Common ethanol fuel mixtures
Several common ethanol fuel mixtures are in use around the world. The use of pure hydrous or anhydrous ethanol in internal combustion engines (ICEs) is only possible if the engines are designed or modified for that purpose, and used only in automobiles, light-duty trucks and motorcycles. Anhydrous ethanol can be blended with gasoline (petrol) for use in gasoline engines, but with high ethanol content only after minor engine modifications.
Ethanol fuel mixtures have "E" numbers which describe the percentage of ethanol fuel in the mixture by volume, for example, E85 is 85% anhydrous ethanol and 15% gasoline. Low-ethanol blends, from E5 to E25, are also known as gasohol, though internationally the most common use of the term refers to the E10 blend.
Blends of E10 or less are used in more than 20 countries around the world, led by the United States, where ethanol represented 10% of the U.S. gasoline fuel supply in 2011. Blends from E20 to E25 have been used in Brazil since the late 1970s. E85 is commonly used in the U.S. and Europe for flexible-fuel vehicles. Hydrous ethanol or E100 is used in Brazilian neat ethanol vehicles and flex-fuel light vehicles and hydrous E15 called hE15 for modern petrol cars in the Netherlands.
E10 or less
E10, a fuel mixture of 10% anhydrous ethanol and 90% gasoline sometimes called gasohol, can be used in the internal combustion engines of most modern automobiles and light-duty vehicles without need for any modification on the engine or fuel system. E10 blends are typically rated as being 2 to 3 octane numbers higher than regular gasoline and are approved for use in all new U.S. automobiles, and mandated in some areas for emissions and other reasons. The E10 blend and lower ethanol content mixtures have been used in several countries, and its use has been primarily driven by the several world energy shortages that have taken place since the 1973 oil crisis.
Other common blends include E5 and E7. These concentrations are generally safe for recent engines that should run on pure gasoline. As of 2006, mandates for blending bioethanol into vehicle fuels had been enacted in at least 36 states/provinces and 17 countries at the national level, with most mandates requiring a blend of 10 to 15% ethanol with gasoline.
One measure of alternative fuels in the U.S. is the "gasoline-equivalent gallon" (GEG). In 2002, the U.S. used as motor fuel, ethanol equal to 137,000 terajoules (TJ), the energy equivalent of 1.13 billion U.S. gallons (4.3 billion liters) of gasoline. This was less than 1% of the total fuel used that year.
E10 and other blends of ethanol are considered to be useful in decreasing U.S. dependence on foreign oil, and can reduce carbon monoxide (CO) emissions by 20 to 30% under the right conditions. Although E10 does decrease emissions of CO and greenhouse gases such as CO2 by an estimated 2% over regular gasoline, it can cause increases in evaporative emissions and some pollutants depending on factors such as the age of the vehicle and weather conditions. According to the Philippine Department of Energy, the use of not more than a 10% ethanol-gasoline mixture is not harmful to cars' fuel systems. Generally, automobile gasoline containing alcohol (ethanol or methanol) is not allowed to be used in U.S. certificated aircraft.
|This section is outdated. (January 2015)|
- E10 was introduced nationwide in Thailand in 2007, and replaced 91 octane pure gasoline in that country in 2013.
- E10 is commonly available in the Midwestern United States. It was also mandated for use in all standard automobile fuel in the state of Florida by the end of 2010. Due to the phasing out of MTBE as a gasoline additive and mainly due to the mandates established in the Energy Policy Act of 2005 and the Energy Independence and Security Act of 2007, ethanol blends have increased throughout the United States, and by 2009, the ethanol market share in the U.S. gasoline supply reached almost 8% by volume.
- The Tesco chain of supermarkets in the UK have started selling an E5 brand of gasoline marketed as 99 RON super-unleaded. Its selling price is lower than the other two forms of high-octane unleaded on the market, Shell's V-Power (99 RON) and BP's Ultimate (97 RON).
- Many petrol stations throughout Australia now also sell E10, typically at a few cents cheaper per litre than regular unleaded. It is more commonly found throughout the state of Queensland due to its large sugarcane farming regions. The use of E10 is also subsidised by the Queensland government. Many petrol stations no longer offer a "Regular 91" petrol option, instead only offering Regular E10 (91), Premium (95) and Premium (98), although regular unleaded remains commonly available in Victoria.
- In Sweden, all 95-octane gasoline is E5, while the status of 98-octane fuel is currently unclear. The product data sheets of the major fuel chains do not clearly state ethanol content of their 98-octane gasoline. In the early-mid-1990s, some fuel chains sold E10.
- From January 2011, all 95-octane fuel in Finland is E10, and 98E5 octane fuel is also available.
- Mandatory blending of ethanol was approved in Mozambique, but the percentage in the blend has not been specified.
- South Africa approved a biofuel strategy in 2007, and mandated an 8% blend of ethanol by 2013.
- A 2007 Uruguayan law mandates a minimum of 5% of ethanol blended with gasoline starting in January 2015. The monopolic, state-owned fuel producer ANCAP started blending premium gasoline with 10% of bioethanol in December 2009, which will be available in all the country by early January 2010. The other two gasolines will follow later in 2010.
- The Dominican Republic has a mandate for blending 15% of ethanol by 2015.
