With a population of 43,880 people, Mailiao has an area of 80.1668 km2.
Maifeng Village, Maijin Village, Wayao Village, Xinghua Village, Haifeng Village, Houan Village, Zhongxing Village, Sancheng Village, Lunhou Village, Qiaotou Village, Xinji Village, Shicuo Village, Leicuo Village.
The township's chief industry is the Formosa Mailiao Refinery, an oil refinery that processes 400,000 barrels (64,000 m3) of crude oil per day. The refinery exports it goods via the township's harbor.
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