Biofuel

For articles on specific fuels used in vehicles, see Biogas, Bioethanol, Biobutanol, Biodiesel, and Straight vegetable oil.

Sugar cane can be used as a biofuel.

Biofuel (also called agrofuel) can be broadly defined as solid, liquid, or gas fuel consisting of, or derived from biomass. This article, however, is principally about biofuel used as transportation fuel. Most transportation vehicles require high power density provided by internal combustion engines. These engines require clean burning fuels, which are generally in liquid form, and to a lesser extent, compressed gaseous phase. Liquids are more portable because they have high energy density, and they can be pumped, which makes handling easier. This is why most transportation fuels are liquids.

Non-transportation applications can usually tolerate the low power-density of external combustion engines, that can run directly on less-expensive solid biomass fuel, for combined heat and power. One type of biomass is wood, which has been used for millennia in varying quantities, and more recently is finding increased use. Wood can also be converted to biofuels such as woodgas, methanol or ethanol.

Biofuel is considered a means of reducing greenhouse gas emissions and increasing energy security by providing an alternative to fossil fuels. However, In October 2007, Nobel Laureate Paul Crutzen published findings that the release of Nitrous Oxide (N₂O) from rapeseed oil, and corn (maize), can contribute as much or more to global warming than the fossil fuels they displace. Although, the Crutzen paper goes on to say that crops with less nitrogen demand, such as grasses and woody coppice species have more favorable climate impacts.

Biofuels are used globally. Biofuel industries are expanding in Europe, Asia and the Americas. The most common use for biofuels is automotive transport (for example E10 fuel). Biofuel can be theoretically produced from any (biological) carbon source. The most common by far is photosynthetic plants that capture solar energy. Many different plants and plant-derived materials are used for biofuel manufacture.

The greatest technical challenge is to develop ways to convert biomass energy specifically to liquid fuels. To achieve this, the two most common strategies are:

• To grow sugar crops (sugar cane, and sugar beet), or starch (corn/maize), and then use yeast fermentation to produce ethanol (ethyl alcohol).
• To grow plants that (naturally) produce oils, such as algae, or jatropha. When these oils are heated, their viscosity is reduced, and they can be burned directly in a diesel engine. The oils can also be chemically processed to produce biodiesel.

History and Policy

Humans have used biomass fuels that is, solid biofuels — for heating and cooking since the discovery of fire. Following the discovery of electricity, it became possible to use biofuels to generate electrical power as well. However, the discovery and use of fossil fuels: coal, gas and oil, have dramatically reduced the amount of biomass fuel used in the developed world for transport, heat and power.

Liquid biofuels have been used since the early days of the automobile industry. Nikolaus August Otto, the German inventor of the internal combustion engine, conceived his invention to run on ethanol. Rudolf Diesel, the German inventor of the Diesel engine, designed it to run on peanut oil, and Henry Ford originally designed the Ford Model T, a car produced from 1903 to 1926, to run completely on ethanol. However, when large supplies of crude oil were discovered in Pennsylvania and Texas, petroleum based fuels became inexpensive, and soon were widely used. Cars and trucks began using fuels derived from mineral oil/petroleum: gasoline/petrol or diesel.

Nevertheless, before World War II, and during the high demand wartime period, biofuels were valued as a strategic alternative to imported oil. Wartime Germany experienced extreme oil shortages, and many energy innovations resulted. This include the powering of some of its vehicles using a blend of gasoline with alcohol fermented from potatoes, called Reichskraftsprit. In Britain, grain alcohol was blended with petrol by the Distillers Company Limited under the name Discol and marketed through Esso's affiliate Cleveland.

During the peacetime post-war period, inexpensive oil from the Middle East contributed in part to the lessened economic and geopolitical interest in biofuels. Then in 1973 and 1979, geopolitical conflict in the Middle East caused OPEC to cut exports, and non-OPEC nations experienced a very large decrease in their oil supply. This "energy crisis" resulted in severe shortages, and a sharp increase in high demand oil-based products, notably petrol/gasoline. There was also increased interest from governments and academics in energy issues and biofuels. Throughout history, the fluctuations of supply and demand, energy policy, military conflict, and the environmental impacts, have all contributed to a highly complex and volatile market for energy and fuel.

In the year 2000 and beyond, renewed interest in biofuels has been seen. The drivers for biofuel research and development include rising oil prices, concerns over the potential oil peak, greenhouse gas emissions (causing global warming and climate change), rural development interests, and instability in the Middle East.

Biomass

Main article: Biomass

Biomass is material derived from recently living organisms. This includes plants, animals and their by-products. For example, manure, garden waste and crop residues are all sources of biomass. It is a renewable energy source based on the carbon cycle, unlike other natural resources such as petroleum, coal, and nuclear fuels. Agricultural products specifically grown for biofuel production include corn, switchgrass, and soybeans, primarily in the United States; rapeseed, wheat and sugar beet primarily in Europe; sugar cane in Brazil; palm oil and miscanthus in South-East Asia; sorghum and cassava in China; and jatropha in India. Hemp has also been proven to work as a biofuel. Biodegradable outputs from industry, agriculture, forestry and households can be used for biofuel production, either using anaerobic digestion to produce biogas, or using second generation biofuels; examples include straw, timber, manure, rice husks, sewage, and food waste. The use of biomass fuels can therefore contribute to waste management as well as fuel security and help to prevent climate change, though alone they are not a comprehensive solution to these problems.

Bioenergy from waste

Using waste biomass to produce energy can reduce the use of fossil fuels, reduce greenhouse gas emissions and reduce pollution and waste management problems. A recent publication by the European Union highlighted the potential for waste-derived bioenergy to contribute to the reduction of global warming. The report concluded that 19 million tons of oil equivalent is available from biomass by 2020, 46% from bio-wastes: municipal solid waste (MSW), agricultural residues, farm waste and other biodegradable waste streams.