- Chile is considering the introduction of E5, and Panama, Bolivia and Venezuela of E10.
|Low ethanol blends used around the world (E5 to E25)|
|Countries with mandatory blends or available for optional use||European Union|| United States
(states where mandatory only)[n 1]
A 2011 study conducted by VTT Technical Research Centre of Finland found practically no difference in fuel consumption in normal driving conditions between commercial gasoline grades 95E10 and 98E5 sold in Finland, despite the public perception that fuel consumption is significantly higher with 95E10. VTT performed the comparison test under controlled laboratory conditions and their measurements showed the cars tested used an average of 10.30 liters (2.27 imp gal; 2.72 U.S. gal) of 95E10 per 100 km (62 mi), as opposed to 10.23 liters (2.25 imp gal; 2.70 U.S. gal) of 98E5 per 100 km (62 mi). The difference was 0.07 in favor of 98E5 on average, meaning that using 95E10 gasoline, which has a higher ethanol content, increases consumption by 0.7%. When the measurements are normalized, the difference becomes 1.0%, a result that is highly consistent with an estimation of calorific values based on approximate fuel composition, which came out at 1.1% in favour of E5.
E15 contains 15% ethanol and 85% gasoline. This is generally the highest ratio of ethanol to gasoline that is possible to use in vehicles recommended by some auto manufacturers to run on E10 in the US.
As a result of the Energy Independence and Security Act of 2007, which mandates an increase in renewable fuels for the transport sector, the U.S. Department of Energy began assessments for the feasibility of using intermediate ethanol blends in the existing vehicle fleet as a way to allow higher consumption of ethanol fuel. The National Renewable Energy Laboratory (NREL) conducted tests to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. In a preliminary report released in October 2008, the NREL presented the results of the first evaluations of the effects of E10, E15 and E20 gasoline blends on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This preliminary report found none of the vehicles displayed a malfunction indicator light as a result of the ethanol blend used; no fuel filter plugging symptoms were observed; no cold start problems were observed at 24 °C (75 °F) and 10 °C (50 °F) laboratory conditions; and as expected, all test vehicles exhibited a loss in fuel economy proportional with the lower energy density of ethanol, for example, with E20, the average reduction in fuel economy was 7.7% when compared to the miles per gallon achieved by the gasoline only (E0) test vehicles.
In March 2009, a lobbying group from the ethanol industry, Growth Energy, formally requested the U.S. Environmental Protection Agency (EPA) to allow the ethanol content in gasoline to be increased to 15% from 10%. Organizations doing such studies included the Energy Department, the State of Minnesota, the Renewable Fuels Association, the Rochester Institute of Technology, the Minnesota Center for Automotive Research, and Stockholm University in Sweden.
In October 2010, the EPA granted a waiver to allow up to 15% of ethanol blended with gasoline to be sold only for cars and light pickup trucks with a model year of 2007 or later, representing about 15% of vehicles on U.S. roads. In January 2011, the waiver was expanded to authorize use of E15 to include model year 2001 through 2006 passenger vehicles. The EPA also decided not to grant any waiver for E15 use in any motorcycles, heavy-duty vehicles, or nonroad engines because current testing data do not support such a waiver. According to the Renewable Fuels Association, the E15 waivers now cover 62% of vehicles on the road in the US, and the ethanol group estimates if all 2001 and newer cars and pickups were to use E15, the theoretical blend wall for ethanol use would be approximately 17.5 billion gallons (66.2 billion liters) per year. The EPA was still studying if older cars can withstand a 15% ethanol blend.
As the EPA waiver authorizes, but does not require stations to offer E15, a practical barrier to the commercialization of the higher blend is the lack of infrastructure, similar to the limitations suffered by sales of E85, as most fuel stations do not have enough pumps to offer the new blend, few existing pumps are certified to dispense E15, and no dedicated tanks are readily available to store E15. Also, some state and federal regulations would have to change before E15 can be legally sold. The National Association of Convenience Stores, which represents most gasoline retailers, considers the potential for actual E15 demand is small, "because the auto industry is not embracing the fuel and is not adjusting their warranties or recommendations for the fuel type." One possible solution to the infrastructure barriers is the introduction of blender pumps that allow consumers to turn a dial to select the level of ethanol, which would also allow owners of flexible-fuel cars to buy E85 fuel.
In June 2011 EPA, in cooperation with the Federal Trade Commission, issued its final ruling regarding the E15 warning label required to be displayed in all E15 fuel dispensers in the U.S. to inform consumers about what vehicles can, and what vehicles and equipment cannot, use the E15 blend. Both the Alliance of Automobile Manufacturers and the National Petrochemical and Refiners Association complained that relying solely on this warning label is not enough to protect consumers from misfueling. In July 2012, a fueling station in Lawrence, Kansas became the first in the U.S. to sell the E15 blend. The fuel is sold through a blender pump that allows customers to choose between E10, E15, E30 or E85, with the latter blends sold only to flexible-fuel vehicles. As of June 2013[update], there are about 24 fueling stations selling E15 out of 180,000 stations across the U.S.
In December 2010, several groups, including the Alliance of Automobile Manufacturers, the American Petroleum Institute, the Association of International Automobile Manufacturers, the National Marine Manufacturers Association, the Outdoor Power Equipment Institute, and the Grocery Manufacturers Association, filed suit against the EPA in the United States Court of Appeals for the District of Columbia Circuit. The plaintiffs argued the EPA does not have the authority to issue a “partial waiver” that covers some cars and not others. Among other arguments, the groups argued that the higher ethanol blend is not only a problem for cars, but also for fuel pumps and underground tanks not designed for the E15 mixture. It was also argued that the rise in ethanol has contributed to the big jump in corn prices in recent years. In August 2012, the federal appeals court rejected the suit against the EPA. The case was thrown out on a technical reason, as the court ruled the groups did not have legal standing to challenge EPA's decision to issue the waiver for E15. In June 2013 the U.S. Supreme Court declined to hear an appeal from industry groups opposed to the EPA ruling about E15, and let the 2012 federal appeals court ruling stand.
