors with throughputs of more than 1 kilotonne (2.2×10^⁶ lb) of uranium per year. These are La Hague, France with a capacity of 1.6 kilotonnes (3.5×10^⁶ lb) per year and Sellafield, England at 1.2 kilotonnes (2.6×10^⁶ lb) uranium per year. The rest are small experimental plants.^[143] The two large-scale commercial reprocessing plants together can reprocess 2,800 tonnes of uranium waste annually.^[144]

Most of the spent fuel components can be recovered and recycled. About two-thirds of the U.S. spent fuel inventory is uranium. This includes residual fissile uranium-235 that can be recycled directly as fuel for heavy water reactors or enriched again for use as fuel in light water reactors.^[145]

Plutonium and uranium can be chemically separated from spent fuel. When used nuclear fuel is reprocessed using the de facto standard PUREX method, both plutonium and uranium are recovered separately. The spent fuel contains about 1% plutonium. Reactor-grade plutonium contains Pu-240 which has a high rate of spontaneous fission, making it an undesirable contaminant in producing safe nuclear weapons. Nevertheless, nuclear weapons can be made with reactor grade plutonium.^[146]

The spent fuel is primarily composed of uranium, most of which has not been consumed or transmuted in the nuclear reactor. At a typical concentration of around 96% by mass in the used nuclear fuel, uranium is the largest component of used nuclear fuel.^[147] The composition of reprocessed uranium depends on the time the fuel has been in the reactor, but it is mostly uranium-238, with about 1% uranium-235, 1% uranium-236 and smaller amounts of other isotopes including uranium-232. However, reprocessed uranium is also a waste product because it is contaminated and undesirable for reuse in reactors.^[148] During its irradiation in a reactor, uranium is profoundly modified. The uranium that leaves the reprocessing plant contains all the isotopes of uranium between uranium-232 and uranium-238 except uranium-237, which is rapidly transformed into neptunium-237. The undesirable isotopic contaminants are:

Uranium-232 (whose decay products emit strong gamma radiation making handling more difficult), and
Uranium-234 (which is fertile material but can affect reactivity differently from uranium-238).
Uranium-236 (which affects reactivity and absorbs neutrons without fissioning, becoming neptunium-237 which is one of the most difficult isotopes for long-term disposal in a deep geological repository)
Daughter products of uranium-232: bismuth-212, thallium-208.^[149]

At present, reprocessing and the use of plutonium as reactor fuel is far more expensive than using uranium fuel and disposing of the spent fuel directly – even if the fuel is only reprocessed once.^[148]

The main problems with uranium reprocessing are the cost of mined uranium compared to the cost of reprocessing,^[142]^[150] nuclear proliferation risks, the risk of major policy change, the risk of incurring large cleanup costs, stringent regulations for reprocessing plants, and the anti-nuclear movement ^{[citation needed]}.

Unconventional resources

Unconventional resources are occurrences that require novel technologies for their exploitation and/or use. Often unconventional resources occur in low-concentration. The exploitation of unconventional uranium requires additional research and development efforts for which there is no imminent economic need, given the large conventional resource base and the option of reprocessing spent fuel.^[151] Phosphates, seawater, uraniferous coal ash, and some type of oil shales are examples of unconventional uranium resources.

Phosphates

The soaring price of uranium may cause long-dormant operations to extract uranium from phosphate. Uranium occurs at concentrations of 50 to 200 parts per million in phosphate-laden earth or phosphate rock. As uranium prices increase, there has been interest in some countries in extraction of uranium from phosphate rock, which is normally used as the basis of phosphate fertilizers.^[152]

Worldwide, approximately 400 wet-process phosphoric acid plants were in operation. Assuming an average recoverable content of 100 ppm of uranium, and that uranium prices do not increase so that the main use of the phosphates are for fertilizers, this scenario would result in a maximum theoretical annual output of 3.7 kilotonnes (8.2×10^⁶ lb) U₃O₈.^[153]

Historical operating costs for the uranium recovery from phosphoric acid range from $48–$119/kg U₃O₈.^[154] In 2011, the average price paid for U₃O₈ in the United States was $122.66/kg.^[155]

There are 22 million tons of uranium in phosphate deposits. Recovery of uranium from phosphates is a mature technology;^[151] it has been utilized in Belgium and the United States, but high recovery costs limit the utilization of these resources, with estimated production costs in the range of US$60–100/kgU including capital investment, according to a 2003 OECD report for a new 100 tU/year project.^[156]

Seawater

Unconventional uranium resources include up to 4,000 megatonnes (8,800×10^⁹ lb) of uranium contained in sea water. Several technologies to extract uranium from sea water have been demonstrated at the laboratory scale.

In the mid-1990s extraction costs were estimated at 260 USD/kgU (Nobukawa, et al., 1994) but scaling up laboratory-level production to thousands of tonnes is unproven and may encounter unforeseen difficulties.^[157]

According to the OECD, uranium may be extracted from seawater using this method for about US$300/kgU.^[156]

In 2006 the same research group stated: "If 2g-U/kg-adsorbent is submerged for 60 days at a time and used 6 times, the uranium cost is calculated to be 88,000 JPY/kgU, including the cost of adsorbent production, uranium collection, and uranium purification. When an extraction 6g of U per kg of adsorbent and 20 repetitions or more becomes possible, the uranium cost reduces to 15,000 yen. This price level is equivalent to that of the highest cost of the minable uranium. The lowest cost attainable now is 25,000 yen with 4g-U/kg-adsorbent used in the sea area of Okinawa, with 18 repetition uses. In this case, the initial investment to collect the uranium from seawater is 107.7 billion yen, which is 1/3 of the construction cost of a one gigawatt nuclear power plant."^[158]

