Leo Baekeland

From Wikipedia, the free encyclopedia
Jump to: navigation, search
Leo Baekeland
Leo Hendrik Baekeland, 1916.jpg
Portrait of Leo Baekeland in 1916.
Born Leo Henricus Arthur Baekeland
November 14, 1863
Sint-Martens-Latem, Belgium
Died February 23, 1944(1944-02-23) (aged 80)
Beacon, New York, USA
Occupation chemist/inventor
Known for plastics research, Bakelite, Novolac
Awards John Scott Medal (1910)
Willard Gibbs Award (1913)
Perkin Medal (1916)[1]
Franklin Medal (1940)

Leo Henricus Arthur Baekeland FRSE(Hon) (November 14, 1863 – February 23, 1944) was a Belgian-born American chemist. He is best known for the inventions of Velox photographic paper in 1893 and Bakelite in 1907. He has been called "The Father of the Plastics Industry"[2]:13 for his invention of Bakelite, an inexpensive, nonflammable, versatile, and popular plastic, which marked the beginning of the modern plastics industry.[3][4]

Early life[edit]

Leo Baekeland was born in Sint-Martens-Latem, Belgium on November 14, 1863,[5] the son of a cobbler and a house maid.[6] He told The Literary Digest: "The name is a Flemish word meaning 'Land of Beacons.'"[7] He spent much of his early life in Ghent, Belgium. He graduated with honours from the Ghent Municipal Technical School and was awarded a scholarship by the City of Ghent[8] to study chemistry at the University of Ghent, which he entered in 1880.[2]:13 He acquired a PhD maxima cum laude at the age of 21.[8] After a brief appointment as Professor of Physics and Chemistry at the Government Higher Normal School in Bruges (1887-1889) he was appointed associate professor of chemistry at Ghent in 1889.[2]:14 Baekeland married Céline Swarts, the daughter of his professor Theodore Swarts and Celine (Platteau) Swarts, on August 8, 1889. They had three children, George, Nina, and Jenny.[9][10]

Career[edit]

In 1889 Baekeland and his wife took advantage of a travel scholarship to visit universities in England and America.[1]:178[2]:14 They visited New York City, where he met Professor Charles F. Chandler of Columbia University and Richard Anthony, of the E. and H.T. Anthony photographic company. Professor Charles F. Chandler of Columbia University was influential in convincing Baekeland to stay in the United States.[11] Baekeland had already invented a process to develop photographic plates using water instead of other chemicals, which he had patented in Belgium in 1887;[2]:13 Anthony saw potential in the young chemist and offered him a job.[12]

Baekeland worked for the Anthony company for two years, and in 1891 set up in business for himself as a consulting chemist. However, a spell of illness and disappearing funds made him rethink his actions and he decided to return to his old interest of producing a photographic paper that would allow enlargements to be printed by artificial light.[13] After two years of intensive effort he perfected the process to produce the paper, which he named "Velox"; it was the first commercially successful photographic paper. At the time the US was suffering a recession and there were no investors or buyers for his proposed new product, so Baekeland became partners with Leonardi Jacobi and established the Nepera Chemical Company in Nepera Park, Yonkers, New York.[12]

In 1899 Jacobi, Baekeland, and Albert Hahn, a further associate, sold Nepera to George Eastman of the Eastman Kodak Co. for $750,000. [14][15] Baekeland earned circa $215,000 net through the transaction. [16]

With a portion of the money he purchased "Snug Rock", a house in Yonkers, New York, where he set up his own well-equipped laboratory. There, he later said, "in comfortable financial circumstances, a free man, ready to devote myself again to my favorite studies... I enjoyed for several years that great blessing, the luxury of not being interrupted in one's favorite work."[17]

One of the requirements of the Nepera sale was, in effect, a non-compete clause: Baekeland agreed not to do research in photography for at least 20 years. He would have to find a new area of research. His first step was to return to Germany in 1900, for a "refresher in electrochemistry" at the Technical Institute at Charlottenburg.[2]:14

Upon returning to the United States, Baekeland was involved briefly but successfully in helping Clinton Paul Townsend and Elon Huntington Hooker to develop a production-quality electrolytic cell. Baekeland was hired as an independent consultant, with the responsiblity of constructing and operating a pilot plant.[8]:138-139 Baekeland developed a stronger diaphragm cell for the chloralkali process, using woven asbestos cloth filled with mixture of iron oxide, asbestos fibre and iron hydroxide. Baekeland's improvements were important to the founding of Hooker Chemical Company and the construction of one of the world's largest electrochemical plants, at Niagara Falls.[2][18][17]

Invention of Bakelite[edit]

