Jump to content

Rectified spirit: Difference between revisions

From Wikipedia, the free encyclopedia
Browse history interactively
← Previous editNext edit →
Content deleted Content added
VisualWikitext
m fixing CS1 error
→Moonshine: mentioned column still. 95% not 96 (https://onlinelibrary.wiley.com/doi/10.1002/jctb.5040340408). added https://www.scielo.br/j/bjce/a/XnGLp8855JYfV7ckCLvsjzS/?lang=en
Line 39: Line 39:
{{main|Moonshine#Rectified spirit}}
{{main|Moonshine#Rectified spirit}}


A [[Moonshine#Column still|column still]] can achieve a vapor alcohol content of 95%.
⚫
[[Moonshine]] is usually distilled to 40% ABV, and seldom above 66% based on 48 samples.<ref>{{cite journal |last1=Holstege |first1=CP |last2=Ferguson |first2=JD |last3=Wolf |first3=CE |last4=Baer |first4=AB |last5=Poklis |first5=A |title=Analysis of moonshine for contaminants. |journal=Journal of Toxicology. Clinical Toxicology |date=2004 |volume=42 |issue=5 |pages=597–601 |doi=10.1081/clt-200026976 |pmid=15462151|s2cid=97866750 }}</ref> However, [[ethanol]] can be dried to 95% ABV (rectified spirit) with a column of 3A molecular sieves.<ref>{{cite journal |last1=Burfield |first1=David R. |last2=Hefter |first2=Glenn T. |last3=Koh |first3=Donald S. P. |title=Desiccant efficiency in solvent and reagent drying 8. molecular sieve column drying of 95% ethanol: An application of hygrometry to the assay of solvent water content |journal=Journal of Chemical Technology and Biotechnology. Chemical Technology |volume=34 |issue=4 |pages=187–194 |language=en |doi=10.1002/jctb.5040340408 |date=1984}}</ref><ref>{{cite journal |last1=Simo |first1=Marian |last2=Sivashanmugam |first2=Siddharth |last3=Brown |first3=Christopher J. |last4=Hlavacek |first4=Vladimir |title=Adsorption/Desorption of Water and Ethanol on 3A Zeolite in Near-Adiabatic Fixed Bed |journal=Industrial & Engineering Chemistry Research |volume=48 |issue=20 |pages=9247–9260 |doi=10.1021/ie900446v |date=21 October 2009}}</ref>

⚫
Also, conventional [[moonshine]] is usually distilled to 40% ABV, and seldom above 66% based on 48 samples,<ref>{{cite journal |last1=Holstege |first1=CP |last2=Ferguson |first2=JD |last3=Wolf |first3=CE |last4=Baer |first4=AB |last5=Poklis |first5=A |title=Analysis of moonshine for contaminants. |journal=Journal of Toxicology. Clinical Toxicology |date=2004 |volume=42 |issue=5 |pages=597–601 |doi=10.1081/clt-200026976 |pmid=15462151|s2cid=97866750 }}</ref> but the ethanol can be dried to 95% ABV by heating 3A molecular sieves such as 3A [[zeolite]].<ref>{{cite journal |last1=Carmo |first1=M. J. |last2=Gubulin |first2=J. C. |title=ETHANOL-WATER ADSORPTION ON COMMERCIAL 3A ZEOLITES: KINETIC AND THERMODYNAMIC DATA |journal=Brazilian Journal of Chemical Engineering |date=September 1997 |volume=14 |doi=10.1590/S0104-66321997000300004 |url=https://www.scielo.br/j/bjce/a/XnGLp8855JYfV7ckCLvsjzS/?lang=en |language=en |issn=0104-6632}}</ref><ref>{{cite journal |last1=Burfield |first1=David R. |last2=Hefter |first2=Glenn T. |last3=Koh |first3=Donald S. P. |title=Desiccant efficiency in solvent and reagent drying 8. molecular sieve column drying of 95% ethanol: An application of hygrometry to the assay of solvent water content |journal=Journal of Chemical Technology and Biotechnology. Chemical Technology |volume=34 |issue=4 |pages=187–194 |language=en |doi=10.1002/jctb.5040340408 |date=1984}}</ref><ref>{{cite journal |last1=Simo |first1=Marian |last2=Sivashanmugam |first2=Siddharth |last3=Brown |first3=Christopher J. |last4=Hlavacek |first4=Vladimir |title=Adsorption/Desorption of Water and Ethanol on 3A Zeolite in Near-Adiabatic Fixed Bed |journal=Industrial & Engineering Chemistry Research |volume=48 |issue=20 |pages=9247–9260 |doi=10.1021/ie900446v |date=21 October 2009}}</ref>


== See also ==
== See also ==

Revision as of 04:29, 22 July 2021

Rectified spirit made in Poland by Polmos

Rectified spirit, also known as neutral spirits, rectified alcohol, or ethyl alcohol of agricultural origin[1] is highly concentrated ethanol that has been purified by means of repeated distillation in a process called rectification. In some countries, denatured alcohol or denatured rectified spirit may commonly be available as "rectified spirit".