In 2012, ORNL researchers announced the successful development of a new absorbent material dubbed HiCap, which vastly outperforms previous best adsorbents, which perform surface retention of solid or gas molecules, atoms or ions. "We have shown that our adsorbents can extract five to seven times more uranium at uptake rates seven times faster than the world's best adsorbents", said Chris Janke, one of the inventors and a member of ORNL's Materials Science and Technology Division. HiCap also effectively removes toxic metals from water, according to results verified by researchers at Pacific Northwest National Laboratory.^[159]^[160]^[161]^[162]^[163]

Among the other methods to recover uranium from sea water, two seem promising: algae bloom to concentrate uranium^[164] and nanomembrane filtering.^[165]

So far, no more than a very small amount of uranium has been recovered from sea water in a laboratory.^[151]

Uraniferous coal ash

In particular, nuclear power facilities produce about 200,000 metric tons of low and intermediate level waste (LILW) and 10,000 metric tons of high level waste (HLW) (including spent fuel designated as waste) each year worldwide.^[168]

Although only several parts per million average concentration in coal before combustion (albeit more concentrated in ash), the theoretical maximum energy potential of trace uranium and thorium in coal (in breeder reactors) actually exceeds the energy released by burning the coal itself, according to a study by Oak Ridge National Laboratory.^[167]

From 1965 to 1967 Union Carbide operated a mill in North Dakota, United States burning uraniferous lignite and extracting uranium from the ash. The plant produced about 150 metric tons of U₃O₈ before shutting down.^[169]

An international consortium has set out to explore the commercial extraction of uranium from uraniferous coal ash from coal power stations located in Yunnan province, China.^[151] The first laboratory scale amount of yellowcake uranium recovered from uraniferous coal ash was announced in 2007.^[170] The three coal power stations at Xiaolongtang, Dalongtang and Kaiyuan have piled up their waste ash. Initial tests from the Xiaolongtang ash pile indicate that the material contains (160–180 parts per million uranium), suggesting a total of some 2.085 kilotonnes (4.60×10^⁶ lb) U₃O₈ could be recovered from that ash pile alone.^[170]

Oil shales

Some oil shales contain uranium, which may be recovered as a byproduct. Between 1946 and 1952, a marine type of Dictyonema shale was used for uranium production in Sillamäe, Estonia, and between 1950 and 1989 alum shale was used in Sweden for the same purpose.^[171]

Breeding

A breeder reactor produces more nuclear fuel than it consumes and thus can extend the uranium supply. It typically turns the dominant isotope in natural uranium, uranium-238, into fissile plutonium-239. This results in hundredfold increase in the amount of energy to be produced per mass unit of uranium, because U-238, which constitute 99.3% of natural uranium, is not used in conventional reactors which instead use U-235 which only represent 0.7% of natural uranium.^[172] In 1983, physicist Bernard Cohen proposed that the world supply of uranium is effectively inexhaustible, and could therefore be considered a form of renewable energy.^[117]^[173] He claims that fast breeder reactors, fueled by naturally-replenished uranium-238 extracted from seawater, could supply energy at least as long as the sun's expected remaining lifespan of five billion years.,^[117] making them as sustainable in fuel availability terms as renewable energy sources. Despite this hypothesis there is no known economically viable method to extract sufficient quantities from sea water. Experimental techniques are under investigation.^[174]^[175]

There are two types of breeders: Fast breeders and thermal breeders.

Fast breeder

A fast breeder, in addition to consuming U-235, converts fertile U-238 into Pu-239, a fissile fuel. Fast breeder reactors are more expensive to build and operate, including the reprocessing, and could only be justified economically if uranium prices were to rise to pre-1980 values in real terms. Over 300 reactor-years of operating experience have been accumulated. In addition to considerably extending the exploitable fuel supply, these reactors have an advantage in that they produce less long-lived transuranic wastes, and can consume nuclear waste from current light water reactors, generating energy in the process.^[176] Several countries have research and development programs for improving these reactors. For instance, one scenario in France is for half of the present nuclear capacity to be replaced by fast breeder reactors by 2050. China, India, and Japan plan large scale utilization of breeder reactors during the coming decades.^[177] (Following the crisis at Japan's Fukishima Daiichi nuclear power plant in 2011, Japan is revising its plans regarding future use of nuclear power. (See: Fukushima Daiichi nuclear disaster: Energy policy implications.))

Uranium turned out to be far more plentiful than anticipated, and the price of uranium declined rapidly (with an upward blip in the 1970s). This is why the US halted their use in 1977^[178] and the UK abandoned the idea in 1994.^[179]

Fast Breeder Reactors, are called fast because they have no moderator slowing down the neutrons (light water, heavy water or graphite) and breed more fuel than they consume. The word 'fast' in fast breeder thus refers to the speed of the neutrons in the reactor's core. The higher the energy the neutrons have, the higher the breeding ratio or the more uranium that is changed into plutonium.

Significant technical and materials problems were encountered with FBRs, and geological exploration showed that scarcity of uranium was not going to be a concern for some time. By the 1980s, due to both factors, it was clear that FBRs would not be commercially competitive with existing light water reactors. The economics of FBRs still depend on the value of the plutonium fuel which is bred, relative to the cost of fresh uranium.^[180] Research continues in several countries with working prototypes Phénix in France, the BN-600 reactor in Russia, and the Monju in Japan.^[181]

On February 16, 2006, the United States, France and Japan signed an arrangement to research and develop sodium-cooled fast breeder reactors in support of the Global Nuclear Energy Partnership.^[182] Breeder reactors are also being studied under the Generation IV reactor program.