Landfill sites generate gases as the waste buried in them undergoes anaerobic digestion. These gases are known collectively as landfill gas. This can be burned and is considered a source of renewable energy, even though landfill disposal are often non-sustainable. [Landfill gas (LFG)] can be burned either directly for heat or to generate electricity for public consumption. Landfill gas contains approximately 50 percent methane, the same gas that is found in natural gas.

If landfill gas is not harvested, it escapes into the atmosphere: this is not desirable because methane is a greenhouse gas, with more global warming potential than carbon dioxide. Over a time span of 100 years, methane has a global warming potential of 23 relative to CO₂. Therefore, during this time, one ton of methane produces the same greenhouse gas (GHG) effect as 23 tons of CO₂. When methane burns the formula is CH₄ + 2O₂ = CO₂ + 2H₂O. So by harvesting and burning landfill gas, its global warming potential is reduced a factor of 23, in addition to providing energy for heat and power.

Frank Keppler and Thomas Rockmann discovered that living plants also produce methane CH₄. The amount of methane produced by living plants is 10 to 100 times greater than that produced by dead plants (in an aerobic environment) but does not increase global warming because of the carbon cycle.

Anaerobic digestion can be used as a distinct waste management strategy to reduce the amount of waste sent to landfill and generate methane, or biogas. Any form of biomass can be used in anaerobic digestion and will break down to produce methane, which can be harvested and burned to generate heat, power or to power certain automotive vehicles.

A 3 MW landfill power plant would power 1,900 homes. It would eliminate 6,000 tons per year of methane from getting into the environment. It would eliminate 18,000 tons per year of CO₂ from fossil fuel replacement. This is the same as removing 25,000 cars from the road, or planting 36,000 acres (146 km²) of forest, or not using 305,000 barrels of oil per year.

First generation biofuels

'First-generation fuels' refer to biofuels made from sugar, starch, vegetable oil, or animal fats using conventional technology.

The most common first generation biofuels are listed below.

Vegetable oil

Main article: Vegetable oil used as fuel

Vegetable oil can be used for either food or fuel; the quality of the oil may be lower for fuel use. Vegetable oil can be used in many older diesel engines (equipped with indirect injection systems), but only in warm climates. In most cases, vegetable oil is used to manufacture biodiesel, which is compatible with most diesel engines when blended with conventional diesel fuel. MAN B&W Diesel, Wartsila and Deutz AG offer engines that are compatible with straight vegetable oil. Used vegetable oil is increasingly being processed into biodiesel, and at a smaller scale, cleaned of water and particulates and used as a fuel.

Biodiesel

Main articles: Biodiesel and Biodiesel around the world

Biodiesel is the most common biofuel in Europe. It is produced from oils or fats using transesterification and is a liquid similar in composition to mineral diesel. Its chemical name is fatty acid methyl (or ethyl) ester (FAME). Oils are mixed with sodium hydroxide and methanol (or ethanol) and the chemical reaction produces biodiesel (FAME) and glycerol. 1 part glycerol is produced for every 10 parts biodiesel.

Biodiesel can be used in any diesel engine when mixed with mineral diesel. In some countries manufacturers cover their diesel engines under warranty for 100% biodiesel use, although Volkswagen Germany, for example, asks drivers to make a telephone check with the VW environmental services department before switching to 100% biodiesel (see biodiesel use). Many people have run their vehicles on biodiesel without problems. However, the majority of vehicle manufacturers limit their recommendations to 15% biodiesel blended with mineral diesel. In many European countries, a 5% biodiesel blend is widely used and is available at thousands of gas stations.

In the USA, more than 80% of commercial trucks and city buses run on diesel. Therefore "the nascent U.S. market for biodiesel is growing at a staggering rate—from 25 million gallons per year in 2004 to 78 million gallons by the beginning of 2005. By the end of 2006 biodiesel production was estimated to increase fourfold to more than 1 billion gallons," energy expert Will Thurmond writes in an article for the July-August 2007 issue of THE FUTURIST magazine.

Bioalcohols

Main article: Alcohol fuel

Biologically produced alcohols, most commonly ethanol, and less commonly propanol and butanol, are produced by the action of microorganisms and enzymes through fermentation of sugars or starches (easiest), or celulose (which is more difficult). Biobutanol (also called biogasoline) is often claimed to provide a direct replacement for gasoline, because it can be used directly in a gasoline engine (in a similar way to biodiesel in diesel engines).

Butanol is formed by ABE fermentation (acetone, butanol, ethanol) and experimental modifications of the process show potentially high net energy gains with butanol as the only liquid product. Butanol will produce more energy and allegedly can be burned "straight" in existing gasoline engines (without modification to the engine or car), and is less corrosive and less water soluble than ethanol, and could be distributed via existing infrastructures. DuPont and BP are working together to help develop Butanol.

Ethanol fuel is the most common biofuel worldwide, particularly ethanol fuel in Brazil. Alcohol fuels are produced by fermentation of sugars derived from wheat, corn, sugar beets, sugar cane, molasses and any sugar or starch that alcoholic beverages can be made from (like potato and fruit waste, etc.). The ethanol production methods used are enzyme digestion (to release sugars from stored starches, fermentation of the sugars, distillation and drying. The process requires significant energy input for heat (often unsustainable natural gas fossil fuel).

Cellulosic ethanol production uses non food crops or inedible waste products, which has less of an impact on food. Lignocellulose is the "woody" structural material of plants. This feedstock is abundant and diverse, and in some cases (like citrus peels or sawdust) it is a significant industry-specific disposal problem.

Producing ethanol from cellulose is a more difficult-and-expensive additional-step technical problem to solve. Ruminant livestock (like cattle) eat grass and then use slow enzymatic digestive processes to break it into glucose (sugar). In cellulosic ethanol laboratories, various experimental processes are being used to do the same thing, and then do the above process to make ethanol fuel.