As of November 2012[update], sales of E15 are not authorized in California, and according to the California Air Resources Board (CARB), the blend is still awaiting approval, and in a public statement the agency said that "it would take several years to complete the vehicle testing and rule development necessary to introduce a new transportation fuel into California's market."
According to a survey conducted by the American Automobile Association (AAA) in 2012, only about 12 million out of the more than 240 million light-duty vehicles on the U.S. roads in 2012 are approved by manufacturers are fully compliant with E15 gasoline. According with the Association, BMW, Chrysler, Nissan, Toyota, and Volkswagen warned that their warranties will not cover E15-related damage. Despite the controversy, in order to adjust to EPA regulations, 2012 and 2013 model year vehicles manufactured by General Motors can use fuel containing up to 15 percent ethanol, as indicated in the vehicle owners' manuals. However, the carmaker warned that for model year 2011 or earlier vehicles, they "strongly recommend that GM customers refer to their owners manuals for the proper fuel designation for their vehicles." Ford Motor Company also is manufacturing all of its 2013 vehicles E15 compatible, including hybrid electrics and vehicles with Ecoboost engines. Also Porsches built since 2001 are approved by its manufacturer to use E15. Volkswagen announced that for the 2014 model year, its entire lineup will be E15 capable. Fiat Chrysler Automobiles announced in August 2015 that all 2016 model year Chrysler/Fiat, Jeep, Dodge and Ram vehicles will be E15 compatible.
In November 2013, the Environmental Protection Agency opened for public comment its proposal to reduce the amount of ethanol required in the U.S. gasoline supply as mandated by the Energy Independence and Security Act of 2007. The agency cited problems with increasing the blend of ethanol above 10%. This limit, known as the "blend wall," refers to the practical difficulty in incorporating increasing amounts of ethanol into the transportation fuel supply at volumes exceeding those achieved by the sale of nearly all gasoline as E10.
A 15% hydrous ethanol and 85% gasoline blend, hE15, has been introduced at public gas stations in the Netherlands since 2008. Ethanol fuel specifications worldwide traditionally dictate use of anhydrous ethanol (less than 1% water) for gasoline blending. This results in additional costs, energy usage and environmental impacts associated with the extra processing step required to dehydrate the hydrous ethanol produced via distillation (3.5-4.9 vol.% water) to meet the current anhydrous ethanol specifications. A patented discovery reveals hydrous ethanol can be effectively used in most ethanol/gasoline blending applications. 
According to the Brazilian ANP specification, hydrous ethanol contains up to 4.9 vol.% water. In hE15, this would be up to 0.74 vol.% water in the overall mixture. Japanese and German scientific evidence revealed the water is an inhibitor for corrosion by ethanol. 
The experiments show that water in fuel ethanol inhibits dry corrosion. At 10,000 ppm water in the E50 experiments by JARI and 3,500 ppm water in the E20 experiments by TU Darmstadt the alcoholate/alkoxide corrosion stopped. In the fuel ethanol this resembles 20,000 ppm or 2 volume% in the case of JARI and 5 x 3500 = 17,500 ppm of 1.75 volume% in the case of TU Darmstadt. The observations are in line with the fact that hydrous ethanol is known for being less corrosive than anhydrous ethanol. The reaction mechanism will be the same at lower-mid blends. When enough water is present in the fuel, the aluminum will react preferably with water to produce aluminum oxide, repairing the protective aluminum oxide layer, which is why the corrosion stops. The aluminum alcoholate/alkoxide does not make a tight oxide layer, which is why the corrosion continues. In other words, water is essential to repair the holes in the oxide layer. Based on the Japanese/German results, a minimum of 2 vol.% or 2.52% m/m water is currently proposed in the revision of the hydrous ethanol specification for blending in petrol at E10+ levels. Water injection has additional positive effects on the engine performance (thermodynamic efficiency) and reduces overall CO2 emissions.
Overall, a transition from anhydrous to hydrous ethanol for gasoline blending is expected to make a significant contribution to ethanol's cost-competitiveness, fuel cycle net energy balance, air quality, and greenhouse gas emissions.
The level of blending above 10% (V/V) is chosen both from a technical (safety) perspective and to distinguish the product in Europe from regular unleaded petrol for reasons of taxes and customer clarity. Small-scale tests have shown many vehicles with modern engine types can run smoothly on this hydrous ethanol blend. Mixed tanking scenarios with anhydrous ethanol blends at 5% or 10% level do not induce phase separation. As avoiding mixing with E0, in particular at extremely low temperatures, in logistic systems and engines is not recommended, a separate specification for controlled usage is presented in a Netherlands Technical Agreement NTA 8115. The NTA 8115 is written for a worldwide application in trading and fuel blending.
of ethanol blends used in Brazil
1931–2010 (Selected years only)
|Source: 1937–2007, J.A. Puerto Rico (2007), Table 3.8, pp. 81–82
Note: The 2010 reduction from E25 to E20 was temporary and took
place between February and April. The lower limit was reduced
from 20% to 18% in April 2011.
