Rhenium(VII) oxide
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| Other names
Rhenium heptoxide
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| Identifiers | |
3D model (JSmol)
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| ECHA InfoCard | 100.013.857 |
PubChem CID
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| UNII | |
CompTox Dashboard (EPA)
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| Properties | |
| Re2O7 | |
| Molar mass | 484.40298 g/mol |
| Appearance | yellow crystalline powder |
| Density | 6.103 g/cm3, solid |
| Melting point | 360 °C (680 °F; 633 K) |
| Boiling point | sublimes |
| Related compounds | |
Related compounds
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Manganese(VII) oxide; technetium(VII) oxide; perrhenic acid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Rhenium(VII) oxide is the inorganic compound with the formula Re2O7. This yellowish solid is the anhydride of HOReO3. Perrhenic acid, Re2O7·2H2O, is closely related to Re2O7. Re2O7 is the raw material for all rhenium compounds, being the volatile fraction obtained upon roasting the host ore.[1]
Structure
Crystalline Re2O7 is an inorganic polymer, which consists of alternating octahedral and tetrahedral Re centres. Upon heating, the polymer cracks to give molecular (nonpolymeric) Re2O7. This molecular species closely resembles manganese heptoxide, consisting of a pair of ReO4 tetrahedra that share a vertex, i.e., O3Re-O-ReO3.[2]
Synthesis and reactions
Rhenium(VII) oxide is formed when metallic rhenium or its oxides or sulfides are oxidized at 500-700 °C in air.:[3]
Re2O7 is very reactive toward water. It dissolves in water to give perrhenic acid. It is a precursor to methylrhenium trioxide ("MTO"), a catalyst for oxidations.[4]
Uses
Hydrogenation catalyst
Rhenium(VII) oxide finds some use in organic synthesis as a catalyst for ethenolysis,[5] carbonyl reduction and amide reduction.[6]
See also
References
- ^ Hans Georg Nadler "Rhenium and Rhenium Compounds" Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2000. doi:10.1002/14356007.a23_199
- ^ Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN 0-19-855370-6.
- ^ Schmidt, M.; Schmidbaur, H., "Trimethylsilyl perrhenate", Inorg. Synth. 1967, 9, 149-151. doi:10.1002/9780470132401.ch40
- ^ W. A. Herrmann and F. E. Kuhn (1997). "Organorhenium Oxides". Acc. Chem. Res. 30 (4): 169–180. doi:10.1021/ar9601398.
- ^ "Metathesis". Kirk-Othmer Encyclopedia of Chemical Technology. Wiley.
{{cite encyclopedia}}: Unknown parameter|authors=ignored (help) - ^ Nishimura, Shigeo (2001). Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis (1st ed.). Newyork: Wiley-Interscience. pp. 42–43, 182, 389–390, & 408. ISBN 9780471396987.
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