Some scientists have expressed concern that if experimental recombinant DNA genetic engineering continues to be used to develop unprecedented enzymes that break down wood much faster than in nature, such microscopic life forms may accidentally be released into nature, grow exponentially, be distributed by the wind, and eventually destroy the structure of all trees, ending all Earthly life that breathes oxygen released by photosynthesis in trees. The probably of this happening is thought to be extremely small, but it is based on the very-real possibility of human error, doing things that have never been done before in nature (conceptually similar to 20th century nuclear power plant accidents, which were very rare, but still significant). Cellulosic ethanol experiments are not without risk.

Ethanol can be used in petrol engines as a replacement for gasoline; it can be mixed with gasoline to any percentage. Most petrol engines can run on blends of up to 15% bioethanol with petroleum/gasoline, but ethanol is very corrosive to fuel systems, rubber hoses-and-gaskets, aluminum, and combustion chambers. It is therefore illegal to use fuels containing alcohol in aircraft. Ethanol is incompatible with marine fiberglass fuel tanks. For higher ethanol percentage blends, and 100% ethanol vehicles, engine modifications are required.

Corrosive ethanol cannot be transported in petroleum pipelines, so more-expensive over-the-road stainless-steel tank trucks increase the cost, and energy consumption, required to deliver ethanol to the customer at the pump. When considering the total energy consumed by farm equipment, cultivation, planting, fertilizers and herbicides from petroleum, irrigation systems, harvesting, transport of feedstock to processing plants, fermentation, distillation, drying, and transport to fuel terminals and retail pumps, the net energy content value added and delivered to consumers is very small. And, the net benefit does little to reduce unsustainable imported oil and fossil fuels required to produce the ethanol.

Many car manufacturers are now producing flexible-fuel vehicles (FFV's), which can safely run on any combination of bioethanol and petrol, up to 100% bioethanol. They dynamically sense exhaust oxygen content, and adjust the engine's computer systems, spark, and fuel injection accordingly. This adds initial cost and ongoing increased vehicle maintenance. Efficiency falls and pollution emissions increase when FFV system maintenance is needed (regardless of the 0%-to-100% ethanol mix being used), but not performed (as with all vehicles). FFV internal combustion engines are becoming increasingly complex, as are multiple-propulsion-system FFV hybrid vehicles, which impacts cost, maintenance, reliability, and useful lifetime longevity.

Alcohol mixes with both petroleum and with water, so ethanol fuels are often diluted after the drying process by absorbing environmental moisture from the atmosphere. Water in alcohol-mix fuels reduces efficiency, makes engines harder to start, causes intermittent operation (sputtering), and oxidizes aluminum (carburetors) and steel components (rust).

Even dry ethanol has roughly one-third lower energy content per unit of volume compared to gasoline, so larger / heavier fuel tanks are required to travel the same distance, or more fuel stops are required. With large current un-sustainable, non-scalable subsidies, ethanol fuel still costs much more per unit of distance traveled than current high gasoline prices.

Methanol is currently produced from natural gas, a non-renewable fossil fuel. It can also be produced from biomass as biomethanol. The methanol economy is an interesting alternative to the hydrogen economy, compared to today's hydrogen produced from natural gas, but not hydrogen production directly from water and state-of-the-art clean solar thermal energy processes.

BioGas

Main article: biogas

Biogas is produced by the process of anaerobic digestion of organic material by anaerobes. It can be produced either from biodegradable waste materials or by the use of energy crops fed into anaerobic digesters to supplement gas yields. The solid byproduct, digestate, can be used as a biofuel or a fertilizer.

Biogas contains methane and can be recovered from industrial anaerobic digesters and mechanical biological treatment systems. Landfill gas is a less clean form of biogas which is produced in landfills through naturally occurring anaerobic digestion. If it escapes into the atmosphere it is a potent greenhouse gas.

Oils and gases can be produced from various biological wastes:

• Thermal depolymerization of waste can extract methane and other oils similar to petroleum.
• GreenFuel Technologies Corporation developed a patented bioreactor system that uses nontoxic photosynthetic algae to take in smokestacks flue gases and produce biofuels such as biodiesel, biogas and a dry fuel comparable to coal.

Solid Biofuels

Examples include wood, charcoal, and dried manure.

Second generation biofuels

Main article: Second generation biofuels

Supporters of biofuels claim that a more viable solution is to increase political and industrial support for, and rapidity of, second-generation biofuel implementation from non food crops, including cellulosic biofuels. Second-generation biofuel production processes can use a variety of non food crops. These include waste niomass, the stalks of wheat, corn, wood, and special-energy-or-biomass crops (e.g. Miscanthus).

Second generation (2G) biofuels use biomass to liquid technology, including cellulosic biofuels from non food crops.

The following second generation biofuels are under development:

• Biohydrogen
• Bio-DME
• Biomethanol
• DMF
• HTU diesel
• Fischer-Tropsch diesel
• Mixed Alcohols (i.e., mixture of mostly ethanol, propanol and butanol, with some pentanol, hexanol, heptanol and octanol)

Bio-DME, Fischer-Tropsch, BioHydrogen diesel, Biomethanol and Mixed Alcohols all use syngas for production. This syngas is produced by gasification of biomass, however, it can be produced much easier from coal or natural gas, which is done on very large scales in power plants and in gas-to-liquid processes. HTU (High Temperature Upgrading) diesel is produced from particularly wet biomass stocks using high temperature and pressure to produce an oil.

Biohydrogen is the same as hydrogen except it is produced from a biomass feedstock. This is done using gasification of the biomass and then reforming the methane produced, or alternatively, this might be accomplished with some organisms that produce hydrogen directly under certain conditions. BioHydrogen can be used in fuel cells to produce electricity.

