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Rubidium, 37Rb
Rubidium
Pronunciation/ruːˈbɪdiəm/ ​(roo-BID-ee-əm)
Appearancegrey white
Standard atomic weight Ar°(Rb)
Rubidium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
K
↑
Rb
↓
Cs
krypton ← rubidium → strontium
Atomic number (Z)37
Groupgroup 1: hydrogen and alkali metals
Periodperiod 5
Block  s-block
Electron configuration[Kr] 5s1
Electrons per shell2, 8, 18, 8, 1
Physical properties
Phase at STPsolid
Melting point312.45 K ​(39.30 °C, ​102.74 °F)
Boiling point961 K ​(688 °C, ​1270 °F)
Density (at 20° C)1.534 g/cm3[3]
when liquid (at m.p.)1.46 g/cm3
Triple point312.41 K, ​? kPa[4]
Critical point2093 K, 16 MPa (extrapolated)[4]
Heat of fusion2.19 kJ/mol
Heat of vaporization69 kJ/mol
Molar heat capacity31.060 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 434 486 552 641 769 958
Atomic properties
Oxidation states−1, +1 (a strongly basic oxide)
ElectronegativityPauling scale: 0.82
Ionization energies
  • 1st: 403 kJ/mol
  • 2nd: 2632.1 kJ/mol
  • 3rd: 3859.4 kJ/mol
Atomic radiusempirical: 248 pm
Covalent radius220±9 pm
Van der Waals radius303 pm
Color lines in a spectral range
Spectral lines of rubidium
Other properties
Natural occurrenceprimordial
Crystal structure ​body-centered cubic (bcc) (cI2)
Lattice constant
Body-centered cubic crystal structure for rubidium
a = 569.9 pm (at 20 °C)[3]
Thermal expansion85.6×10−6/K (at 20 °C)[3]
Thermal conductivity58.2 W/(m⋅K)
Electrical resistivity128 nΩ⋅m (at 20 °C)
Magnetic orderingparamagnetic[5]
Molar magnetic susceptibility+17.0×10−6 cm3/mol (303 K)[6]
Young's modulus2.4 GPa
Bulk modulus2.5 GPa
Speed of sound thin rod1300 m/s (at 20 °C)
Mohs hardness0.3
Brinell hardness0.216 MPa
CAS Number7440-17-7
History
DiscoveryRobert Bunsen and Gustav Kirchhoff (1861)
First isolationGeorge de Hevesy
Isotopes of rubidium
Main isotopes[7] Decay
abun­dance half-life (t1/2) mode pro­duct
82Rb synth 1.2575 m β+ 82Kr
83Rb synth 86.2 d ε 83Kr
γ –
84Rb synth 32.9 d ε 84Kr
β+ 84Kr
γ –
β− 84Sr
85Rb 72.2% stable
86Rb synth 18.7 d β− 86Sr
γ –
87Rb 27.8% 4.923×1010 y β− 87Sr
 Category: Rubidium
| references

Rubidium (/[invalid input: 'icon']r[invalid input: 'ʉ']ˈbɪdiəm/ roo-BID-ee-əm) is a chemical element with the symbol Rb and atomic number 37. Rubidium is a soft, silvery-white metallic element of the alkali metal group. The atomic weight is 85.4678. Elemental rubidium is highly reactive, with properties similar to those of other elements in group 1, such as very rapid oxidation in air. Rubidium has only one stable isotope, 85Rb. The isotope 87Rb, which composes almost 28% of naturally occurring rubidium, is radioactive and has a half-life of 49 billion years—more than three times longer than the estimated age of the universe.

German chemists Robert Bunsen and Gustav Kirchhoff discovered rubidium in 1861 by the newly developed method of flame spectroscopy. Its compounds have chemical and electronic applications. Rubidium metal is easily vaporized and has a convenient spectral absorption range, making it a frequent target for laser manipulation of atoms.

Rubidium is not known to be necessary for any living organisms. However, like caesium, rubidium ions are handled by living organisms in a manner similar to potassium ions: they are actively taken up by plants and living animal cells.