E20 contains 20% ethanol and 80% gasoline, while E25 contains 25% ethanol. These blends have been widely used in Brazil since the late 1970s. As a response to the 1973 oil crisis, the Brazilian government made mandatory the blend of ethanol fuel with gasoline, fluctuating between 10% to 22% from 1976 until 1992. Due to this mandatory minimum gasoline blend, pure gasoline (E0) is no longer sold in Brazil. A federal law was passed in October 1993 establishing a mandatory blend of 22% anhydrous ethanol (E22) in the entire country. This law also authorized the Executive to set different percentages of ethanol within pre-established boundaries, and since 2003, these limits were fixed at a maximum of 25% (E25) and a minimum of 20% (E20) by volume. Since then, the government has set the percentage on the ethanol blend according to the results of the sugarcane harvest and ethanol production from sugarcane, resulting in blend variations even within the same year.
Since July 1, 2007, the mandatory blend was set at 25% of anhydrous ethanol (E25) by executive decree, and this has been the standard gasoline blend sold throughout Brazil most of the time as of 2011. However, as a result of a supply shortage and the resulting high ethanol fuel prices, in 2010, the government mandated a temporary 90-day blend reduction from E25 to E20 beginning February 1, 2010. As prices rose abruptly again due to supply shortages that took place again between the 2010 and 2011 harvest seasons, some ethanol had to be imported from the United States, and in April 2011, the government reduced the minimum mandatory blend to 18%, leaving the mandatory blend range between E18 and E25.
All Brazilian automakers have adapted their gasoline engines to run smoothly with this range of mixtures, thus, all gasoline vehicles are built to run with blends from E20 to E25, defined by local law as "common gasoline type C". Some vehicles might work properly with lower concentrations of ethanol, but with a few exceptions, they are unable to run smoothly with pure gasoline, which causes engine knocking, as vehicles traveling to neighboring South American countries have demonstrated. Flex-fuel vehicles, which can run on any type of gasoline E20-E25 up to 100% hydrous ethanol (E100 or hydrated ethanol) ratios, were first available in mid-2003. In July 2008, 86% of all new light vehicles sold in Brazil were flexible-fuel, and only two carmakers build models with a flex-fuel engine optimized to operate with pure gasoline (E0): Renault with the models Clio, Symbol, Logan, Sandero and Mégane, and Fiat with the Siena Tetrafuel.
Thailand introduced E20 in 2008, but shortages in ethanol supplies by mid-2008 caused a delay in the expansion of the E20 fueling station network in the country. By mid-2010, 161 fueling stations were selling E20, and sales have risen 80% since April 2009. The rapid growth in E20 demand is because most vehicle models launched since 2009 were E20-compatible, and sales of E20 are expected to grow faster once more local automakers start producing small, E20-compatible, fuel-efficient cars. The Thai government is promoting ethanol usage through subsidies, as ethanol costs four baht a litre more than gasoline.
A state law approved in Minnesota in 2005 mandates that ethanol comprise 20% of all gasoline sold in this American state beginning in 2013. Successful tests have been conducted to determined the performance under E20 by current vehicles and fuel dispensing equipment designed for E10.
A study commissioned by BP and published in September 2013, concluded that the use of advanced biofuels in the UK, and particularly E20 cellulosic ethanol, is a more cost-effective way of reducing emissions than using plug-in electric vehicles (PEVs) in the timeframe to 2030. The study also found that the use of higher blends of biofuels is complementary to hybrid electric vehicles (HEVs) and plug-in hybrids (PHEVs). Battery electric vehicles (BEVs) can deliver strong CO2 savings with a decarbonised electric grid, but are expected to have significantly higher costs than internal combustion engine vehicles and hybrid cars to 2030, as the latter are expected to be the most popular models by 2030. According to the study, in 2030 an E20 blend in an HEV can achieve a 10% emission savings compared to an HEV running on E5, for an annual fuel cost premium of £13 compared to an annual cost of £195 for an all-electric car.
E70 contains 70% ethanol and 30% gasoline, while E75 contains 75% ethanol. These winter blends are used in the United States and Sweden for E85 flexible-fuel vehicles during the cold weather, but still sold at the pump labeled as E85. The seasonal reduction of the ethanol content to an E85 winter blend is mandated to avoid cold starting problems at low temperatures.
In the US, this seasonal reduction of the ethanol content to E70 applies only in cold regions, where temperatures fall below 32 °F (0 °C) during the winter. In Wyoming for example, E70 is sold as E85 from October to May. In Sweden, all E85 flexible-fuel vehicles use an E75 winter blend. This blend was introduced since the winter 2006-07 and E75 is used from November until March.
For temperatures below −15 °C (5 °F), all E85 flex vehicles require an engine block heater to avoid cold starting problems. The use of this device is also recommended for gasoline vehicles when temperatures drop below −23 °C (−9 °F). Another option when extreme cold weather is expected is to add more pure gasoline in the tank, thus reducing the ethanol content below the E70 winter blend, or simply not to use E85 during extreme low temperature spells.
E85, a mixture of 85% ethanol and 15% gasoline, is generally the highest ethanol fuel mixture found in the United States and several European countries, particularly in Sweden, as this blend is the standard fuel for flexible-fuel vehicles. This mixture has an octane rating of 94-97, which is significantly lower than pure ethanol, but still higher than normal gasoline (87-93 octane, depending on country).