DMF. Recent advances in producing DMF from fructose and glucose using catalytic biomass-to-liquid process have increased its attractiveness.

Bio-DME is the same as DME but is produced from a bio-sources. Bio-DME can be produced from Biomethanol using catalytic dehydration or it can be produced from syngas using DME synthesis. DME can be used in the compression ignition engine.

Biomethanol is the same as methanol but it is produced from biomass. Biomethanol can be blended with petrol up to 10-20% without any infrastructure changes.

HTU diesel is produced from wet biomass. It can be mixed with fossil diesel in any percentage without need for infrastructure.

Fischer-Tropsch diesel (FT) diesel is produced using the Fischer-Tropsch gas-to-liquids technology. FT diesel can be mixed with fossil diesel at any percentage without need for infrastructure change.

Mixed alcohols are produced from syngas with catalysts similar to those used for methanol. Most R&D in this area is concentrated in producing mostly ethanol. However, some fuels are marketed as mixed alcohols (see Ecalene). Mixed alcohols are superior to pure methanol or ethanol, in that the higher alcohols have higher energy content. Also, when blending, the higher alcohols increase compatibility of gasoline and ethanol, which increases water tolerance and decreases evaporative emissions. In addition, higher alcohols have also lower heat of vaporization than ethanol, which is important for cold starts. (For another method for producing mixed alcohols from biomass see bioconversion of biomass to mixed alcohol fuels)

Wood diesel A new biofuel was developed by the University of Georgia from wood chips. The oil is extracted and then added to unmodified diesel engines. Either new plants are used or planted to replace the old plants. The charcoal byproduct is put back into the soil as a fertilizer. According to the director Tom Adams since carbon is put back into the soil, this biofuel can actually be carbon negative not just carbon neutral. Carbon negative decreases carbon dioxide in the air reversing the greenhouse effect not just reducing it.

Third generation biofuels

Main article: Algae fuel

Algae fuel, also called oilgae or third generation biofuel, is a biofuel from algae. Algae are low-cost/high-yield (30 times more energy per acre than land) feedstocks to produce biofuels and algae fuel are biodegradable:

• With the higher prices of oil, there is much interest in algaculture (farming algae).

• One advantage of many biofuels over most other fuel types is that they are biodegradable, and so relatively harmless to the environment if spilled.

• The United States Department of Energy estimates that if algae fuel replaced all the petroleum fuel in the United States, it would require 15,000 square miles (38,849 square kilometers), which is a few thousand miles larger than Maryland.

Efforts and promotion

Recognizing the importance of implementing bioenergy, there are international organizations such as IEA Bioenergy, established in 1978 by the OECD International Energy Agency (IEA), with the aim of improving cooperation and information exchange between countries that have national programs in bioenergy research, development and deployment.

The U.N. International Biofuels Forum is formed by Brazil, China, India, South Africa, the United States and the European Commission.

The world leaders in biofuel development and use are Brazil, United States, France, Sweden and Germany.

Asia

In China, the government is making E10 blends mandatory in five provinces that account for 16% of the nation's passenger cars. In Southeast Asia, Thailand has mandated an ambitious 10% ethanol mix in gasoline starting in 2007. For similar reasons, the palm oil industry plans to supply an increasing portion of national diesel fuel requirements in Malaysia and Indonesia.

India

Main article: Biofuels in India

In India, a bioethanol program calls for E5 blends throughout most of the country targeting to raise this requirement to E10 and then E20.

Canada

In Canada, the government aims for 45% of the country’s gasoline consumption to contain 10% ethanol by 2010.

Europe

The European Union in its biofuels directive (updated 2006) has set the goal that for 2010 that each member state should achieve at least 5.75% biofuel usage of all used traffic fuel. By 2020 the figure should be 10%. As of January 2008 these aims are being reconsidered in light of certain environmental and social concerns associated with biofuels such as rising food prices and deforestation.

France is the second largest biofuel consumer among the EU States in 2006. According to the Ministry of Industry, France's consumption increased by 62.7% to reach 682,000 toe (i.e. 1.6% of French fuel consumption). Biodiesel represents the largest share of this (78%, far ahead of bioethanol with 22%). The unquestionable biodiesel leader in Europe is the French company Diester Industrie. In bioethanol, the French agro-industrial group Téréos is increasing its production capacities. Germany itself remained the largest European biofuel consumer, with a consumption estimate of 2.8 million tons of biodiesel (equivalent to 2,408,000 toe), 0.71 million ton of vegetable oil (628.492 toe) and 0.48 million ton of bioethanol (307,200 toe).

The biggest biodiesel German company is ADM Oelmühle Hamburg AG, which is a subsidiary of the American group Archer Daniels Midland Company. Among the other large German producers, MUW (Mitteldeutsche Umesterungswerke GmbH & Co KG) and EOP Biodiesel AG. A major contender in terms of bioethanol production is the German sugar corporation, Südzucker.

The Spanish group Abengoa, via its American subsidiary Abengoa Bioenergy, is the European leader in production of bioethanol.

In the united kingdom the Renewable Transport Fuel Obligation (RTFO) (announced 2005) is the requirement that by 2010 5% of all road vehicle fuel is renewable. In 2008 a critical report by the Royal Society stated that biofuels risk failing to deliver significant reductions in greenhouse gas emissions from transport and could even be environmentally damaging unless the Government puts the right policies in place.

Sweden

Main article: Biofuel in Sweden

The government in Sweden has together with BIL Sweden, the national association for the automobile industry, that are the automakers in Sweden started the work to end oil dependency. One-fifth of cars in Stockholm can run on alternative fuels, mostly ethanol fuel. Also Stockholm will introduce a fleet of Swedish-made hybrid ethanol-electric buses. In 2005, oil phase-out in Sweden by 2020 was announced.