Characteristics

Rubidium is a very soft, ductile, silvery-white metal.[8] It is is the second most electropositive of the non-radioactive alkali metals and melts at a temperature of 39.3 °C (102.7 °F). Similar to other alkali metals, this metal reacts violently with water, forms amalgams with mercury and alloys with gold, caesium, sodium, and potassium.[9] As with potassium (which is slightly less reactive) and caesium (which is slightly more reactive), this reaction is usually vigorous enough to ignite the hydrogen gas it liberates. Rubidium has also been reported to ignite spontaneously in air.[8]Rubidium has a very low ionization energy of only 406 J/mol.[10] Rubidium and potassium shows a very similar violet color in the flame test which makes spectroscopy methods necessary to distinguish the two elements.[11]

Compounds

See also: Category:Rubidium compounds

Rubidium chloride (RbCl) is probably the most used rubidium compound; it is used in biochemistry to induce cells to take up DNA, and as a biomarker since it is readily taken up to replace potassium, and does only occur in small quantities in living organisms. Other common rubidium compounds are the corrosive rubidium hydroxide (RbOH), the starting material for most rubidium-based chemical processes; rubidium carbonate (RbCO3), which is used in some optical glasses, and rubidium copper sulfate, Rb2SO4•CuSO4•6H2O. Rubidium silver iodide (RbAg4I5) has the highest room temperature conductivity of any known ionic crystal, a property that is being exploited in thin film batteries and other applications.[12][13]

Rubidium has a number of oxides, including rubidium monoxide (Rb2O), Rb6O and Rb9O2, which form if rubidium metal is exposed to air; rubidium in excess oxygen gives the superoxide RbO2. Rubidium forms salts with halides, making rubidium fluoride, rubidium chloride, rubidium bromide and rubidium iodide.

Isotopes

Main article: Isotopes of rubidium

Naturally occurring rubidium is composed of two isotopes: the stable 85Rb (72.2%) and the radioactive 87Rb (27.8%).[14] Natural rubidium is radioactive with specific activity of about 670 Bq/g, enough to significantly expose a photographic film in 110 days.[15][16] Asides from from 85Rb and 87Rb, another 24 isotopes are known with half times of under 3 months. Most of them are highly radioactive and have little uses.

Rubidium-87 has a half-life of 4.88×1010 years, which is more than three times the age of the universe of 13.75 ± 0.11 ×109 years,[17] making it a Primordial nuclide. It readily substitutes for potassium in minerals, and is therefore fairly widespread. Rb has been used extensively in dating rocks; 87Rb decays to stable 87Sr by emission of a negative beta particle. During fractional crystallization, Sr tends to become concentrated in plagioclase, leaving Rb in the liquid phase. Hence, the Rb/Sr ratio in residual magma may increase over time, resulting in rocks with elevated Rb/Sr ratios due to progressing differentiation. The highest ratios (10 or more) occur in pegmatites. If the initial amount of Sr is known or can be extrapolated then the age can be determined by measurement of the Rb and Sr concentrations and of the 87Sr/86Sr ratio. The dates indicate the true age of the minerals only if the rocks have not been subsequently altered (see rubidium-strontium dating).[18][19]

One of the non-natural isotopes rubidium-82 is produced by electron capture decay of Strontium-82 with a half-life of 25.36 days. The subsequent decay of rubidium-82 with a half-life of 76 seconds to stable krypton-82 happens by positron emission.[14]

Occurrence

Rubidium is the twenty-third most abundant element in the Earth's crust, roughly as abundant as zinc and rather more common than copper.[20] It occurs naturally in the minerals leucite, pollucite, carnallite and zinnwaldite, which contain up to 1% of its oxide. Lepidolite contains between 0.3% and 3.5% rubidium and this is the commercial source of the element.[21] Some potassium minerals and potassium chlorides also contain the element in commercially significant amounts.[22]

Sea water contains an average of 125 µg/L of rubidium compared to the much higher value for potassium of 408 mg/L and the much lower value of 0.3 µg/L for caesium[23]