Early prototypes have been plagued with problems. The liquid sodium coolant is highly flammable, bursting into flames if it comes into contact with air and exploding if it comes into contact with water. Japan's fast breeder Monju Nuclear Power Plant has been scheduled to re-open in 2008, 13 years after a serious accident and fire involving a sodium leak. In 1997 France shut down its Superphenix reactor, while the Phenix, built earlier, closed as scheduled in 2009.^[183]^[184]

At higher uranium prices breeder reactors may be economically justified. Many nations have ongoing breeder research programs. China, India, and Japan plan large scale utilization of breeder reactors during the coming decades. 300 reactor-years experience has been gained in operating them.^[177]

As of June 2008 there are only two running commercial breeders and the rate of reactor-grade plutonium production is very small (20 tonnes/yr). The reactor grade plutonium is being processed into MOX fuel. Next to the rate at which uranium is being mined (46,403 tonnes/yr), this is not enough to stave off peak uranium; however, this is only because mined and reprocessed uranium oxide is plentiful and cheap, so breeding new fuel is uneconomical. They can switch to breed large amounts of new fuel as needed, and many more breeding reactors can be built in a short time span.

Thermal breeder

Thorium is an alternate fuel cycle to uranium. Thorium is three times more plentiful than uranium. Thorium-232 is in itself not fissile, but fertile. It can be made into fissile uranium-233 in a breeder reactor. In turn, the uranium-233 can be fissioned, with the advantage that smaller amounts of transuranics are produced by neutron capture, compared to uranium-235 and especially compared to plutonium-239.

Despite the thorium fuel cycle having a number of attractive features, development on a large scale can run into difficulties:^[185]

The resulting U-233 fuel is expensive to fabricate.
The U-233 chemically separated from the irradiated thorium fuel is highly radioactive.
Separated U-233 is always contaminated with traces of U-232
Thorium is difficult to recycle due to highly radioactive Th-228
If the U-233 can be separated on its own, it becomes a weapons proliferation risk
And, there are technical problems in reprocessing.

Advocates for liquid core and molten salt reactors such as LFTR claim that these technologies negate the above-mentioned thorium's disadvantages present in solid fueled reactors.

The first successful commercial reactor at the Indian Point power station in Buchanan, New York (Indian Point Unit 1) ran on Thorium. The first core did not live up to expectations.^[186]

Indian interest in thorium is motivated by their substantial reserves. Almost a third of the world's thorium reserves are in India.^[187] India's Department of Atomic Energy (DAE) says that it will construct a 500 MWe prototype reactor in Kalpakkam. There are plans for four breeder reactors of 500 MWe each - two in Kalpakkam and two more in a yet undecided location.^[188]

China has initiated a research and development project in thorium molten-salt breeder reactor technology.^[189] It was formally announced at the Chinese Academy of Sciences (CAS) annual conference in January 2011. Its ultimate target is to investigate and develop a thorium based molten salt breeder nuclear system in about 20 years.^[190]^[191]^[192] A 5 MWe research MSR is apparently under construction at Shanghai Institute of Applied Physics (under the academy) with 2015 target operation.^[193]

Peak uranium

Peak uranium is the point in time that the maximum global uranium production rate is reached.

Pessimistic predictions of future high-grade uranium production operate on the thesis that either the peak has already occurred in the 1980s or that a second peak may occur sometime around 2035.

As of 2017^[update], identified uranium reserves recoverable at US$130/kg were 6.14 million tons (compared to 5.72 million tons in 2015). At the rate of consumption in 2017, these reserves are sufficient for slightly over 130 years of supply. The identified reserves as of 2017 recoverable at US$260/kg are 7.99 million tons (compared to 7.64 million tons in 2015).^[133]

Optimistic predictions of nuclear fuel supply are based upon one of three possible scenarios.

LWRs only consume about half of one percent of their uranium fuel while fast breeder reactors will consume closer to 99%. Currently, more than 80% of the World's reactors are Light Water Reactors (LWRs).
Current reserves of uranium are about 5.3 million tons. Theoretically, 4.5 billion tons of uranium are available from sea water at about 10 times the current price of uranium.^[194] Currently no high volume seawater extraction systems exist. The Earth's crust contains approximately 65 trillion tons of uranium, of which about 32 thousand tons flow into oceans per year via rivers, which are themselves fed via geological cycles of erosion, subduction and uplift.^[115]
Thorium (3–4 times as abundant as uranium) might be used when supplies of uranium are depleted. However, in 2010, the UK's National Nuclear Laboratory (NNL) concluded that for the short to medium term, "...the thorium fuel cycle does not currently have a role to play," in that it is "technically immature, and would require a significant financial investment and risk without clear benefits," and concluded that the benefits have been "overstated."^[195] Currently there are no commercially practical thorium reactors in operation.

If these predictions became reality, it would have the potential to increase the supply of nuclear fuel significantly.

Optimistic predictions claim that the supply is far more than demand and do not predict peak uranium.

Thirteen countries have hit peak and exhausted their economically recoverable uranium resources at current prices.^[196]^[127]

In a similar manner to every other natural metal resource, for every tenfold increase in the cost per kilogram of uranium, there is a three-hundredfold increase in available lower quality ores that would then become economical.^[197] The theory could be observed in practice during the Uranium bubble of 2007 when an unprecedented price hike led to investments in the development of uranium mining of lower quality deposits which mostly became stranded assets after uranium prices returned to a lower level.