South America

Colombia mandates the use of 10% ethanol in all gasoline sold in cities with populations exceeding 500,000. In Venezuela, the state oil company is supporting the construction of 15 sugar cane distilleries over the next five years, as the government introduces a E10 (10% ethanol) blending mandate.

Brazil

Main article: Biofuel in Brazil

In Brazil, the government hopes to build on the success of the Proálcool ethanol program by expanding the production of biodiesel which must contain 2% biodiesel by 2008, increasing to 5% by 2013.

USA

Main article: Biofuel in the United States

A senior member of the House Energy and Commerce Committee Congressman Fred Upton has introduced legislation to use at least E10 fuel by 2012 in all cars in the USA.

General Motors is starting a project to produce E85 fuel from cellulose ethanol for a projected cost of $1 a gallon. The raw materials can be as simple as corn stalks and scrap petroleum-based vehicle tires, but used tires are an expensive feedstock with other more-valuable uses.

Michigan State University researcher Bruce Dale says that 30% of USA’s energy can be achieved by 2030.

The greenhouse gas emissions are reduced by 86% for cellulose compared to corn’s 29% reduction.

A plant is now being built in Georgia to make up to 100 million gallons per year.

In 2006, the United States president George W. Bush said in a State of the Union speech that the US is "addicted to oil" and should replace 75% of imported oil by 2025 by alternative sources of energy including biofuels.

The 2007-12-19 U.S. Energy Independence and Security Act of 2007 requires American “fuel producers to use at least 36 billion gallons of biofuel in 2022. This is nearly a fivefold increase over current levels.” This is causing a significant agricultural resource shift away from food production to biofuels. American food exports have decreased (increasing grain prices worldwide), and US food imports have increased significantly.

Most biofuels are not currently cost-effective without significant subsidies. "America's ethanol programme is a product of government subsidies. There are more than 200 different kinds, as well as a 54 cents-a-gallon tariff on imported ethanol. That keeps out greener Brazilian ethanol, which is made from sugar rather than maize. Federal subsidies alone cost $7 billion a year (equal to around $1.90 a gallon)."

The appropriateness of the Bush administration energy policy and the extent to which it addresses the energy issues mentioned, is considered highly controversial among many citizens of the United States and by many scientists of other countries, such as by those who have ratified the Kyoto protocol.

Biofuels in developing countries

Biofuel industries are becoming established in many developing countries. Many developing countries have extensive biomass resources that are becoming more valuable as demand for biomass and biofuels increases. The approaches to biofuel development in different parts of the world varies. Countries such as India and China are developing both bioethanol and biodiesel programs. India is extending plantations of jatropha, an oil-producing tree that is used in biodiesel production. The Indian sugar ethanol program sets a target of 5% bioethanol incorporation into transport fuel. China is a major bioethanol producer and aims to incorporate 15% bioethanol into transport fuels by 2010. Costs of biofuel promotion programs can be very high, though.

Amongst rural populations in developing countries, biomass provides the majority of fuel for heat and cooking. Wood, animal dung and crop residues are commonly burned. Figures from the International Energy Agency show that biomass energy provides around 30% of the total primary energy supply in developing countries; over 2 billion people depend on biomass fuels as their primary energy source.

The use of biomass fuels for cooking indoors is a source of health problems and pollution. 1.3 million deaths were attributed to the use of biomass fuels with inadequate ventilation by the International Energy Agency in its World Energy Outlook 2006. Proposed solutions include improved stoves and alternative fuels. However, fuels are easily damaged, and alternative fuels tend to be expensive. People in developing countries are unlikely to be able to afford to put these solutions in place. Organizations such as Intermediate Technology Development Group work to make improved facilities for biofuel use and better alternatives accessible to those who cannot get them.

Current issues in biofuel production and use

Biofuels can provide benefits including: reduction of greenhouse gas emissions, reduction of fossil fuel use, increased national energy security, increased rural development and a sustainable fuel supply for the future.

However, biofuels have limitations. The feedstocks for biofuel production must be replaced rapidly and biofuel production processes must be designed and implemented so as to supply the maximum amount of fuel at the cheapest cost, while providing maximum environmental benefits. Broadly speaking, first generation biofuel production processes cannot supply us with more than a few percent of our energy requirements sustainably. The reasons for this are described below. Second generation processes can supply us with more biofuel, with better environmental gains. The major barrier to the development of second generation biofuel processes is their capital cost: establishing second generation biodiesel plants has been estimated at €500million.

Collocation

Collocation of synergistic processing plants can enhance efficiency. One example is to use the exhaust heat from an industrial process for ethanol production, which can then recycle cooler processing water, instead of evaporating hot water that warms the atmosphere.[3]

Carbon emissions

Biofuels and other forms of renewable energy aim to be carbon neutral. This means that the carbon released during the use of the fuel, e.g. through burning to power transport or generate electricity, is reabsorbed and balanced by the carbon absorbed by new plant growth. These plants are then harvested to make the next batch of fuel. Carbon neutral fuels lead to no net increases in human contributions to atmospheric carbon dioxide levels, reducing the human contributions to global warming.

In practice, biofuels are not carbon neutral. This is because energy is required to grow crops and process them into fuel. Examples of energy use during the production of biofuels include: fertilizer manufacture, fuel used to power machinery, and fuel used to transport crops and fuels to and from biofuel processing plants. The amount of fuel used during biofuel production has a large impact on the overall greenhouse gas emissions savings achieved by biofuels.

A 2007 study by scientists from Britain, U.S., Germany, Switzerland and including Professor Paul Crutzen, who won a Nobel Prize for his work on ozone, have reported that measurements of emissions from the burning of biofuels derived from rapeseed and corn have been found to produce more greenhouse gas emissions than they save. The advantages of reduced carbon dioxide emissions are more than offset by increased nitrous oxide emissions. Nitrous oxide is both a potent greenhouse gas and a destroyer of atmospheric ozone.