Because of its large ionic radius, rubidium is one of the "incompatible elements."[24] During magma crystallization, rubidium is concentrated together with its heavier analogue caesium in the liquid phase and crystallizes last. Therefore the largest deposits of rubidium and caesium are zone pegmatite ore bodies formed by this enrichment process. Because rubidium substitutes for potassium in the crystallization of magma, the enrichment is far less effective than in the case of caesium. Zone pegmatite ore bodies containing mineable quantities of caesium as pollucite or the lithium minerals lepidolite are also a source for rubidium as a by-product.[20]

Two notable sources of rubidium are the rich deposits of pollucite at Bernic Lake, Manitoba. Both of these are also sources of caesium. Rubicline ((Rb,K)AlSi3O8) found as impurities in pollucite on the Italian island of Elba with a rubidium content of 17.5%[25]

Production

Although rubidium is more abundant in Earth's crust than caesium the limited applications and the lack of a mineral rich in rubidium limits the production of rubidium compounds to 2 to 4 tonnes per year.[20] The are several methods to separate potassium, rubidium and caesium. The fractional crystallization of a rubidium and caesium alum (Cs,Rb)Al(SO4)2·12H2O yields after 30 subsequent steps pure rubidium alum. Reports of two other methods are given in the literature the chlorostannate process and the ferrocyanide process.[20][26] For several years in the 1950s and 1960s a by-product of the potassium production called Alkarb was a main source for rubidium. Alkarb contained 21% rubidium while the rest was potassium and a small fraction of caesium.[27] Today the largest producers of caesium, for example the Tanco Mine, Manitoba, Canada, produce rubidium as by-product from pollucite.[20]

History

Rubidium was discovered in 1861 by Robert Bunsen and Gustav Kirchhoff in the mineral lepidolite through the use of a spectroscope. Because of the bright red lines in its emission spectrum, they chose a name derived from the Latin word rubidus, dark red.[28][29]

Three middle-aged men, with the one in the middle sitting down. All wear long jackets, and the shorter man on the left has a beard.
Gustav Kirchhoff (left) and Robert Bunsen (center) discovered rubidium spectroscopically.

Rubidium is present as a minor component in lepidolite. Kirchhoff and Bunsen processed 150 kg of a lepidolite containing only 0.24% rubidium oxide (Rb2O). Potassium, rubidium form insoluble salts with chloroplatinic acid, but these salts show a slight difference in solubility in hot water. Therefore, the less-soluble rubidium hexachloroplatinate (Rb2PtCl6) could be obtained by fractional crystallization. After reduction of the hexachloroplatinate with hydrogen, rubidium could be separated by the difference in solubility of their carbonates in alcohol. This process yielded 0.51 grams of rubidium chloride for further studies. The first large scale isolation of caesium and rubidium compounds, performed from 44,000 liters of mineral water by Bunsen and Kirchhoff, yielded, besides 7.3 grams of caesium chloride, also 9.2 grams of rubidium chloride.[28][29] Rubidium was the second element, shortly after caesium, to be discovered spectroscopically, only one year after the invention of the spectroscope by Bunsen and Kirchhoff.[30]

The two scientists used the rubidium chloride thus obtained to estimate the atomic weight of the new element as 85.36 (the currently accepted value is 85.47).[28] They tried to generate elemental rubidium by electrolysis of molten rubidium chloride, but instead of a metal, they obtained a blue homogenous substance which "neither under the naked eye nor under the microscope showed the slightest trace of metallic substance." They assigned it as a subchloride (Rb
2Cl); however, the product was probably a colloidal mixture of the metal and rubidium chloride.[31] In a second experiment to produce metallic rubidium Bunsen was able to reduce rubidium by heating charred rubidium tartrate. Although the distilled rubidium was pyrophoric it was possible to determine the density and the melting point of rubidium. The quality of the research done in the 1860s can be appraise by the fact that the determined density differes less than 0.1 g/cm3 and the melting point by less than 1 °C from the presently accepted values.[32]