The 85% limit in the ethanol content was set to reduce ethanol emissions at low temperatures and to avoid cold starting problems during cold weather, at temperatures lower than 11 °C (52 °F). A further reduction in the ethanol content is used during the winter in regions where temperatures fall below 0 °C (32 °F) and this blend is called Winter E85, as the fuel is still sold under the E85 label. A winter blend of E70 is mandated in some regions in the US, while Sweden mandates E75. Some regions in the United States now allow E51 (51% ethanol, 49% gasoline) to be sold as E85 in the winter months.
As of October 2010, nearly 3,000 E85 fuel pumps were in Europe, led by Sweden with 1,699 filling stations. The United States had 3,354 public E85 fuel pumps located in 2,154 cities by August 2014, mostly concentrated in the Midwest.
ED95 designates a blend of 95% ethanol and 5% ignition improver; it is used in modified diesel engines where high compression is used to ignite the fuel, as opposed to the operation of gasoline engines, where spark plugs are used. This fuel was developed by Swedish ethanol producer SEKAB. Because of the high ignition temperatures of pure ethanol, the addition of ignition improver is necessary for successful diesel engine operation. A diesel engine running on ethanol also has a higher compression ratio and an adapted fuel system.
This fuel has been used with success in many Swedish Scania buses since 1985, which has produced around 700 ethanol buses, more than 600 of them to Swedish cities, and more recently has also delivered ethanol buses for commercial service in Great Britain, Spain, Italy, Belgium, and Norway. As of June 2010 Stockholm has the largest ethanol ED95 bus fleet in the world.
As of 2010, the Swedish ED95 engine is in its third generation and already has complied with Euro 5 emission standards, without any kind of post-treatment of the exhaust gases. The ethanol-powered engine is also being certified as environmentally enhanced vehicle (EEV) in the Stockholm municipality. The EEV rule still has no date to enter into force in Europe and is stricter than the Euro 5 standard.
Nottingham became the first city in England to operate a regular bus service with ethanol-fueled vehicles. Three ED95 single-deck buses entered regular service in the city in March 2008. Soon after, Reading also introduced ED95 double-deck buses.
Under the auspices of the BioEthanol for Sustainable Transport project, more than 138 bioethanol ED95 buses were part of demonstration trial at four cities, three in Europe, and one in Brazil, between 2006 and 2009. A total of 127 ED95 buses operated in Stockholm, five buses operated in Madrid, three in La Spezia, and one in Brazil. In Brazil, the first Scania ED95 bus with a modified diesel engine was introduced as a trial in São Paulo city on December 2007, and since November 2009, two ED95 buses were in regular service. The Brazilian trial project ran for three years and performance and emissions were monitored by the National Reference Center on Biomass (CENBIO- Portuguese: Centro Nacional de Referência em Biomassa) at the Universidade de São Paulo.
In November 2010, the municipal government of São Paulo city signed an agreement with UNICA, Cosan, Scania and Viação Metropolitana, a local bus operator, to introduced a fleet of 50 ethanol-powered ED95 buses by May 2011. Scania manufactures the bus engine and chassis in its plant located in São Bernardo do Campo, São Paulo, using the same technology and fuel as the ED95 buses already operating in Stockholm. The bus body is a Brazilian CAIO. The first ethanol-powered buses were delivered in May 2011, and the 50 buses will start regular service in June 2011 in the southern region of São Paulo. The 50 ED95 buses had a cost of R$ 20 million (US$12.3 million) and due to the higher cost of the ED95 fuel and the lower energy content of ethanol as compared to diesel, one of the firms participating in the cooperation agreement, Raísen (a joint venture between Royal Dutch Shell and Cosan), supplies the fuel to the municipality at 70% of the market price of regular diesel.
E100 is pure ethanol fuel. Straight hydrous ethanol as an automotive fuel has been widely used in Brazil since the late 1970s for neat ethanol vehicles and more recently for flexible-fuel vehicles. The ethanol fuel used in Brazil is distilled close to the azeotrope mixture of 95.63% ethanol and 4.37% water (by weight) which is approximately 3.5% water by volume. The azeotrope is the highest concentration of ethanol that can be achieved by distillation. The maximum water concentration according to the ANP specification is 4.9 vol.% (approximately 6.1 weight%)  The E nomenclature is not adopted in Brazil, but hydrated ethanol can be tagged as E100, meaning it does not have any gasoline, because the water content is not an additive, but rather a residue from the distillation process. However, straight hydrous ethanol is also called E95 by some authors.
The first commercial vehicle capable of running on pure ethanol was the Ford Model T, produced from 1908 through 1927. It was fitted with a carburetor with adjustable jetting, allowing use of gasoline or ethanol, or a combination of both. At that time, other car manufacturers also provided engines for ethanol fuel use. Thereafter, and as a response to the 1973 and 1979 energy crises, the first modern vehicle capable of running with pure hydrous ethanol (E100) was launched in the Brazilian market, the Fiat 147, after testing with several prototypes developed by the Brazilian subsidiaries of Fiat, Volkswagen, General Motors and Ford. As of September 2012[update], there were 1.1 million neat ethanol vehicles still in use in Brazil. Since 2003, Brazilian newer flex-fuel vehicles are capable of running on pure hydrous ethanol (E100) or blended with any combination of E20 to E25 gasoline (a mixture made with anhydrous ethanol), the national mandatory blend. As of September 2012[update], there were 17.1 million flexible-fuel vehicles running on Brazilian roads.