The claim that biofuels result in emissions savings has also been critiqued on the grounds that it overlooks the 'displacement' effects of large-scale biofuel production, in terms of its direct and indirect role in promoting land use changes and soil carbon losses.

The carbon emissions (Carbon footprint) produced by biofuels are calculated using a technique called Life Cycle Analysis (LCA). This uses a "cradle to grave" or "well to wheels" approach to calculate the total amount of carbon dioxide and other greenhouse gases emitted during biofuel production, from putting seed in the ground to using the fuel in cars and trucks. Many different LCAs have been done for different biofuels, with widely differing results. The majority of LCA studies show that biofuels provide significant greenhouse gas emissions savings when compared to fossil fuels such as petroleum and diesel. Therefore, using biofuels to replace a proportion of the fossil fuels that are burned for transportation can reduce overall greenhouse gas emissions.

This does assume however that the land used for growing the crops would alternatively be desert or paved area. If the land was previously a (tropical rain-) forest, the carbon absorption of this forest should be deducted from the greenhouse gas savings. This implies that the net effect of burning bio-fuels is an increase in greenhouse gasses. This effect should be incorporated in the LCA, to get a proper overview of the total net effect. Using waste material from plantation forests on previous agricultural land could be carbon positive, due to the carbon stored below ground in the root systems.

The well-to-wheel analysis for biofuels has shown that first generation biofuels can save up to 60% carbon emission and second generation biofuels can save up to 80% as opposed to using fossil fuels. However these studies do not take into account emissions from nitrogen fixation, deforestation, land use, or any indirect emissions.

In 2006, a UK Government study showed that carbon emissions were reduced between 50% and 60% when biofuels were used in conjunction with other fuels such as petrol and diesel.

Rising food prices/the "food vs. fuel" debate

Due to government subsidies, and rising demand for biofuels, farmers worldwide have an increased economic incentive to grow crops for biofuel production instead of food production. Without political intervention, this could lead to reduced food production and increased food prices and inflation. The impacts of this would be greatest on poorer countries, a concern was expressed by Oxfam in 2007.

Reports in 2007 linked stories as diverse as food riots in Mexico due to rising prices of corn for tortillas, and reduced profits at Heineken the large international brewer, to the increasing use of corn (maize) grown in the US Midwest for bio-ethanol production. (In the case of beer, the barley area was cut in order to increase corn production. Barley is not currently used to produce bioethanol.

Environmental campaigner George Monbiot has argued in the British newspaper The Guardian for a 5-year freeze on biofuels while their impact on poor communities and the environment is assessed. One problem with this approach is that economic drivers are required in order to push through the development of more sustainable second-generation biofuel processes: these will be stalled if biofuel production decreases.

A recent UN report on biofuel also raises issues regarding food security and biofuel production. Jean Ziegler, the UN Special Rapporteur on food, concluded that while the argument for biofuels in terms of energy efficiency and climate change are legitimate, the effects for the world's hungry of transforming wheat and maize crops into biofuel are "absolutely catastrophic," and terms such use of arable land a "crime against humanity." Ziegler also calls for a 5-year moratorium on biofuel production. Food surpluses exist in many developed countries. For example, the UK wheat surplus was around 2 million tonnes in 2005. This surplus alone could produce sufficient bioethanol to replace around 2.5% of the UK's petroleum consumption, without requiring any increase in wheat cultivation or reduction in food supply or exports. However, above a few percent, there would be direct competition between first generation biofuel production and food production. This is one reason why many view second-generation biofuel production processes as increasingly important.

Biofuels can also be produced from the waste byproducts of food-based agriculture (such as citrus peels or used vegetable oil ) to manufacture an environmentally sustainable fuel supply, and reduce waste disposal cost. Collocation of a waste generator with a waste-to-ethanol plant can reduce the waste producer's operating cost, while creating a more-profitable ethanol production business. This innovative collocation concept is sometimes called holistic systems engineering. Collocation disposal elimination may be one of the few cost-effective, environmentally-sound, biofuel strategies, but its scalability is limited by availability of appropriate waste generation sources. For example, millions of tons of wet Florida-and-California citrus peels cannot supply billions of gallons of biofuels. Due to the higher cost of transporting ethanol, it is a local partial solution, at best.

Ethanol from sugar cane works in Brazil because they have an equatorial year-round growing season, and the Amazon River – world’s largest fresh water supply. Sugar cane is easier to convert to ethanol than cellulosic feedstock. Other locations with snow on the ground part of the year, short growing seasons, and limited fresh water supplies are less effective. Growing crops (such as high-yield thirsty genetically-engineered corn) can require significant irrigation, when overpopulation has already caused a serious global water crisis. The major aspects of the water crisis are overall scarcity of usable water and water pollution.

Ethanol fuel production consumes large quantities of unsustainable petroleum and natural gas. Even with the most-optimistic energy return on investment claims, in order to use 100% solar energy to grow corn and produce ethanol (fueling farm-and-transportation machinery with ethanol, distilling with heat from burning crop residues, using no fossil fuels), the consumption of ethanol fuel to replace current U.S. petroleum use alone would require about 75% of all cultivated land on the face of the Earth, with no ethanol available for other countries, or sufficient food and water for humans and animals. Scientists at the Paris Global Science Forum Conference on Scientific Challenges for Energy Research believe that many biofuels are therefore non-scalable non-solutions to our current worldwide energy crisis.