The slight radioactivity of rubidium was discovered in 1908 but before the theory of isotopes was established in the 1910s and the low activity due to the long half live of above 1010 years made interpretation complicated. The now proven decay of 87Rb to stable 87Sr through beta decay was still under discussion in the late 1940s.[33][34]

Rubidium had minimal industrial value before the 1920s.[35] Since then, the most important use of rubidium has been in research and development, primarily in chemical and electronic applications. In 1995, rubidium-87 was used to produce a Bose-Einstein condensate,[36] for which the discoverers won the 2001 Nobel Prize in Physics.[37]

Applications

A rubidium fountain atomic clock at the United States Naval Observatory

Rubidium compounds are sometimes used in fireworks to give them a purple color.[38] Rubidium has also been considered for use in a thermoelectric generator using the magnetohydrodynamic principle, where rubidium ions are formed by heat at high temperature and passed through a magnetic field.[39] These conduct electricity and act like an armature of a generator thereby generating an electric current. Rubidium, particularly vaporized 87Rb, is one of the most commonly used atomic species employed for laser cooling and Bose-Einstein condensation. Its desirable features for this application include the ready availability of inexpensive diode laser light at the relevant wavelength, and the moderate temperatures required to obtain substantial vapor pressures.[40][citation needed]

Rubidium has been used for polarizing 3He, producing volumes of magnetized 3He gas, with the nuclear spins aligned toward a particular direction in space, rather than randomly. Rubidium vapor is optically pumped by a laser and the polarized Rb polarizes 3He through the hyperfine interaction.[41] Spin-polarized 3He cells are becoming popular for neutron polarization measurements and for producing polarized neutron beams for other purposes.[42]

Rubidium is the main component of secondary frequency references (rubidium oscillators) to maintain frequency accuracy in cell site transmitters and other electronic transmitting, networking and test equipment. This rubidium standard are often used with GPS to produce a "primary frequency standard" that has greater accuracy and is less expensive than caesium standards.[43][44] Rubidium standards are mass-produced for the telecommunication industry.[45]

Other potential or current uses of rubidium include a working fluid in vapor turbines, a getter in vacuum tubes and a photocell component.[46] The resonant element in atomic clocks utilizes the hyperfine structure of rubidium's energy levels.[44] Rubidium is also used as an ingredient in special types of glass, in the production of superoxide by burning in oxygen, in the study of potassium ion channels in biology and as the vapor to make atomic magnetometers.[47] In particular, 87Rb is currently being used, with other alkali metals, in the development of spin-exchange relaxation-free (SERF) magnetometers.[47]

Rubidium-82 is used for positron emission tomography. Rubidium is very similar to potassium and therefore tissue with high potassium content will also accumulate the radioactive rubidium. One of the main uses is in myocardial perfusion imaging. The very short half-life of 76 seconds makes it necessary to produce the rubidium-82 from decay of strontium-82 close to the patient.[48] As a result of changes in the blood brain barrier in brain tumors, rubidium collects more in brain tumors than normal brain tissue, allowing to use the radioisotope rubidium-82 in nuclear medicine to locate and image brain tumors.[49]

Rubidium was tested for the influence on manic depression and depression.[50][51] Dialysis patient show a depletion in rubidium and therefore a supplementation might help during depression.[52] In some tests the rubidium was administered as rubidium chloride with up to 720 mg.[53]

Precautions and biological effects

Rubidium reacts violently with water and can cause fires. To ensure safety and purity, this metal is kept under a dry mineral oil and is usually sealed in glass ampoules in an inert atmosphere. Rubidium forms peroxides on exposure even to small amount of air diffusing into oil, and is thus subject to similar peroxide precautions as storage of metallic potassium.[54]

Rubidium, like sodium and potassium, almost always has +1 oxidation state when dissolved in water, and this includes all biological systems. The human body tends to treat Rb+ ions as if they were potassium ions, and therefore concentrates rubidium in the body's intracellular fluid (i.e., inside cells).[55] The ions are not particularly toxic, a 70 kg person contains on average 0.36 g of rubidium and an increase in this value by 50 to 100 times did not show negative effects in test persons.[56] The biological half-life in humans was measured as 31–46 days.[50] Although a partial substitution of potassium by rubidium is possible, rats with more than 50% of potassium substituted in the muscle tissue died.[57][58]

