Lithium sulfate
Appearance
Names | |
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IUPAC name
Lithium sulfate
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Other names
Lithium sulphate
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Identifiers | |
ECHA InfoCard | 100.030.734 |
PubChem CID
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RTECS number |
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CompTox Dashboard (EPA)
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Properties | |
Li2SO4 | |
Molar mass | 109.94 g/mol |
Appearance | White crystalline solid, hygroscopic |
Density | 2.221 g/cm3 (anhydrous) 2.06 g/cm3 (monohydrate) |
Melting point | 859 °C |
Boiling point | 1377 °C |
monohydrate: 34.9 g/100 mL (25 °C) 29.2 g/100 mL (100 °C) | |
Solubility | insoluble in absolute ethanol, acetone and pyridine |
Refractive index (nD)
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1.465 (β-form) |
Thermochemistry | |
Heat capacity (C)
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1.07 J/g K |
Std enthalpy of
formation (ΔfH⦵298) |
−1436.37 kJ/mol |
Hazards | |
NFPA 704 (fire diamond) | |
Related compounds | |
Other cations
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Sodium sulfate Potassium sulfate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Lithium sulfate is a white inorganic salt with the formula Li2SO4. It is the lithium salt of sulfuric acid.
Properties
Lithium sulfate is soluble in water, though it does not follow the usual trend of solubility versus temperature — its solubility in water decreases with increasing temperature, as its dissolution is an endothermic process. This property is shared with few inorganic compounds, such as the lanthanoid sulfates.
Lithium sulfate crystals, being piezoelectric, are also used in ultrasound-type non-destructive testing because they are very efficient sound generators. However, they do suffer in this application because of their water solubility.
Uses
Lithium sulfate is used to treat bipolar disorder (see lithium pharmacology).
References
- ^ Patnaik, Pradyot (2002). Handbook of Inorganic Chemicals. McGraw-Hill. ISBN 0-07-049439-8.