Soil Erosion, Deforestation, and Biodiversity

It is important to note that carbon compounds in waste biomass that is left on the ground are consumed by other microorganisms. They break down biomass in the soil to produce valuable nutrients that are necessary for future crops. On a larger scale, plant biomass waste provides small wildlife habitat, which in turn ripples up through the food chain. The widespread human use of biomass (which would normally compost the field) would threaten these organisms and natural habitats. When cellulosic ethanol is produced from feedstock like switchgrass and saw grass, the nutrients that were required to grow the lignocellulose are removed and cannot be processed by microorganisms to replenish the soil nutrients. The soil is then of poorer quality. Loss of ground cover root structures accelerates unsustainable soil erosion.

Significant areas of native Amazon rainforest have been cleared by slash and burn techniques to make room for sugar cane production, which is used in large part for ethanol fuel in Brazil, and growing ethanol exports. Large-scale deforestation of mature trees (which help remove CO₂ through photosynthesis - much better than does sugar cane or most other biofuel feedstock crops do) contributes to un-sustainable global warming atmospheric greenhouse gas levels, loss of habitat, and a reduction of valuable biodiversity.

A portion of the biomass should be retained onsite to support the soil resource. Normally this will be in the form of raw biomass, but processed biomass is also an option. If the exported biomass is used to produce syngas, the process can be used to co-produce biochar, a low-temperature charcoal used as a soil amendment to increase soil organic matter to a degree not practical with less recalcitrant forms of organic carbon. For co-production of biochar to be widely adopted, the soil amendment and carbon sequestration value of co-produced charcoal must exceed its net value as a source of energy.

Biofuel prices

Retail, at the pump prices, including U.S. subsidies, Federal and state motor taxes, B2/B5 prices for low-level Biodiesel (B2-B5) are lower than petroleum diesel by about 12 cents, and B20 blends are the same per unit of volume as petrodiesel.

Due to the 1/3 lower energy content of ethanol fuel, even the heavily-subsidized net cost to drive a specific distance in flexible-fuel vehicles is higher than current gasoline prices.

Poverty reduction

Researchers at the Overseas Development Institute have argued that biofuels could help to reduce poverty in the developing world, through increased employment, wider economic growth multipliers and energy price effects. However, this potential is described as 'fragile', and is reduced where feedstock production tends to be large scale, or causes pressure on limited agricultural resources: capital investment, land, water, and the net cost of food for the poor.

With regards to the potential for poverty reduction or exacerbation, biofuels rely on many of the same policy, regulatory or investment shortcomings that impede agriculture as a route to poverty reduction. Since many of these shortcomings require policy improvements at a country level rather than a global one, they argue for a country-by-country analysis of the potential poverty impacts of biofuels. This would consider, among other things, land administration systems, market coordination and prioritising investment in biodiesel, as this 'generates more labour, has lower transportation costs and uses simpler technology'.

Energy efficiency and energy balance of biofuels

Production of biofuels from raw materials requires energy (for farming, transport and conversion to final product as well as the production of fertilizers, pesticides and herbicides). The level of energy expenditure varies by location: more intensive agricultural regimes such as those found in Western countries are more energy intensive. The more machinery is used for farming, the greater the energy expended in the process; developing countries tend to have less intensive agricultural methods. It is possible to produce biomass without incurring large agricultural energy costs: for example, wild-harvesting excess wood from established forests can be done without much energy input. However the yield of biomass from such resources is not consistent or large enough to support biofuel manufacture on a large scale.

The energy balance of a biofuel is determined by the amount of energy put into the manufacture of fuel compared to the amount of energy released when it is burned in a vehicle and some biofuels can produce up to 2–36 times the input rate of fossil fuels. Biofuels tend to require higher energy inputs per unit energy than fossil fuels: oil can be pumped out of the ground and processed more efficiently than biofuels can be grown and processed. However, this is not necessarily a reason to use oil instead of biofuels, nor does it have an impact on the environmental benefits provided by a given biofuel.

Other factors connected to energy balance are a) cost and b) environmental impact. High energy impacts do not necessarily mean that the resulting fuel will be bad for the environment: energy can be derived from renewable resources to power biofuel manufacture.

Energy balance is not necessarily a measure of a good biofuel. Biofuels should be affordable, sustainable, abundant and provide good GHG emissions savings when compared with fossil fuels.

Energy balance/ efficiency of conversion is relevant when considering how best to use a given amount of biomass resources. For example, given limited resources should biomass be converted into heat and power or liquid transport fuels? Looking at energy balance and the efficiency of energy conversion can help to use biomass resources efficiently and with maximum environmental gain.

Studies have been done that calculate energy balances for biofuel production. Some of these show large differences depending on the biomass feedstock used and location.

The energy balance is more favourable for biofuels made from crops grown in subtropical or tropical areas than those made from crops grown in temperate areas. This is largely due to the increased yield of biomass from crops in areas that receive more sunlight.

Life cycle assessments of biofuel production show that under certain circumstances, biofuels produce only limited savings in energy and greenhouse gas emissions. Fertiliser inputs and transportation of biomass across large distances can reduce the GHG savings achieved. The location of biofuel processing plants can be planned to minimize the need for transport, and agricultural regimes can be developed to limit the amount of fertiliser used for biomass production. A European study on the greenhouse gas emissions found that well-to-wheel (WTW) CO₂ emissions of biodiesel from seed crops such as rapeseed could be almost as high as fossil diesel. It showed a similar result for bio-ethanol from starch crops, which could have almost as many WTW CO₂ emissions as fossil petrol. This study showed that second generation biofuels have far lower WTW CO₂ emissions.

Other independent LCA studies show that biofuels save around 50% of the CO₂ emissions of the equivalent fossil fuels. This can be increased to 80-90% GHG emissions savings if second generation processes or reduced fertiliser growing regimes are used. Further GHG savings can be achieved by using by-products to provide heat, such as using bagasse to power ethanol production from sugarcane.

Environmental effects

Some mainstream environmental groups support biofuels as a significant step toward slowing or stopping global climate change. However, biofuel production can threaten the environment if it is not done sustainably. This finding has been backed by reports of the UN, the IPCC, and some other smaller environmental and social groups as the EEB and the Bank Sarasin, which generally remain negative about biofuels.