References

  1. ^ "Standard Atomic Weights: Rubidium". CIAAW. 1969.
  2. ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  3. ^ a b c Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
  4. ^ a b Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.122. ISBN 1-4398-5511-0.
  5. ^ Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (PDF) (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
  6. ^ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
  7. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  8. ^ a b Ohly, Julius (1910). "Rubidium". Analysis, detection and commercial value of the rare metals. Mining Science Pub. Co.
  9. ^ Holleman, Arnold F.; Wiberg, Egon; Wiberg, Nils (1985). "Vergleichende Übersicht über die Gruppe der Alkalimetalle". Lehrbuch der Anorganischen Chemie (in German) (91–100 ed.). Walter de Gruyter. pp. 953–955. ISBN 3-11-007511-3.
  10. ^ Moore, John W; Stanitski, Conrad L; Jurs, Peter C (2009-01-21). Principles of Chemistry: The Molecular Science. p. 259. ISBN 9780495390794.
  11. ^ . p. 48 http://books.google.de/books?ei=vSyFTZ_qDszBtAb3lumBAwpg=PA48. {{cite book}}: Missing or empty |title= (help)
  12. ^ Smart, Lesley (1995). "RbAg4I5". Solid state chemistry: an introduction. CRC Press. pp. 176–177. ISBN 9780748740680. {{cite book}}: Unknown parameter |coauthor= ignored (|author= suggested) (help)
  13. ^ Bradley, J. N. (1967). "Relationship of structure and ionic mobility in solid MAg4I5". Trans. Faraday Soc. 63: 2516. doi:10.1039/TF9676302516. {{cite journal}}: Unknown parameter |coauthor= ignored (|author= suggested) (help)
  14. ^ a b Audi, Georges (2003). "The NUBASE Evaluation of Nuclear and Decay Properties". Nuclear Physics A. 729 (1). Atomic Mass Data Center: 3–128. doi:10.1016/j.nuclphysa.2003.11.001.
  15. ^ Strong, W. W. (1909). "On the Possible Radioactivity of Erbium, Potassium and Rubidium". Physical Review (Series I). 29 (2): 170–173. doi:10.1103/PhysRevSeriesI.29.170.
  16. ^ Lide, David R; Frederikse, H. P. R (1995-06). CRC handbook of chemistry and physics: a ready-reference book of chemical and physical data. p. 4-25. ISBN 9780849304767. {{cite book}}: Check date values in: |date= (help)
  17. ^ "Seven-Year Wilson Microwave Anisotropy Probe (WMAP) Observations: Sky Maps, Systematic Errors, and Basic Results" (PDF). nasa.gov. Retrieved 2011-02-01. (see p. 39 for a table of best estimates for various cosmological parameters)
  18. ^ Attendorn, H. -G.; Bowen, Robert (1988). "Rubidium-Strontium Dating". Isotopes in the Earth Sciences. Springer. pp. 162–165. ISBN 9780412537103.
  19. ^ Walther, John Victor (1988 2009). "Rubidium-Strontium Systematics". Essentials of geochemistry. Jones & Bartlett Learning. pp. 383–385. ISBN 9780763759223. {{cite book}}: Check date values in: |year= (help)
  20. ^ a b c d e Butterman, William C.; Brooks, William E.; Reese, Jr., Robert G. (2003). "Mineral Commodity Profile: Rubidium" (PDF). United States Geological Survey. Retrieved 2010-12-04.
  21. ^ Wise, M. A. (1995). "Trace element chemistry of lithium-rich micas from rare-element granitic pegmatites". Mineralogy and Petrology. 55 (13): 203–215. doi:10.1007/BF01162588.
