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Pentaoxygen difluoride

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Pentaoxygen difluoride
Identifiers
3D model (JSmol)
  • InChI=1S/F2O5/c1-3-5-7-6-4-2
    Key: YDWQUFUNVRYGQP-UHFFFAOYSA-N
  • FOOOOOF
Properties
F2O5
Molar mass 117.992 g·mol−1
Appearance reddish-brown liquid at 90 K
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Pentaoxygen difluoride is a binary inorganic compound of fluorine and oxygen with the chemical formula O5F2.[1][2] The compound is one of many known oxygen fluorides.

Synthesis

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The compound can be prepared by electric discharges through the F2O2 mixture of the certain molar ratio at 60 to 77 K. The ratio is predicted to be 5:2.[3]

Physical properties

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Pentaoxygen difluoride is an oxidizing agent. At 90 K, the compound looks like a reddish-brown liquid and as an oil at 77  K.[3]

At 77 K, the compound is insoluble in liquid N2, soluble in liquid O2 and CH4. At 65 K, it is soluble in liquid OF2.[3]

References

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  1. ^ Streng, A. G.; Grosse, A. V. (January 1966). "Two New Fluorides of Oxygen, O5F2 and O6F2 1,2". Journal of the American Chemical Society. 88 (1): 169–170. doi:10.1021/ja00953a035. Retrieved 19 May 2023.
  2. ^ Bailar, John Christian; Trotman-Dickenson, A. F. (1973). Comprehensive Inorganic Chemistry: Ge, Sn, Pb, Group VB, Group VIB, Group VIIB. Pergamon Press. p. 764. ISBN 978-0-08-017275-0. Retrieved 19 May 2023.
  3. ^ a b c F Fluorine: Compounds with Oxygen and Nitrogen. Springer Science & Business Media. 29 June 2013. p. 134. ISBN 978-3-662-06339-2. Retrieved 19 May 2023.