E100 imposes a limitation on normal vehicle operation, as ethanol's lower evaporative pressure (as compared to gasoline) causes problems when cold starting the engine at temperatures below 15 °C (59 °F). For this reason, both pure ethanol and E100 flex-fuel vehicles are built with an additional small gasoline reservoir inside the engine compartment to help in starting the engine when cold by initially injecting gasoline. Once started, the engine is then switched back to ethanol. An improved flex-fuel engine generation was developed to eliminate the need for the secondary gas tank by warming the ethanol fuel during starting, and allowing them to start at temperatures as low as −5 °C (23 °F), the lowest temperature expected anywhere in the Brazilian territory. The Polo E-Flex, launched in March 2009, was the first flex-fuel model without an auxiliary tank for cold start. The warming system, called Flex Start, was developed by Robert Bosch GmbH.
Swedish carmakers have developed ethanol-only capable engines for the new Saab Aero X BioPower 100 Concept E100, with a V6 engine which is fuelled entirely by E100 bioethanol, and the limited edition of the Koenigsegg CCXR, a version of the CCX converted to use E85 or E100, as well as standard 98-octane gasoline, and currently the fastest and most powerful flex-fuel vehicle with its twin-supercharged V8 producing 1018 hp when running on biofuel, as compared to 806 hp on 91-octane unleaded gasoline.
Modifications to engines
The use of ethanol blends in conventional gasoline vehicles is restricted to low mixtures, as ethanol is corrosive and can degrade some of the materials in the engine and fuel system. Also, the engine has to be adjusted for a higher compression ratio as compared to a pure gasoline engine to take advantage of ethanol's higher oxygen content, thus allowing an improvement in fuel efficiency and a reduction of tailpipe emissions. The following table shows the required modifications to gasoline engines to run smoothly and without degrading any materials. This information is based on the modifications made by the Brazilian automotive industry at the beginning of the ethanol program in that country in the late 1970s, and reflects the experience of Volkswagen do Brasil.
|Required adjustments to gasoline engines to cope with different blends of ethanol fuel|
|Carburetor||Fuel Injection||Fuel pump||Fuel
|Fuel filter||Ignition system||Evaporative
|≤ 5%||Modifications not necessary for any vehicle|
|E5 to E10||Modifications not necessary for vehicles since about 1987-92|
|E10 to E25||Specially designed vehicles|
|E25 to E85||Specially designed vehicles|
|E85 to E100||Specially designed vehicles|
|Source: Josehp (2007) in The Royal Society (2008), "Sustainable biofuels: prospects and challenges, pp. 35-36".|
Disadvantages to ethanol fuel blends when used in engines designed exclusively for gasoline include lowered fuel mileage, metal corrosion, deterioration of plastic and rubber fuel system components, clogged fuel systems, fuel injectors, and carburetors, delamination of composite fuel tanks, varnish buildup on engine parts, damaged or destroyed internal engine components, water absorption, fuel phase separation, and shortened fuel storage life. Many major auto, marine, motorcycle, lawn equipment, generator, and other internal combustion engine manufacturers have issued warnings and precautions about the use of ethanol-blended gasolines of any type in their engines, and the Federal Aviation Administration and major aviation engine manufacturers have prohibited the use of automotive gasolines blended with ethanol in light aircraft due to safety issues from fuel system and engine damage.
- Butanol fuel
- Ethanol fuel
- Ethanol fuel energy balance
- Ethanol fuel in Brazil
- Biofuel in Sweden
- Ethanol fuel in the United States
- Food vs. fuel
- Indirect land use change impacts of biofuels
- List of flexible-fuel vehicles by car manufacturer
- Though mandated only in 10 states, ethanol blends in the U.S. are available in other states as optional or added without any labeling, making E blends present in two-thirds of the U.S. gasoline supply.
- Actual blend is subject to ethanol availability. Blend for 2010 was 2.7% and expected to reach 4.5% in 2011
- Actual blend is subject to ethanol availability
- Started in late 2011 in Guadalajara. Scheduled for Monterrey and Mexico City in 2012.
- Starting on December 15, 2010.
- The State of Oregon exempted premium unleaded gasoline (91octane or higher) from the 10% ethanol mandate for road use since January 2010.
- E5 is scheduled to be phased out in 2013
- In Colombia mandatory blend was enforced only in cities with more than 500.000 inhabitants.
- Actual blend is 7.8% ethanol (E8) and mandatory only in certain regions. Sales of E8 began in April 2010 in nine regions in northern Peru, and in July 2011 in the Lima-Callao metropolitan area.
- Mandatory blend scheduled for 2009 was postponed. Sales of E7 continue in the original trial region in the Guanacaste Province and six municipalities in the Puntarenas Province. Nationwide availability rescheduled to begin in June 2012.
- Since November 1, 2008 became available in some cities and will become mandatory in May 2009.
- Renewable Fuels Association (2012-03-06). "Acelerating Industry Innovation - 2012 Ethanol Industry Outlook" (PDF). Renewable Fuels Association. Retrieved 2012-05-06. See pp. 10
- BEST Cities and Regions (2009). "BioEthanol for Sustainable Transport: Results and recommendations from the European BEST project" (PDF). Environmental and Health Administration, City of Stockholm. Retrieved 2011-05-29.