  22. ^ Norton, J. J. (1973). "Lithium, cesium, and rubidium—The rare alkali metals". In Brobst, D. A., and Pratt, W. P. (ed.). United States mineral resources. Vol. Paper 820. U.S. Geological Survey Professional. pp. 365–378. Retrieved 2010-09-26.{{cite book}}: CS1 maint: multiple names: editors list (link)
  23. ^ Bolter, E; Turekian, K; Schutz, D (1964). "The distribution of rubidium, cesium and barium in the oceans". Geochimica et Cosmochimica Acta. 28 (9): 1459. doi:10.1016/0016-7037(64)90161-9.
  24. ^ McSween, Harry Y; Jr,; Huss, Gary R (2010). Cosmochemistry. p. 224. ISBN 9780521878623.{{cite book}}: CS1 maint: extra punctuation (link)
  25. ^ Teertstra, David K.; Cerny, Petr; Hawthorne, Frank C.; Pier, Julie; Wang, Lu-Min; Ewing, Rodney C. (1998). "Rubicline, a new feldspar from San Piero in Campo, Elba, Italy". American Mineralogist. 83 (11–12 Part 1): 1335–1339.
  26. ^ bulletin 585. United States. Bureau of Mines. 1995.
  27. ^ "Cesium and Rubidium Hit Market". Chemical & Engineering News. 37 (22): 50. 1959. doi:10.1021/cen-v037n022.p050.
  28. ^ a b c Kirchhoff,, G.; Bunsen, R. (1861). "Chemische Analyse durch Spectralbeobachtungen". Annalen der Physik und Chemie. 189 (7): 337–381. doi:10.1002/andp.18611890702.{{cite journal}}: CS1 maint: extra punctuation (link)
  29. ^ a b Weeks, Mary Elvira (1932). "The discovery of the elements. XIII. Some spectroscopic discoveries". Journal of Chemical Education. 9 (8): 1413–1434. doi:10.1021/ed009p1413.
  30. ^ Ritter, Stephen K. (2003). "C&EN: It's Elemental: The Periodic Table – Cesium". American Chemical Society. Retrieved 2010-02-25.
  31. ^ Zsigmondy, Richard (2007). Colloids and the Ultra Microscope. Read books. p. 69. ISBN 978-1-4067-5938-9. Retrieved 2010-09-26.
  32. ^ Bunsen, R. (1863). "Ueber die Darstellung und die Eigenschaften des Rubidiums". Annalen der Chemie und Pharmacie. 125 (3): 367. doi:10.1002/jlac.18631250314.
  33. ^ . doi:10.1080/14786441008520248. {{cite journal}}: Cite journal requires |journal= (help); Missing or empty |title= (help)
  34. ^ Campell, N. R.; Wood, A. (1908). 14: 15. {{cite journal}}: Cite journal requires |journal= (help); Missing or empty |title= (help); Unknown parameter |unused_data= ignored (help)
  35. ^ Butterman, W.C.; Reese, Jr., R.G. "Mineral Commodity Profiles Rubidium" (PDF). United States Geological Survey. Retrieved 2010-10-13.
  36. ^ "Press Release: The 2001 Nobel Prize in Physics". Retrieved 2010-02-01.
  37. ^ Levi, Barbara Goss (2001). "Cornell, Ketterle, and Wieman Share Nobel Prize for Bose-Einstein Condensates". Search & Discovery. Physics Today online. Archived from the original on 2007-10-24. Retrieved 2008-01-26.
  38. ^ Koch, E.-C. (2002). "Special Materials in Pyrotechnics, Part II: Application of Caesium and Rubidium Compounds in Pyrotechnics". Journal Pyrotechnics. 15: 9–24.
  39. ^ Boikess, Robert S; Edelson, Edward (1981). Chemical principles. p. 193. ISBN 9780060408084.
  40. ^ . Vol. 101. 1996. pp. 419–618 http://nvl.nist.gov/pub/nistpubs/jres/101/4/cnt101-4.htm. {{cite book}}: |journal= ignored (help); Missing or empty |title= (help)
  41. ^ Gentile, T. R.; Chen, W. C.; Jones, G. L.; Babcock, E.; Walker, T. G. "Polarized 3He spin filters for slow neutron physics" (PDF). Journal of Research of the National Institute of Standards and Technology. 100: 299–304.