In its undiluted form, it contains at least 55% alcohol by volume (ABV) (110 US proof) in the European Union.[1] The purity of rectified spirit has a practical limit of 95% ABV (95.6% by mass)[2] when produced using conventional distillation processes, as a mixture of ethanol and water becomes a minimum-boiling azeotrope at this concentration. Rectified spirit is typically distilled in continuous multi-column stills at 96–96.5% ABV and diluted as necessary.

Neutral spirits can be produced from grains, corn, grapes, sugar beets, sugarcane, tubers, or other fermented plant materials. In particular, large quantities of neutral alcohol are distilled from wine. A product made from grain is "grain neutral spirit", while a spirit made from grapes is called "grape neutral spirit"[3] or "vinous alcohol".[4] These terms are commonly abbreviated as either GNS or NGS.[5][6][7]

Neutral spirits are used in the production of blended whisky, cut brandy, some liqueurs, and some bitters. As a consumer product, it is almost always mixed with other beverages to create drinks like alcoholic punch or Jello shots or is sometimes added to cocktails in place of vodka or rum.[8] It is also used to make home made liqueurs, such as limoncello or cassis, and in cooking because its high concentration of alcohol acts as a solvent to extract flavors.[9] Rectified spirits are also used for medicinal tinctures and as a household solvent. It is sometimes consumed undiluted; however because the alcohol is very high proof, overconsumption can cause alcohol poisoning more quickly than more traditional distilled spirits.[10]

Regional

Poland

Spirytus Rektyfikowany made by Polmos is the iconic brand with 95% ABV.[11]

United States

Neutral spirit is legally defined as spirit distilled from any material distilled at or above 95% ABV (190 US proof) and bottled at or above 40% ABV.[3] When the term is used in an informal context rather than as a term of U.S. law, any distilled spirit of high alcohol purity (e.g., 170 proof or higher) that does not contain added flavoring may be referred to as neutral alcohol.[12] Prominent brands of neutral spirits sold in the U.S. include:

"Grain spirit" is a legal classification for neutral spirit that is distilled from fermented grain mash and stored in oak containers.[3]

Retail availability

Availability of neutral spirit for retail purchase varies between states.[15][16] States where consumer sales of high-ABV neutral spirit are[when?] prohibited include California,[14] Florida,[17] Hawaii,[14] Maine,[14] Maryland,[14] Massachusetts,[14] Michigan,[14] Minnesota,[18] New Hampshire,[14] Nevada,[19] North Carolina,[20] Ohio,[14] Pennsylvania,[21] Iowa, and West Virginia.[21] In Virginia, the purchase of neutral spirits requires a no-cost "Grain Alcohol Permit", issued "strictly for industrial, commercial, culinary or medicinal use".[22] In 2017, Virginia approved the sale of up to 151 proof neutral spirits at its ABC stores without a permit.[23] Pennsylvania sells 151 proof without a permit but requires one for 190 proof.[24]

Canada

Global 94 %, a 94% ABV rectified spirit, is available in Quebec through SAQ[25] and in Ontario through LCBO.[26]

Germany

In Germany, rectified spirit is generically called Primasprit (colloquial) or, more technically, Neutralalkohol. It is available in pharmacies, bigger supermarkets, and East European markets. In the former East Germany, it was available in regular stores. Primasprit is most often used for making homemade liqueurs; other types of use are rare. Most of the Primasprit produced in Germany is made from grain and is, therefore, a neutral grain spirit.

Norway

The import[27] and sale[28] of spirits containing more than 60% alcohol by volume is prohibited, so only weaker grain spirits are permitted.

Moonshine

Main article: Moonshine § Rectified spirit

A column still can achieve a vapor alcohol content of 95%.

Also, conventional moonshine is usually distilled to 40% ABV, and seldom above 66% based on 48 samples,[29] but the ethanol can be dried to 95% ABV by heating 3A molecular sieves such as 3A zeolite.[30][31][32]