- E10: Every vehicle's ethanol blend, drivingethanol.org.[dead link]
- "Towards Sustainable Production and Use of Resources: Assessing Biofuels" (PDF). United Nations Environment Programme See Table 3.3. 2009-10-16. Retrieved 2009-10-27.
- Low-Level Ethanol Fuel Blends, Clean Cities fact sheet, April 2005.
- E10 Emissions, U.S. Department of Energy.
- "AF/Bioethanol.htm Bioethanol". Doe.gov.ph. Retrieved 2010-12-05.
- Special Airworthiness Information Bulletin CE-07-06 (October 27, 2006), Federal Aviation Administration.[dead link]
- Florida E85 Laws and Incentives, U.S. Department of Energy.
- "Bioenergy: Background - Ethanol". U.S. Department of Agriculture. 2010-04-10. Retrieved 2010-09-16.
- MTBE & Ethanol, State of Texas Energy Conservation Office.
- Mitchell, Donald (2011). Biofuels in Africa: Opportunities, Prospects, and Challenges. The World Bank, Washington, D.C. p. 84. ISBN 978-0-8213-8516-6. See Table 4.1
- Ley Nº 18.195: Agrofuels (in Spanish) - Parliament of Uruguay.
- Ancap planea llevar de 2% a 5% mezcla con biodiesel - Diario El País, December 12, 2009 (Spanish)
- "Technology Roadmaps: Biofuels for Transport" (PDF). International Energy Agency. 2011. Retrieved 2011-08-27. See Table 1 pp. 10-11.
- "State Legislation". Ethanol.org. Retrieved 2008-10-24.Florida starting in 2010 and Minnesota will go up to E20 in 2013.
- Kate Galbraith (2008-07-26). "In Gas-Powered World, Ethanol Stirs Complaints". The New York Times. Retrieved 2008-10-24.
- "Situación del Mercado de Etanol en Argentina" (in Spanish). Más Producción.com. 2010-11-26. Retrieved 2011-02-13.
- AIT/FIA Information Centre (OTA) (2007). "Sale of biofuels around the world" (PDF). Motormannen. Retrieved 2008-10-25.
- "Shell Unleaded E10 Launched". Shell Australia. 2006-04-12. Retrieved 2008-10-25.
- El Universal (Mexico City) (2010-10-14). "Pemex adquirirá etanol para usarlo como combustible en Guadalajara". Informador.com.mx. Retrieved 2011-08-27.
- "Lei Nº 8.723, de 28 de Outubro de 1993. Dispõe sobre a redução de emissão de poluentes por veículos automotores e dá outras providências" (in Portuguese). Casa Civil da Presidência da República. Retrieved 2008-10-05. See article 9º and modifications approved by Law Nº 10.696, 2003-07-02
- Datamonitor (2008-08-12). "Gull New Zealand Launches New 91 Octane Biofuel". redOrbit. Retrieved 2008-10-25.
- "New 95 E10 petrol introduced in Finland".
- "Government of Canada Releases Final Regulations for Renewable Fuel Content in Gasoline". Environmental Canada. 2010-09-01. Retrieved 2010-09-16.
- PSO (2009-08-19). "PSO Launches 'E10 Gasoline' in Karachi". PSO. Retrieved 2008-08-19.
- "Le nouveau super carburant SP95-E10" (in French). Department of Ecology, Sustainable Development, Transportation and Housing. 2011-01-17. Retrieved 2011-02-14.
- "SP95 E10 : le point sur le nouveau carburant distribué en France" (in French). Moto-Net.com. 2009-02-06. Retrieved 2011-02-14.
- "Oregon Biofuel renewable fuel standard". Oregon.gov. Retrieved 2010-12-05.
- "China Fuel Ethanol Production Projected to Increase 12% in 2007". Green Car Congress. 2007-06-27. Retrieved 2008-10-25. Five provinces almost have reached full use of E10, while four provinces have only partly adopted the blend.
- Souto, Guillermo (2008). "Paraguay explora su potencial en biocombustibles" (PDF) (in Spanish) 4 (May–August). COMUN IICA. pp. 44–52. Retrieved 2011-02-14.
- "E10 coming to pumps in Germany 1 January". Green Car Congress. 2010-12-30. Retrieved 2010-12-31.
- Gloria Rey (2007-10-12). "Energy-Colombia: Harvesting Sunshine for Biofuels". Inter Press Service News Agency. Retrieved 2008-10-25. E10 use began in 2005
- "A rodar con alcohol carburante" (in Spanish). Diario Occidente. Retrieved 2008-10-25.[dead link]
- Rothkopf, Garten (2007). A Blueprint for Green Energy in the Americas. Inter-American Development Bank, Washington, D.C. p. 100. Retrieved 2009-03-09.
- Agencia Peruana de Noticias (2011-07-15). "Producción peruana de etanol para gasohol crecería a más del doble en el último trimestre". América Economía (in Spanish). Retrieved 2011-10-26.
- "Ireland adopts mandatory ethanol blend". English.unica.com.br. Retrieved 2010-12-05.
- "California Statistics and Data on Ethanol and E85 as Transportation Fuels". State of California. 2012-03-16. Retrieved 2014-10-07.
- Mercedes Agüero (2009-03-04). "Recope obligada a guardar etanol por atraso del Minaet". La Nación (in Spanish). Retrieved 2009-05-10.