Hubbert's peak and uranium

M. King Hubbert created his peak theory in 1956 for a variety of finite resources such as coal, oil, and natural gas.^[198] Hubbert saw oil as a resource which would soon run out, but he believed that uranium had much more promise as an energy source,^[198] and that breeder reactors and nuclear reprocessing, which were new technologies at the time, would allow uranium to be a power source for a very long time. The technologies Hubbert envisioned would substantially reduce the rate of depletion of uranium-235, but they are still more costly than the "once-through" cycle, and have not been widely deployed to date.^[142] If these and other more costly technologies such as seawater extraction are used, any possible peak would occur in the very distant future.

Uranium supply

Uranium occurs naturally in many rocks, and even in seawater. However, like other metals, it is seldom sufficiently concentrated to be economically recoverable.^[125] Like any resource, uranium cannot be mined at any desired concentration. No matter the technology, at some point it is too costly to mine lower grade ores. One highly criticized^[199] life cycle study by Jan Willem Storm van Leeuwen suggested that below 0.01–0.02% (100–200 ppm) in ore, the energy required to extract and process the ore to supply the fuel, operate reactors and dispose properly comes close to the energy gained by using the uranium as a fissible material in the reactor.^[200] Researchers at the Paul Scherrer Institute who analyzed the Jan Willem Storm van Leeuwen paper however have detailed the number of incorrect assumptions of Jan Willem Storm van Leeuwen that led them to this evaluation, including their assumption that all the energy used in the mining of Olympic Dam is energy used in the mining of uranium, when that mine is predominantly a copper mine and uranium is produced only as a co-product, along with gold and other metals.^[199] The report by Jan Willem Storm van Leeuwen also assumes that all enrichment is done in the older and more energy intensive gaseous diffusion technology, however the less energy intensive gas centrifuge technology has produced the majority of the world's enriched uranium now for a number of decades.

An appraisal of nuclear power by a team at MIT in 2003, and updated in 2009, have stated that:^[201]

Most commentators conclude that a half century of unimpeded growth is possible, especially since resources costing several hundred dollars per kilogram (not estimated in the Red Book) would also be economically usable...We believe that the world-wide supply of uranium ore is sufficient to fuel the deployment of 1000 reactors over the next half century.

In the early days of the nuclear industry, uranium was thought to be very scarce, so a closed fuel cycle would be needed. Fast breeder reactors would be needed to create nuclear fuel for other power producing reactors. In the 1960s, new discoveries of reserves, and new uranium enrichment techniques allayed these concerns.^[123]

Mining companies usually consider concentrations greater than 0.075% (750 ppm) as ore, or rock economical to mine at current uranium market prices.^[202] There is around 40 trillion tons of uranium in Earth's crust, but most is distributed at low parts per million trace concentration over its 3 * 10¹⁹ ton mass.^[203]^[204] Estimates of the amount concentrated into ores affordable to extract for under $130 per kg can be less than a millionth of that total.^[196]

**Uranium Grades**^[205]
Source	Concentration
Very high-grade ore – 20% U	200,000 ppm U
High-grade ore – 2% U	20,000 ppm U
Low-grade ore – 0.1% U	1,000 ppm U
Very low-grade ore – 0.01% U	100 ppm U
Granite	4–5 ppm U
Sedimentary rock	2 ppm U
Earth's continental crust (av)	2.8 ppm U
Seawater	0.003 ppm U

According to the OECD Redbook, the world consumed 62.8 kilotonnes (138×10^⁶ lb) of uranium in 2017^[133] (compared to 67 kt in 2002). Of that, 59 kt was produced from primary sources,^[132] with the balance coming from secondary sources, in particular stockpiles of natural and enriched uranium, decommissioned nuclear weapons, the reprocessing of natural and enriched uranium and the re-enrichment of depleted uranium tails.^[156]

Economically extractable reserves of uranium (0.01% ore or better)^[197]
Ore concentration	tonnes of uranium	Ore type
>1%	10000	vein deposits
0.2–1%	2 million	pegmatites,unconformity deposits
0.1–0.2%	80 million	fossil placers, sandstones
0.02–0.1%	100 million	lower grade fossil placers, sandstones
100–200 ppm	2 billion	volcanic deposits

The table above assumes the fuel will be used in a LWR burner. Uranium becomes far more economical when used in a fast burner reactor such as the Integral Fast Reactor.

Production

According to Robert Vance of the OECD's Nuclear Energy Agency, the world production rate of uranium has already reached its peak in 1980, amounting to 69,683 tonnes (150×10^⁶ lb) of U₃O₈ from 22 countries. However, this is not due to lack of production capacity. Historically, uranium mines and mills around the world have operated at about 76% of total production capacity, varying within a range of 57% and 89%. The low production rates have been largely attributable to excess capacity. Slower growth of nuclear power and competition from secondary supply significantly reduced demand for freshly mined uranium until very recently. Secondary supplies include military and commercial inventories, enriched uranium tails, reprocessed uranium and mixed oxide fuel.^[207]

According to data from the International Atomic Energy Agency, world production of mined uranium has peaked twice in the past: once, circa 1960 in response to stockpiling for military use, and again in 1980, in response to stockpiling for use in commercial nuclear power. Up until about 1990, the mined uranium production was in excess of consumption by power plants. But since 1990, consumption by power plants has outstripped the uranium being mined; the deficit being made up by liquidation of the military (through decommissioning of nuclear weapons) and civilian stockpiles. Uranium mining has increased since the mid-1990s, but is still less than the consumption by power plants.^[208]