See also

References

  1. ^ a b E.U. Definitions of Categories of Spirit Drinks 110/2008, M(b), 2008
  2. ^ Inge Russell, ed. (2003). Whisky: Technology, Production and Marketing. Graham Stewart. Academic Press. p. 180. ISBN 9780080474854.
  3. ^ a b c 27 CFR 5.22
  4. ^ "Results of sales of vinous alcohol held by public agencies". Official Journal of the European Union. Retrieved November 25, 2018.
  5. ^ David T. Smith (2018). The Gin Dictionary. Octopus Publishing. ISBN 9781784724894. Retrieved May 8, 2019.
  6. ^ "Commercial Alcohols". Greenfield.com. Retrieved May 8, 2019.
  7. ^ Laurel Miller (November 30, 2017). "Getting to the Bottom of What's in Your Glass". EdibleCommunities.com. Retrieved May 8, 2019.
  8. ^ "Drink Recipe Browser: Everclear drinks". Drinknation. 2010. Retrieved 17 November 2010.
  9. ^ Walton, Stuart; Norma Miller (2000). An Encyclopedia of Spirits & Liqueurs and How to Cook with Them. London: Hermes House. ISBN 1-84215-154-1.
  10. ^ Sonja Sharp; Kenneth Lovett (2010). "That's the spirit! State approves 192-proof Spirytus, allowing New Yorkers to get quite the buzz". The Daily News.
  11. ^ "Vodka in Short Supply in Japan as Rubbing Alcohol Sells Out". nippon.com. February 29, 2020.
  12. ^ Lichine, Alexis. Alexis Lichine's New Encyclopedia of Wines & Spirits (New York: Alfred A. Knopf, 1987), 365.
  13. ^ "Neutral Spirits". Luxco official website. Retrieved November 9, 2017.
  14. ^ a b c d e f g h i "Maryland bans grain alcohol". ConsumerAffairs. Retrieved 2018-11-25.
  15. ^ "Report to Congress on the prevention and reduction of underage drinking - Policy summary: High-proof grain alcoholic beverages" (PDF). United States Department of Health and Human Services - Substance Abuse and Mental Health Services Administration. 2017. Retrieved 2019-02-14.
  16. ^ Danae King (30 June 2014). "Laws including high-proof grain alcohol ban take effect Tuesday". The Baltimore Sun. Retrieved 22 December 2018.
  17. ^ 2009 Florida Statutes, Title XXXIV
  18. ^ "2017 Minnesota Statutes: 34A.506 Sales of ethyl alcohol and neutral spirits prohibited". Office of the Revisor of Statutes. Minnesota Legislature. Retrieved November 9, 2017.
  19. ^ "Chapter 202 – Crimes against public health and safety – NRS 202.065 Sale of alcoholic beverage containing more than 80 percent of alcohol by volume". Nevada Legislature. Retrieved November 9, 2017.
  20. ^ "ABC Commission to end sales of 190-proof booze |". watchdogs.blogs.starnewsonline.com. Retrieved 2018-11-25.
  21. ^ a b "Senate Passes Ban Of 190-Proof Alcohol Products". CBS News. Associated Press. February 5, 2014. Retrieved November 9, 2017.
  22. ^ "Get a Permit". www.abc.virginia.gov. Retrieved 2018-11-25.
  23. ^ "Everclear to be legal in Virginia | WTOP". WTOP. 2017-03-07. Retrieved 2018-11-25.
  24. ^ PLCB. "Product Location". www.lcbapps.lcb.state.pa.us. Retrieved 2018-11-25.
  25. ^ "Global 94 % - Univins et Spiritueux". Retrieved 13 March 2020.
  26. ^ ""Global Alcool 94% 1140ml". www.lcbo.com. Retrieved 15 February 2021.
  27. ^ "Alcohol and tobacco quotas". Directorate of Norwegian Customs. Retrieved 26 August 2017.
  28. ^ "Lovdata (in Norwegian)". Retrieved 26 August 2017.
  29. ^ Holstege, CP; Ferguson, JD; Wolf, CE; Baer, AB; Poklis, A (2004). "Analysis of moonshine for contaminants". Journal of Toxicology. Clinical Toxicology. 42 (5): 597–601. doi:10.1081/clt-200026976. PMID 15462151. S2CID 97866750.
  30. ^ Carmo, M. J.; Gubulin, J. C. (September 1997). "ETHANOL-WATER ADSORPTION ON COMMERCIAL 3A ZEOLITES: KINETIC AND THERMODYNAMIC DATA". Brazilian Journal of Chemical Engineering. 14. doi:10.1590/S0104-66321997000300004. ISSN 0104-6632.
  31. ^ Burfield, David R.; Hefter, Glenn T.; Koh, Donald S. P. (1984). "Desiccant efficiency in solvent and reagent drying 8. molecular sieve column drying of 95% ethanol: An application of hygrometry to the assay of solvent water content". Journal of Chemical Technology and Biotechnology. Chemical Technology. 34 (4): 187–194. doi:10.1002/jctb.5040340408.
  32. ^ Simo, Marian; Sivashanmugam, Siddharth; Brown, Christopher J.; Hlavacek, Vladimir (21 October 2009). "Adsorption/Desorption of Water and Ethanol on 3A Zeolite in Near-Adiabatic Fixed Bed". Industrial & Engineering Chemistry Research. 48 (20): 9247–9260. doi:10.1021/ie900446v.


Retrieved from "https://en.wikipedia.org/w/index.php?title=Rectified_spirit&oldid=1034842911"