As a result, governmental and environmental organisations are turning against biofuels made at a non-sustainable way (hereby preferring certain oil sources as jatropha and lignocellulose over palm oil) and are asking for global support for this.

Also, besides supporting these more sustainable biofuels, environmental organisations are redirecting to new technologies that do not use internal combustion engines such as hydrogen and compressed air.

Biofuels produce greenhouse gas emissions during their manufacture. The source of these emissions are: fertilisers and agricultural processing, transportation of the biomass, processing of the fuels, and transport and delivery of biofuels to the consumer. Some biofuel production processes produce far fewer emissions than others; for example sugar cane cultivation requires fewer fertiliser inputs than corn cultivation, therefore sugar cane bioethanol reduces greenhouse gas emissions more effectively than corn derived bioethanol. However, given the appropriate agricultural techniques and processing strategies, biofuels can provide emissions savings of at least 50% when compared to fossil fuels such as diesel and petroleum.

The increased manufacture of biofuels will require increasing land areas to be used for agriculture. Second generation biofuel processes can ease the pressure on land, because they can use waste biomass, and existing (untapped) sources of biomass such as crop residues and potentially even marine algae.

In some regions of the world, a combination of increasing demand for food, and increasing demand for biofuel, is causing deforestation and threats to biodiversity. The best reported example of this is the expansion of oil palm plantations in Malaysia and Indonesia, where rainforest is being destroyed to establish new oil palm plantations. It is an important fact that 90% of the palm oil produced in Malaysia is used by the food industry; therefore biofuels cannot be held solely responsible for this deforestation. There is a pressing need for sustainable palm oil production for the food and fuel industries; palm oil is used in a wide variety of food products. The Roundtable on Sustainable Biofuels is working to define criteria, standards and processes to promote sustainably produced biofuels. Palm oil is also used in the manufacture of detergents, and in electricity and heat generation both in Asia and around the world (the UK burns palm oil in coal-fired power stations to generate electricity).

Significant area is likely to be dedicated to sugar cane in future years as demand for ethanol increases worldwide. The expansion of sugar cane plantations will place pressure on environmentally-sensitive native ecosystems including rainforest in South America. In forest ecosystems, these effects themselves will undermine the climate benefits of alternative fuels, in addition to representing a major threat to global biodiversity.

Although biofuels are generally considered to improve net carbon output, biodiesel and other fuels do produce local air pollution, including nitrogen oxides, the principal cause of smog.

See also

Category:Biofuels by country Algaculture and algology Anaerobic digestion Biobutanol, a direct biofuel that replaces gasoline. Biodiesel Biogas and Biogas powerplant Bioheat, a biofuel blended with heating oil. Biohydrogen Biomass to liquid bio-oil Ecological sanitation and biogas. Energy content of biofuel

Gasification Hybrid vehicle List of vegetable oils section on oils used as biodiesel Low-carbon economy Straight vegetable oil United Nations Environment Programme (UNEP) Vegetable oil economy Waste vegetable oil Energy crop Energy density Energy Policy Act of 2005 Energy security

External links

Governmental & quasi-governmental

• International Panel for Sustainable Resource Management (UN).
• UN International Biofuels Forum.
• Goverments must take the lead on use of biofuels, says UN Secretary-General.
• U.S. Renewable Fuel Standard (EPA).
• Annual Biofuel progress reports of all EU member states
• Alternative Fuel Price Report.
• NNFCC: The UK's National Centre for biofuels and renewable technologies
• "Biomass as Feedstock for a Bioenergy and Bioproducts Industry", a 2005 joint study sponsored by the United States Department of Energy and Department of Agriculture

Academic & media

• Biofuel Boom: Greenwashing and Crimes Against Humanity, Deconstructing Dinner (Radio)
• Biofuels for Transportation, André L. Boehman and Robert L. McCormick
• The Potential of Bagasse-Based Cogeneration in the US, Kevin Ho, Columbia University, 2006.
• If we want to save the planet, we need a five-year freeze on biofuels, George Monbiot, The Guardian, March 29, 2007.
• Foodstuff as Imperial Weapon: Biofuels and Global Hunger, Fidel Castro, Counterpunch, March 31, 2007.
• Biofuels and bio-lubricants', Biofuels and bio-lubricants a growing business, 18 June 2007.
• Biofuels and the Prospect of Converting Plant Fibres into Gasoline Using Enzymes — A Review from the Science Creative Quarterly, January 22, 2007.
• EU Opens Tender to Distil Wine Into Biofuel
• "The Agrofuels Trap" — Foreign Policy in Focus, September 10, 2007.
• Biofuel Review a news portal for the biofuels industry
• Biofuels Central — The Brazil Institute of the Woodrow Wilson International Center for Scholars
• Alternative Fuels Portal
• IEA Bioenergy
• BioenergyWiki — a wiki on biofuels and related subjects, including bioenergy sustainability.
• Biofuels in New Zealand: Radio documentary, Part 1 (broadcast 26 May 2007) and Part 2 (broadcast 2 June 2007)
• Liquid Transportation Fuels from Biomass: Technology and Policy Considerations — a 5-day course at MIT reviewing technology, environmental, economic and agricultural policy issues.

Watchdog groups

• Biofuels — the answer to the wrong question, Ben Courtice, Green Left Weekly, 20 October 2006.
• Biofuels for Transport — a dangerous distraction?, Dr Andrew Boswell, published in Scientists for Global Responsibility (www.sgr.org.uk) newsletter, January 2007.
• Oliomap.com The Long Tail of biofuels
• Biofuelwatch
• Biofuels for Transportation: Global Potential and Implications for Sustainable Agriculture and Energy in the 21st Century