Having been successful with Velox, Baekeland set out to find another promising area for chemical development. As he had done with Velox, he looked for a problem that offered "the best chance for the quickest possible results".[17] Asked why he entered the field of synthetic resins, Baekeland answered that his intention was to make money.[11] By the 1900s, chemists had begun to recognize that many of the natural resins and fibers were polymeric, a term introduced in 1833 by Jöns Jacob Berzelius.[19][20] Adolf von Baeyer had experimented with phenols and aldehydes in 1872, particularly Pyrogallol and benzaldehyde.[21] He created a "black guck" which he considered useless and irrelevant to his search for dyes.[22] Baeyer's student, Werner Kleeberg, experimented with phenol and formaldehyde in 1891, but as Baekeland noted "could not crystallize this mess, nor purify it to constant composition, nor in fact do anything with it once produced".[21]

Baekeland began to investigate the reactions of phenol and formaldehyde.[11] He familiarized himself with previous work and approached the field systematically, carefully controlling and examining the effects of temperature, pressure and the types and proportions of materials used.[8]:144-145[2]

The first application that appeared promising was the development of a synthetic replacement for shellac (made from the excretion of lac beetles). Baekeland produced a soluble phenol-formaldehyde shellac called "Novolak" but concluded that its properties were inferior. It never became a market success, but still exists as Novolac.[3]

Baekeland continued to explore possible combinations of phenol and formaldehyde, intrigued by the possibility that such materials could be used in molding. By controlling the pressure and temperature applied to phenol and formaldehyde, he produced his dreamed-of hard moldable plastic: Bakelite.[3] Bakelite was made from phenol, then known as carbolic acid, and formaldehyde. The chemical name of Bakelite is polyoxybenzylmethylenglycolanhydride.[4] In compression molding, the resin is generally combined with fillers such as wood or asbestos, before pressing it directly into the final shape of the product. Baekeland's process patent for making insoluble products of phenol and formaldehyde was filed in July 1907, and granted on December 7, 1909. In February 1909 Baekeland officially announced his achievement at a meeting of the New York section of the American Chemical Society.[23]

In 1917 Baekeland became a professor by special appointment at Columbia University.[24]:87[25] The Smithsonian contains documents from the County of West Chester Court House in White Plains, NY, indicating that he was admitted to U. S. Citizenship on December 16, 1919.[26][27]

In 1922, after patent litigation favorable to Baekeland, the General Bakelite Co., which he had founded in 1910, along with the Condensite Co. founded by Aylesworth, and the Redmanol Chemical Products Co. founded by L.V. Redman, were merged into the Bakelite Corporation.[23]

Colorful buttons made from Catalin, another variety of phenolic resin.

The invention of Bakelite marks the beginning of the age of plastics.[4] Bakelite was the first plastic invented that retained its shape after being heated. Radios, telephones and electrical insulators were made of Bakelite because of its excellent electrical insulation and heat-resistance. Soon its applications spread to most branches of industry.[4]

Baekeland received many awards and honors, including the Perkin Medal in 1916 and the Franklin Medal in 1940.[17] In 1978 he was posthumously inducted into the National Inventors Hall of Fame at Akron, Ohio.[10]

At Baekeland's death in 1944, the world production of Bakelite was ca. 175000tons, and it was used in over 15000 different products. He held more than 100 patents,[17] including processes for the separation of copper and cadmium, and for the impregnation of wood.

Decline and death[edit]

The gravesite of Leo Hendrik Baekeland

As Baekeland got older he became more eccentric, getting into fierce battles with his son and presumptive heir over salary and other issues. He sold the General Bakelite Company to Union Carbide in 1939 and, at his son's prompting, he retired. He became a recluse, eating all of his meals from cans and becoming obsessed with developing an immense tropical garden on his winter estate in Coconut Grove, Florida.[28] He died of a cerebral hemorrhage in a sanatorium in Beacon, New York.[29] Baekeland is buried in Sleepy Hollow Cemetery in Sleepy Hollow, New York.[30]

See also[edit]

References[edit]

Notes
  1. ^ a b "Perkin Medal Award". The Journal of Industrial and Engineering Chemistry 8 (2): 177–190. 1916. Retrieved 1 September 2015. 
  2. ^ a b c d e f g h Landmarks of the Plastics Industry. England: Imperial Chemical Industries Ltd., Plastics Division. 1962. pp. 13–25. 
  3. ^ a b c "Chemical Achievers: Leo Hendrik Baekeland". Chemical Heritage Foundation. 2005. Retrieved 2007-11-08. 
  4. ^ a b c d Amato, Ivan (1999-03-29). "Time 100: Leo Baekeland". Retrieved 2007-11-08. 
  5. ^ Sas, Benedikt; Vocht, Stanislas De; Jacobs, Philippe (2014). Intellectual Property and Assessing its Financial Value. Kidlington: Chandos Publishing. pp. 2–7. ISBN 9781843347927. Retrieved 1 September 2015. 
  6. ^ Gratzer, Walter (2011). Giant molecules : from nylon to nanotubes. Oxford: Oxford University Press. ISBN 978-0199562138. 
  7. ^ Funk & Wagnalls, 1936.
  8. ^ a b c d Bijker, Wiebe E. (1997). "The Fourth Kingdom: The Social Construction of Bakelite". Of bicycles, bakelites, and bulbs : toward a theory of sociotechnical change (1st MIT Press pbk ed.). Cambridge, Mass.: MIT Press. pp. 101–198. ISBN 9780262522274. Retrieved 2 September 2015. 
  9. ^ "Leo Baekeland". NNDB Tracking the entire world. Soylent Communications. Retrieved 1 September 2015. 
  10. ^ a b Flynn, Tom. "Yonkers, Home of the Plastic Age". Retrieved 2 September 2015. 
  11. ^ a b c "Leo Hendrik Baekeland". Chemical Heritage Foundation. Retrieved 2 September 2015. 
  12. ^ a b Gehani, R. Ray (1998). Management of Technology and Operations. John Wiley and Sons. pp. 81–82. ISBN 0-471-17906-X. 
  13. ^ a b Haynes, Williams (1946). "XIX: Materials for To-morrow". This Chemical Age. London: Secker and Warburg. pp. 238–239. 
  14. ^ Jenkins, Reese V. (1975). Images and Enterprise: Technology and the American Photographic Industry, 1839 to 1925. Baltimore, MD: Johns Hopkins University Press. pp. 191–201. ISBN 0801815886. 
  15. ^ Haynes[13] quotes a surprising immediate offer of $1,000,000, when Baekeland had been hoping for $50,000 at most.
  16. ^ Mercelis, Joris (2012). "Leo Baekeland's Transatlantic Struggle for Bakelite: Patenting Inside and Outside of America". Technology and Culture 53 (2): 372. doi:10.1353/tech.2012.0067. 
  17. ^ a b c d e Kettering, Charles Franklin (1946). Biographical memoir of Leo Hendrik Baekeland, 1863-1944. Presented to the academy at the autumn meeting, 1946. (PDF). National Academy of Sciences (U.S.).; Biographical memoirs. p. 206. 
  18. ^ Thomas, Robert E. (1955). Salt & Water, Power & People: A Short History of Hooker Electrochemical Co. Niagara Falls, NY: Hooker Chemical Co. p. 109. ISBN 1258790807. 
  19. ^ Jensen, William B. (2008). "Ask the Historian: The origin of the polymer concept" (PDF). Journal of Chemical Education (University of California) 85: 624–625. 
  20. ^ Westman, M.; Laddha, S.; Fifield, L.; Kafentzis, T.; Simmons, K. "Natural fiber composites: a review" (PDF). Pacific North National Laboratory. Retrieved 2010. 
  21. ^ a b Kaufman, Morris (1963). The first century of plastics; celluloid and its sequel. London: Plastics Institute. pp. 61–69. 
  22. ^ Schwarcz, Joe (2011). Dr. Joe's brain sparks : 179 inspiring and enlightening inquiries into the science of everyday life. Toronto: Anchor Canada. p. 124. ISBN 978-0385669320. Retrieved 2 September 2015. 
  23. ^ a b American Institute of Chemical Engineers Staff (1977). Twenty-Five Years of Chemical Engineering Progress. Ayer Publishing. p. 216. ISBN 0-8369-0149-5. 
  24. ^ Seymour, Raymond B. (1989). "The development of thermosets by Lee Baekeland and other early 20th century chemists". Pioneers in Polymer Science. Dordrecht: Springer Netherlands. ISBN 978-94-009-2407-9. 
  25. ^ "Baekeland0". ugent.be. 
  26. ^ Harding, Robert (1994). "Guide to the Leo H. Baekeland Papers NMAH.AC.0005" (PDF). Smithsonian National Museum of American History. Retrieved 1 September 2015. 
  27. ^ "County of Westchester". sdfsdf. Retrieved 1 September 2015. 
  28. ^ Fairchild, David (1948). The World Grows Round My Door. New York: Charles Scriber's Sons. p. 258. 
  29. ^ "Leo Baekeland Dead, Created Bakelite. Chemist Noted for Invention in Plastics. Produced Velox, a Photographic Paper". New York Times. February 24, 1944. Retrieved 2015-04-14. 
  30. ^ "Leo Hendrik Baekeland (1863 - 1944) - Find A Grave Memorial". findagrave.com. 
Further reading

External links[edit]

Awards and achievements
Preceded by
Seymour Parker Gilbert
Cover of Time Magazine
22 September 1924
Succeeded by
Hiram Johnson