The world's top uranium producers are Kazakhstan (39% of world production), Canada (22%) and Australia (10%). Other major producers include Namibia (6.7%), Niger (6%), and Russia (5%).^[133] In 1996, the world produced 39 kilotonnes (86×10^⁶ lb) of uranium.^[209] In 2005, the world primary mining production was 41,720 tonnes (92×10^⁶ lb) of uranium,^[206] 62% of the requirements of the power utilities. In 2017 the production had increased to 59,462 tonnes, 93% of the demand.^[132] The balance comes from inventories held by utilities and other fuel cycle companies, inventories held by governments, used reactor fuel that has been reprocessed, recycled materials from military nuclear programs and uranium in depleted uranium stockpiles.^[210] The plutonium from dismantled Cold War nuclear weapon stockpiles will be exhausted by 2013. The industry is trying to find and develop new uranium mines, mainly in Canada, Australia and Kazakhstan. Those under development in 2006 would fill half the gap.^[211]

Of the ten largest uranium mines in the world (Mc Arthur River, Ranger, Rossing, Kraznokamensk, Olympic Dam, Rabbit Lake, Akouta, Arlit, Beverly, and McClean Lake), by 2020, six will be depleted, two will be in their final stages, one will be upgrading and one will be producing.^[212]

World primary mining production fell 5% in 2006 over that in 2005. The biggest producers, Canada and Australia saw falls of 15% and 20%, with only Kazakhstan showing an increase of 21%.^[213] This can be explained by two major events that have slowed world uranium production. Canada's Cameco mine at Cigar Lake is the largest, highest-grade uranium mine in the world. In 2006 it flooded, and then flooded again in 2008 (after Cameco had spent $43 million – most of the money set aside – to correct the problem), causing Cameco to push back its earliest start-up date for Cigar Lake to 2011.^[214] Also, in March 2007, the market endured another blow when a cyclone struck the Ranger mine in Australia, which produces 5,500 tonnes (12×10^⁶ lb) of uranium a year. The mine's owner, Energy Resources of Australia, declared force majeure on deliveries and said production would be impacted into the second half of 2007.^[215] This caused some to speculate that peak uranium has arrived.^[216] In January 2018, McArthur River mine in Canada suspended production, the mine was producing 7000-8000 tonnes of Uranium per year from 2007 to 2017. The mine's owner, Cameco cited low uranium market prices as the reason to halt production and claims ramping production up to normal will take 18–24 months when the decision to re-open the mine is made.^[217]

Primary sources

About 96% of the global uranium reserves are found in these ten countries: Australia, Canada, Kazakhstan, South Africa, Brazil, Namibia, Uzbekistan, the United States, Niger, and Russia.^[124] Out of those the main producers are Kazakhstan (39% of world production), Canada (22%) and Australia (10%) are the major producers.^[133] In 1996, the world produced 39,000 tonnes of uranium,^[218] and in 2005, the world produced a peak of 41,720 tonnes of uranium,^[206]. In 2017 this had increased to 59,462 tonnes, 93% of the world demand.

Various agencies have tried to estimate how long these primary resources will last, assuming a once-through cycle. The European Commission said in 2001 that at the current level of uranium consumption, known uranium resources would last 42 years. When added to military and secondary sources, the resources could be stretched to 72 years. Yet this rate of usage assumes that nuclear power continues to provide only a fraction of the world's energy supply. If electric capacity were increased six-fold, then the 72-year supply would last just 12 years.^[219] The world's present measured resources of uranium, economically recoverable at a price of US$130/kg according to the industry groups Organisation for Economic Co-operation and Development (OECD), Nuclear Energy Agency (NEA) and International Atomic Energy Agency (IAEA), are enough to last for "at least a century" at current consumption rates.^[220]^[221] According to the World Nuclear Association, yet another industry group, assuming the world's current rate of consumption at 66,500 tonnes of uranium per year and the world's present measured resources of uranium (4.7–5.5 Mt)^[220] are enough to last for some 70–80 years.^[126]

Supply-demand gap

Due to reduction in nuclear weapons stockpiles, a large amount of former weapons uranium was released for use in civilian nuclear reactors. As a result, starting in 1990, a significant portion of uranium nuclear power requirements were supplied by former weapons uranium, rather than newly mined uranium. In 2002, mined uranium supplied only 54 percent of nuclear power requirements.^[222] But as the supply of former weapons uranium has been used up, mining has increased, so that in 2012, mining provided 95 percent of reactor requirements, and the OCED Nuclear Energy Agency and the International Atomic Energy Agency projected that the gap in supply would be completely erased in 2013.^[221]^[223]

For individual nations

Eleven countries, Germany, the Czech Republic, France, DR Congo, Gabon, Bulgaria, Tajikistan, Hungary, Romania, Spain, Portugal and Argentina, have seen uranium production peak, and rely on imports for their nuclear programs.^[196]^[127] Other countries have reached their peak production of uranium and are currently on a decline.

Germany – Between 1946 and 1990, SDAG Wismut, the former East German uranium mining company, produced a total of around 220 kilotonnes (490×10^⁶ lb) of uranium. During its peak, production exceeded 7 kilotonnes (15×10^⁶ lb) per year. In 1990, uranium mining was discontinued as a consequence of the German unification.^[196] The company could not compete on the world market. The production cost of its uranium was three times the world market price.^[224] West Germany remained a net uranium importer throughout its existence but ran a small scale uranium mine at Menzenschwand in the Black Forest called Krunkelbach Pit which was closed at the end of the Cold War

India – having already hit its production peak, India is finding itself in making a tough choice between using its modest and dwindling uranium resources as a source to keep its weapons programs rolling or it can use them to produce electricity.^[225] Since India has abundant thorium reserves, it is switching to nuclear reactors powered by the thorium fuel cycle.