  42. ^ "Neutron spin filters based on polarized helium-3". NIST Center for Neutron Research 2002 Annual Report. Retrieved 2008-01-11.
  43. ^ Eidson, John C (2006-04-11). "GPS". Measurement, control, and communication using IEEE 1588. p. 32. ISBN 9781846282508.
  44. ^ a b King, Tim; Newson, Dave (1999-07-31). "Rubidium and crystal oscillators". Data network engineering. p. 300. ISBN 9780792385943.
  45. ^ Marton, L (1977-01-01). "Rubidium Vapor Cell". Advances in electronics and electron physics. ISBN 9780120146444.
  46. ^ Mittal. Introduction To Nuclear And Particle Physics. p. 274. ISBN 9788120336100.
  47. ^ a b Li, Zhimin; Wakai, Ronald T.; Walker, Thad G. (2006). "Parametric modulation of an atomic magnetometer". Applied Physics Letters. 89 (13): 134105. doi:10.1063/1.2357553.
  48. ^ Jadvar, J.; Anthony Parker (2005). "Rubidium-82". Clinical PET and PET/CT. p. 59. ISBN 9781852338381. {{cite book}}: More than one of |first1= and |first= specified (help)
  49. ^ Yen, CK; Yano, Y; Budinger, TF; Friedland, RP; Derenzo, SE; Huesman, RH; O'Brien, HA (1982). "Brain tumor evaluation using Rb-82 and positron emission tomography". Journal of nuclear medicine : official publication, Society of Nuclear Medicine. 23 (6): 532–7. PMID 6281406.
  50. ^ a b Paschalis, C; Jenner, F A; Lee, C R (1978). "Effects of rubidium chloride on the course of manic-depressive illness". J R Soc Med. 71 (9): 343–352. PMC 1436619. PMID 349155.
  51. ^ Malekahmadi, P (1984). "Rubidium in psychiatry: Research implications". Pharmacology Biochemistry and Behavior. 21: 49. doi:10.1016/0091-3057(84)90162-X.
  52. ^ Canavese, Caterina; Decostanzi, Ester; Branciforte, Lino; Caropreso, Antonio; Nonnato, Antonello; Sabbioni, Enrico (2001). "Depression in dialysis patients: Rubidium supplementation before other drugs and encouragement?". Kidney International. 60 (3): 1201–1201. doi:10.1046/j.1523-1755.2001.0600031201.x.
  53. ^ Lake, James A. (2006). Textbook of Integrative Mental Health Care. New York: Thieme Medical Publishers. ISBN 1-58890-299-4.
  54. ^ Martel, Bernard; Cassidy, Keith (2004-07-01). "Rubidium". Chemical risk analysis: a practical handbook. p. 215. ISBN 9781903996652.
  55. ^ Relman, AS (1956). "The physiological behavior of rubidium and cesium in relation to that of potassium". The Yale journal of biology and medicine. 29 (3): 248–62. PMC 2603856. PMID 13409924.
  56. ^ Fieve, Ronald R.; Meltzer, Herbert L.; Taylor, Reginald M. (1971). "Rubidium chloride ingestion by volunteer subjects: Initial experience". Psychopharmacologia. 20 (4): 307. doi:10.1007/BF00403562. PMID 5561654.
  57. ^ Meltzer, HL (1991). "A pharmacokinetic analysis of long-term administration of rubidium chloride". Journal of clinical pharmacology. 31 (2): 179–84. PMID 2010564.
  58. ^ Follis, Richard H., Jr. (1943). "Histological Effects in rats resulting from adding Rubidium or Cesium to a diet deficient in potassium". AJP – Legacy. 138 (2): 246.{{cite journal}}: CS1 maint: multiple names: authors list (link)

Further reading

  • Louis Meites, Handbook of Analytical Chemistry (New York: McGraw-Hill Book Company, 1963)
  • Daniel A. Steck. "Rubidium-87 D Line Data" (PDF). Los Alamos National Laboratory (technical report LA-UR-03-8638).
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