Tin(II) sulfate
-sulfat.png) Unit cell of tin(II) sulfate.
| |
| Names | |
|---|---|
| Other names
Stannous sulfate
| |
| Identifiers | |
3D model (JSmol)
|
|
| ChemSpider | |
| ECHA InfoCard | 100.028.457 |
| EC Number |
|
PubChem CID
|
|
| UNII | |
CompTox Dashboard (EPA)
|
|
| |
| |
| Properties | |
| SnSO4 | |
| Molar mass | 214.773 g/mol |
| Appearance | white-yellowish crystalline solid deliquescent |
| Density | 4.15 g/cm3 |
| Melting point | 378 °C (712 °F; 651 K) |
| Boiling point | decomposes to SnO2 and SO2 |
| 33 g/100 mL (25 °C) | |
| Structure[1] | |
| Primitive orthorhombic | |
| Pnma, No. 62 | |
a = 8.80 Å, b = 5.32 Å, c = 7.12 Å[1]
| |
| Hazards | |
| NFPA 704 (fire diamond) | |
| Flash point | Non-flammable |
| Lethal dose or concentration (LD, LC): | |
LD50 (median dose)
|
2207 mg/kg (oral, rat) 2152 mg/kg (oral, mouse)[2] |
| Related compounds | |
Other anions
|
Tin(II) chloride, tin(II) bromide, tin(II) iodide |
Other cations
|
Lead(II) sulfate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Tin(II) sulfate (SnSO4) is a chemical compound. It is a white solid that can absorb enough moisture from the air to become fully dissolved, forming an aqueous solution; this property is known as deliquescence. It can be prepared by a displacement reaction between metallic tin and copper(II) sulfate:[3]
- Sn (s) + CuSO4 (aq) → Cu (s) + SnSO4 (aq)
Tin(II) sulfate is a convenient source of tin(II) ions uncontaminated by tin(IV) species.
Structure
[edit]In the solid state the sulfate ions are linked together by O-Sn-O bridges. The tin atom has three oxygen atoms arranged pyramidally at 226 pm with the three O-Sn-O bond angles of 79°, 77.1° and 77.1°. Other Sn-O distances are longer ranging from 295 - 334pm.[3][4]
References
[edit]- ^ a b Donaldson, J. D.; Puxley, D. C. (1972). "The crystal structure of tin(II) sulphate". Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry. 28 (3): 864–867. Bibcode:1972AcCrB..28..864D. doi:10.1107/S0567740872003322.
- ^ "Tin (inorganic compounds, as Sn)". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
- ^ a b Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. p. 451. ISBN 978-0-08-022057-4.
- ^ Donaldson, J. D.; Puxley, D. C. (1972). "The crystal structure of tin(II) sulphate". Acta Crystallographica Section B. 28 (3): 864–867. Bibcode:1972AcCrB..28..864D. doi:10.1107/S0567740872003322. ISSN 0567-7408.