Sweden – Sweden started uranium production in 1965 but was never profitable. They stopped mining uranium in 1969.^[226] Sweden then embarked on a massive project based on American light water reactors. Nowadays, Sweden imports its uranium mostly from Canada, Australia and the former Soviet Union.

UK – 1981: The UK's uranium production peaked in 1981 and the supply is running out. Yet the UK still plans to build more nuclear power plants.^[211]
France – 1988: In France uranium production attained a peak of 3,394 tonnes (7.5×10^⁶ lb) in 1988. At the time, this was enough for France to meet the half of its reactor demand from domestic sources.^[227] By 1997, production was 1/5 of the 1991 levels. France markedly reduced its market share since 1997.^[228] In 2002, France ran out of uranium.^[229]

U.S. – 1980: The United States was the world's leading producer of uranium from 1953 until 1980, when annual US production peaked at 16,810 tonnes (37×10^⁶ lb) (U₃O₈) according to the OECD redbook.^[230] According to the CRB yearbook, US production the peak was at 19,822 tonnes (44×10^⁶ lb).^[231] The U.S. production hit another maximum in 1996 at 6.3 million pounds (2.9 kt) of uranium oxide (U₃O₈), then dipped in production for a few years.^[232]

**Uranium mining production in the United States**^[233]
Year	1993	1994	1995	1996	1997	1998	1999	2000	2001	2002	2003	2004	2005	2006	2007	2008	2009
U₃O₈ (Mil lb)	3.1	3.4	6.0	6.3	5.6	4.7	4.6	4.0	2.6	2.3	2.0	2.3	2.7	4.1	4.5	3.9	4.1
U₃O₈ (tonnes)	1,410	1,540	2,700	2,860	2,540	2,130	2,090	1,800	1,180	1,040	910	1,040	1,220	1,860	2,040	1,770	1,860

Canada – 1959, 2001?: The first phase of Canadian uranium production peaked at more than 12 kilotonnes (26×10^⁶ lb) in 1959.^[234] The 1970s saw renewed interest in exploration and resulted in major discoveries in northern Saskatchewan's Athabasca Basin. Production peaked its uranium production a second time at 12,522 tonnes (28×10^⁶ lb) in 2001. Experts believe that it will take more than ten years to open new mines.^[219]

World peak uranium

Historical opinions of world uranium supply limits

In 1943, Alvin M. Weinberg et al. believed that there were serious limitations on nuclear energy if only U-235 were used as a nuclear power plant fuel.^[235] They concluded that breeding was required to usher in the age of nearly endless energy.

In 1956, M. King Hubbert declared world fissionable reserves adequate for at least the next few centuries, assuming breeding and reprocessing would be developed into economical processes.^[198]

In 1975 the US Department of the Interior, Geological Survey, distributed the press release "Known US Uranium Reserves Won't Meet Demand". It was recommended that the US not depend on foreign imports of uranium.^[235]

Pessimistic predictions

All the following sources predict peak uranium:

Edward Steidle, Dean of the School of Mineral Industries at Pennsylvania State College, predicted in 1952 that supplies of fissionable elements were too small to support commercial-scale energy production.^[237]
1980 Robert Vance^[238] while looking back at 40 years of uranium production through all of the Red Books, found that peak global production was achieved in 1980 at 69,683 tonnes (150×10^⁶ lb) from 22 countries.^[207] In 2003, uranium production totaled 35,600 tonnes (78×10^⁶ lb) from 19 countries.

1981 Michael Meacher, the former environment minister of the UK 1997–2003, and UK Member of Parliament, reports that peak uranium happened in 1981. He also predicts a major shortage of uranium sooner than 2013 accompanied with hoarding and its value pushed up to the levels of precious metals.^[239]

1989–2015 M. C. Day projected that uranium reserves could run out as soon as 1989, but, more optimistically, would be exhausted by 2015.^[236]
2034 Jan Willem Storm van Leeuwen, an independent analyst with Ceedata Consulting, contends that supplies of the high-grade uranium ore required to fuel nuclear power generation will, at current levels of consumption, last to about 2034.^[240] Afterwards, the cost of energy to extract the uranium will exceed the price the electric power provided.

2035 The Energy Watch Group has calculated that, even with steep uranium prices, uranium production will have reached its peak by 2035 and that it will only be possible to satisfy the fuel demand of nuclear plants until then.^[241]

Various agencies have tried to estimate how long these resources will last.

The European Commission said in 2001 that at the current level of uranium consumption, known uranium resources would last 42 years. When added to military and secondary sources, the resources could be stretched to 72 years. Yet this rate of usage assumes that nuclear power continues to provide only a fraction of the world's energy supply. If electric capacity were increased six-fold, then the 72-year supply would last just 12 years.^[219]

OECD: The world's present measured resources of uranium, economically recoverable at a price of US$130/kg according to the industry groups OECD, NEA and IAEA, are enough to last for 100 years at current consumption.^[221]
According to the Australian Uranium Association, yet another industry group, assuming the world's current rate of consumption at 66,500 tonnes of uranium per year and the world's present measured resources of uranium (4.7 Mt) are enough to last for 70 years.^[126]

Optimistic predictions

All the following references claim that the supply is far more than demand. Therefore, they do not predict peak uranium.

In his 1956 landmark paper, M. King Hubbert wrote "There is promise, however, provided mankind can solve its international problems and not destroy itself with nuclear weapons, and provided world population (which is now expanding at such a rate as to double in less than a century) can somehow be brought under control, that we may at last have found an energy supply adequate for our needs for at least the next few centuries of the 'foreseeable future.'"^[198] Hubbert's study assumed that breeder reactors would replace light water reactors and that uranium would be bred into plutonium (and possibly thorium would be bred into uranium). He also assumed that economic means of reprocessing would be discovered. For political, economic and nuclear proliferation reasons, the plutonium economy never materialized. Without it, uranium is used up in a once-through process and will peak and run out much sooner.^[242]^{[unreliable source?]} However, at present, it is generally found to be cheaper to mine new uranium out of the ground than to use reprocessed uranium, and therefore the use of reprocessed uranium is limited to only a few nations.

The OECD estimates that with the world nuclear electricity generating rates of 2002, with LWR, once-through fuel cycle, there are enough conventional resources to last 85 years using known resources and 270 years using known and as yet undiscovered resources. With breeders, this is extended to 8,500 years.^[243]

If one is willing to pay $300/kg for uranium, there is a vast quantity available in the ocean.^[221] It is worth noting that since fuel cost only amounts to a small fraction of nuclear energy total cost per kWh, and raw uranium price also constitutes a small fraction of total fuel costs, such an increase on uranium prices wouldn't involve a very significant increase in the total cost per kWh produced.

In 1983, physicist Bernard Cohen proposed that uranium is effectively inexhaustible, and could therefore be considered a renewable source of energy.^[117] He claims that fast breeder reactors, fueled by naturally replenished uranium extracted from seawater, could supply energy at least as long as the sun's expected remaining lifespan of five billion years.^[117] While uranium is a finite mineral resource within the earth, the hydrogen in the sun is finite too – thus, if the resource of nuclear fuel can last over such time scales, as Cohen contends, then nuclear energy is every bit as sustainable as solar power or any other source of energy, in terms of sustainability over the time scale of life surviving on this planet.

We thus conclude that all the world’s energy requirements for the remaining 5×10⁹ yr of existence of life on Earth could be provided by breeder reactors without the cost of electricity rising by as much as 1% due to fuel costs. This is consistent with the definition of a "renewable" energy source in the sense in which that term is generally used.

His paper assumes extraction of uranium from seawater at the rate of 16 kilotonnes (35×10^⁶ lb) per year of uranium.^[117] The current demand for uranium is near 70 kilotonnes (150×10^⁶ lb) per year; however, the use of breeder reactors means that uranium would be used at least 60 times more efficiently than today.

James Hopf, a nuclear engineer writing for American Energy Independence in 2004, believes that there is several hundred years' supply of recoverable uranium even for standard reactors. For breeder reactors, "it is essentially infinite".^[244]

All the following references claim that the supply is far more than demand. Therefore, they believe that uranium will not deplete in the foreseeable future.

The IAEA estimates that using only known reserves at the current rate of demand and assuming a once-through nuclear cycle that there is enough uranium for at least 100 years. However, if all primary known reserves, secondary reserves, undiscovered and unconventional sources of uranium are used, uranium will be depleted in 47,000 years.^[221]
Kenneth S. Deffeyes estimates that if one can accept ore one tenth as rich then the supply of available uranium increased 300 times.^[197] His paper shows that uranium concentration in ores is log-normal distributed. There is relatively little high-grade uranium and a large supply of very low grade uranium.
Ernest Moniz, a professor at the Massachusetts Institute of Technology and the former United States Secretary of Energy, testified in 2009 that an abundance of uranium had put into question plans to reprocess spent nuclear fuel. The reprocessing plans dated from decades previous, when uranium was thought to be scarce. But now, "roughly speaking, we’ve got uranium coming out of our ears, for a long, long time," Professor Moniz said.^[245]

Possible effects and consequences

As uranium production declines, uranium prices would be expected to increase. However, the price of uranium makes up only 9% of the cost of running a nuclear power plant, much lower than the cost of coal in a coal-fired power plant (77%), or the cost of natural gas in a gas-fired power plant (93%).^[246]^[247]

Uranium is different from conventional energy resources, such as oil and coal, in several key aspects. Those differences limit the effects of short-term uranium shortages, but most have no bearing on the eventual depletion. Some key features are:

The uranium market is diverse, and no country has a monopoly influence on its prices.
Thanks to the extremely high energy density of uranium, stockpiling of several years' worth of fuel is feasible.
Significant secondary supplies of already mined uranium exist, including decommissioned nuclear weapons, depleted uranium tails suitable for reenrichment, and existing stockpiles.
Vast amounts of uranium, roughly 800 times the known reserves of mined uranium, are contained in extremely dilute concentrations in seawater.
Introduction of fast neutron reactors, combined with seawater uranium extraction, would make the uranium supply virtually inexhaustible.^[248] There are currently seven experimental fast neutron reactors running globally, in India, Japan, Russia and China.^[249]

Fast neutron reactors (breeder reactors) could utilize large amounts of Uranium-238 indirectly by conversion to Plutonium-239, rather than fissioning primarily just Uranium-235 (which is 0.7% of original mined uranium), for approximately a factor of 100 increase in uranium usage efficiency.^[248] Intermediate between conventional estimates of reserves and the 40 trillion tons total of uranium in Earth's crust (trace concentrations adding up over its 3 * 10¹⁹ ton mass), there are ores of lower grade than otherwise practical but of still higher concentration than the average rock.^[203]^[204] Accordingly, resource figures depend on economic and technological assumptions.