- Mercedes Agüero (2009-03-04). "Gasolineros estarían listos para vender mezcla en noviembre" (in Spanish). La Nación. Retrieved 2009-05-10.Introduction was delay for November 2009.
- Jairo Villegas (2010-07-14). "Recope descarta plan de etanol a corto plazo". La Nación (in Spanish). Retrieved 2011-02-14.
- Jairo Villegas (2011-04-07). "Recope pretende extender uso de etanol a todo el país". La Nación (in Spanish). Retrieved 2012-01-05.
- "Ethanol Around the World". Biofuels Association of Australia. Retrieved 2010-12-31.
- "India Making E5 Mandatory in October 2006". Green Car Congress. 2006-05-27. Retrieved 2008-10-25. E10 was expected to be in effect in October 2008
- "E10, E20 market share up to 48 percent in Thailand, state oil CEO says production should increase". Biofuels Digest. 2008-08-07. Retrieved 2008-10-25.
- Kingsman (2009-08-18). "Kingsman EU ETBE/Ethanol Report" (PDF). Retrieved 2011-03-15.
- "E10 Blend Projected to save Jamaica US 92 million on fuel imports". Jamaica Information Service. 2008-11-05. Retrieved 2008-11-06.
- "VTT study finds no significant difference in car fuel consumption between E10 and E5". Green Car Congress. 2011-06-06. Retrieved 2011-06-12.
- "Moving to E15 would help extend the fuel supply in the wake of the hurricanes". American Coalition for Ethanol. 2008-09-16. Retrieved 2008-10-19.
- "How do I tell if my vehicle is an Flexible Fuel Vehicle (FFV)?". E85. Retrieved 2008-10-19.
- Brian West, Keith Knoll, Wendy Clark, Ronald Graves, John Orban, Steve Przesmitzki, and Timothy Theiss (2008). "Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1" (PDF). Oak Ridge National Laboratory and National Renewable Energy Laboratory. Retrieved 2008-10-19. NREL/TP-540-43543, ORNL/TM-2008/117
- "Preliminary Test Report Shows No Significant Change in Vehicle Emissions from Intermediate Ethanol Blends". Green Car Congress. 2008-10-07. Retrieved 2008-10-19.
- Jensen, Christopher (2010-06-18). "E.P.A. Delays Ruling on Increasing Ethanol Content in Gasoline". New York Times. Retrieved 2010-06-19.
- Matthew L. Wald (2010-10-13). "A Bit More Ethanol in the Gas Tank". New York Times. Retrieved 2010-10-14.
- Fred Meier (2010-10-13). "EPA allows 15% ethanol in gasoline, but only for late-model cars". USA Today. Retrieved 2010-10-14.
- John O'Dell (2010-11-19). "EPA Postpones Ruling on Expanded E15 Use, Says Testing Not Completed". Edmunds.com. Retrieved 2010-11-27.
- "US EPA extends E15 fuel waiver to MY 2001–2006 light-duty vehicles". Green Car Congress. 2011-01-21. Retrieved 2011-01-26.
- Matthew L. Wald (2011-01-21). "E.P.A. Approves Use of More Ethanol in Gasoline". The New York Times. Retrieved 2011-02-26.
- Jim Motavalli (2011-06-28). "E.P.A.'s E15 Pump Labels Raise Ire of Automakers". The New York Times. Retrieved 2011-06-29.
- Eric Loveday (2011-06-29). "Attention! EPA releases finalized E15 warning label". AutoblogGreen. Retrieved 2011-06-29.
- Matthew L. Wald (2012-07-11). "In Kansas, Stronger Mix of Ethanol". The New York Times. Retrieved 2012-08-18.
- David Sheparson (2013-06-24). "Court declines to hear challenge to EPA's stance on E15 gasoline". The Detroit News. Retrieved 2013-06-25.
- Matthew L. Wald (2010-12-20). "Engine Makers Sue to Block E15 Fuel". The New York Times. Retrieved 2012-08-18.
- David Shepardson (2012-08-17). "U.S. court rejects auto industry challenge to E15". The Detroit News. Retrieved 2012-08-18.
- Sara Forden (2012-08-17). "EPA Defeats Challenge To Higher Ethanol Levels In Fuel". Bloomberg News. Retrieved 2012-08-18.
- Jon LeSage (2012-11-14). "CARB: It will take years for California to decide on E15". Autoblog Green. Retrieved 2012-11-15.
- Michael Green (2012-11-30). "New E15 Gasoline May Damage Vehicles and Cause Consumer Confusion". American Automobile Association. Retrieved 2015-08-26.
- Susanne Retka Schill (2012-10-17). "GM, Ford announce E15 compatibility with new models". Ethanol Producer Magazine. Retrieved 2013-04-09.
- VW US Media Room (2013-07-14). "Volkswagen of America bringing in downsized 1.8L EA888 engine to displace 2.5L; all vehicles E15 capable". Green Car Congress. Retrieved 2013-07-14.
- "FCA approving use of E15 in MY 2016 vehicles". Green Car Congress. 2015-08-18. Retrieved 2015-08-25.
- EPA. "EPA Proposes 2014 Renewable Fuel Standards, 2015 Biomass-Based Diesel Volume" (PDF). U.S. Environmental Protection Agency (EPA). Retrieved 2013-11-24.
- Matthew L. Wald (2013-11-15). "For First Time, E.P.A. Proposes Reducing Ethanol Requirement for Gas Mix". The New York Times. