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Cetyl alcohol

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Cetyl alcohol[1]
Names
IUPAC name
Hexadecan-1-ol
Other names
Cetanol, Cetyl alcohol, Ethal, Ethol, Hexadecanol, Hexadecyl alcohol, Palmityl alcohol
Identifiers
3D model (JSmol)
ECHA InfoCard 100.048.301 Edit this at Wikidata
  • CCCCCCCCCCCCCCCCO
Properties
CH3(CH2)15OH
Molar mass 242.44 g/mol
Appearance White crystals
Density 0.811 g/cm³
Melting point 49 °C (120 °F; 322 K)
Boiling point 344 °C (651 °F; 617 K)
Insoluble
Hazards
Flash point 185 °C (365 °F; 458 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Cetyl alcohol, also known as 1-hexadecanol and palmityl alcohol, is a solid organic compound with the chemical formula CH3(CH2)15OH. At room temperature, cetyl alcohol takes the form of a waxy white solid or flakes. It belongs to the group of fatty alcohols.

The name cetyl derives from the whale oil (Latin: cetus) from which it was first isolated.[2]

History

Cetyl alcohol was discovered in 1817 by the French chemist Michel Chevreul when he heated spermaceti, a waxy substance obtained from sperm whale oil, with caustic potash (potassium hydroxide). Flakes of cetyl alcohol were left behind on cooling.[3]

Production

With the demise of commercial whaling, cetyl alcohol is no longer primarily produced from whale oil, but instead either as an end-product of the petroleum industry, or produced from vegetable oils such as palm oil and coconut oil. Production of cetyl alcohol from palm oil gives rise to one of its alternative names, palmityl alcohol.

Uses

Cetyl alcohol is used in the cosmetic industry as a surfactant in shampoos, or as an emollient, emulsifier or thickening agent in the manufacture of skin creams and lotions.[4] It is also employed as a lubricant for nuts and bolts.

References

  1. ^ Merck Index, 11th Edition, 2020.
  2. ^ Nordegren, Thomas (2002). The A-Z Encyclopedia of Alcohol and Drug Abuse. Universal Publishers. p. 165. ISBN 158112404X. {{cite book}}: Cite has empty unknown parameter: |coauthors= (help)
  3. ^ Booth, James Curtis (1862). The Encyclopedia of Chemistry, Practical and Theoretical. p. 429. {{cite book}}: Cite has empty unknown parameter: |coauthors= (help)
  4. ^ Smolinske, Susan C (1992). Handbook of Food, Drug, and Cosmetic Excipients. CRC Press. pp. 75–76. ISBN 084933585X. {{cite book}}: Cite has empty unknown parameter: |coauthors= (help)