Uranium price

Monthly uranium spot price in US$.^[250]

The uranium spot price has increased from a low in Jan 2001 of US$6.40 per pound of U₃O₈ to a peak in June 2007 of US$135. The uranium prices have dropped substantially since.^[250] Currently (15 July 2013) the uranium spot is US$38.^[251]

The high price in 2007 resulted from shrinking weapons stockpiles and a flood at the Cigar Lake Mine, coupled with expected rises in demand due to more reactors coming online, leading to a uranium price bubble. Miners and Utilities are bitterly divided on uranium prices.^[252]

As of 2018^[update] the price of nuclear fuel was stable at around US$38.81 per pound, 81 cents more than in 2013 and 1 cent more than in 2017, way lower than inflation. At such a low and stable price, breeding is uneconomical.

Number of contracts

Unlike other metals such as gold, silver, copper or nickel, uranium is not widely traded on an organized commodity exchange such as the London Metal Exchange. It is traded on the NYMEX but on very low volume.^[253] Instead, it is traded in most cases through contracts negotiated directly between a buyer and a seller.^[254]

Since the number of companies mining uranium is small, the number of available contracts is also small. Supplies are running short due to flooding of two of the world's largest mines and a dwindling amount of uranium salvaged from nuclear warheads being removed from service.^[255]

Mining

Rising uranium prices draw investments into new uranium mining projects.^[252] Mining companies are returning to abandoned uranium mines with new promises of hundreds of jobs and millions in royalties. Some locals want them back. Others say the risk is too great, and will try to stop those companies "until there's a cure for cancer."^[256]

Electric utilities

Since many utilities have extensive stockpiles and can plan many months in advance, they take a wait-and-see approach on higher uranium costs. Those trying to find uranium in a rising cost climate are forced to face the reality of a seller's market. Sellers remain reluctant to sell significant quantities. By waiting longer, sellers expect to get a higher price for the material they hold. Utilities on the other hand, are very eager to lock up long-term uranium contracts.^[252]

According to the NEA, the nature of nuclear generating costs allows for significant increases in the costs of uranium before the costs of generating electricity significantly increase. A 100% increase in uranium costs would only result in a 5% increase in electric cost.^[120] This is because uranium has to be converted to gas, enriched, converted back to yellow cake and fabricated into fuel elements. The cost of the finished fuel assemblies are dominated by the processing costs, not the cost of the raw materials.^[257] Furthermore, the cost of electricity from a nuclear power plant is dominated by the high capital and operating costs, not the cost of the fuel. Nevertheless, any increase in the price of uranium is eventually passed on to the consumer either directly or through a fuel surcharge.^{[citation needed]} As of 2020^[update], this has not happened and the price of nuclear fuel is low enough to make breeding uneconomical.

Substitutes

An alternative to uranium is thorium which is three times more common than uranium. Fast breeder reactors are not needed. Compared to conventional uranium reactors, thorium reactors using the thorium fuel cycle may produce some 40 times the amount of energy per unit of mass.^[258] However, creating the technology, infrastructure and know-how needed for a thorium-fuel economy is uneconomical at current and predicted uranium prices.

References

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External links

Health Impacts for Uranium Mine and Mill Residents – Science Issues.
Uranium mining left a legacy of death.
Paterson-Beedle, M.; Macaskie, Lynne E.; Readman, J.E.; Hriljac, J.A. (May 2009). "Biorecovery of Uranium from Minewaters into Pure Mineral Product at the Expense of Plant Wastes". Advanced Materials Research. 71–73: 621–624. doi:10.4028/www.scientific.net/AMR.71-73.621. S2CID 136720757.
World Uranium Mining (giving production statistics) Archived 2018-12-26 at the Wayback Machine, World Nuclear Association, July 2006
Uranium resources and nuclear energy Energy Watch Group, December 2006
In Situ Leaching Method at Uranium SA Website (South Australian Chamber of Mines and Energy)
Evaluation of Cost of Seawater Uranium Recovery and Technical Problems toward Implementation
Watch Uranium, a 1990 documentary on the risks of uranium mining
World Supply of Uranium Archived 2013-02-12 at the Wayback Machine — World Nuclear Association, March 2007
The Guardian (22 Jan. 2008): Awards shine spotlight on big business green record
Extracting a disaster The Guardian, 2008
Mudd, Gavin M.; Diesendorf, Mark (1 April 2008). "Sustainability of Uranium Mining and Milling: Toward Quantifying Resources and Eco-Efficiency". Environmental Science & Technology. 42 (7): 2624–2630. Bibcode:2008EnST...42.2624M. doi:10.1021/es702249v. PMID 18505007.
Uranium glows ever hotter (Investors Chronicle, UK)

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v t e Uranium mining
By country	Australia Kakadu National Park Canada Bancroft Elliot Lake Kazakhstan Namibia United States Arizona Colorado Navajo Nation New Mexico Utah Wyoming
Lists	List of uranium projects List of countries by uranium production List of countries by uranium reserves List of inquiries into uranium mining in Australia
Opposition	Thomas Banyacya Kevin Buzzacott Katsumi Furitsu Jim Green Jacqui Katona Scott Ludlam Yvonne Margarula JoAnn Tall Sun Xiaodi Floyd Red Crow Westerman List of Nuclear-Free Future Award recipients World Uranium Hearing
Other articles	Uranium in the environment Uranium market Uranium mining debate Peak uranium Botanical prospecting for uranium Nuclear power in the United States Church Rock uranium mill spill Sequoyah Fuels Corporation Anti-nuclear movement in the United States Uranium Mill Tailings Radiation Control Act The Return of Navajo Boy Nuclear labor issues International Uranium Film Festival History of the anti-nuclear movement The Navajo People and Uranium Mining Hibakusha 1974 Elliot Lake miners strike Yellowcake boomtown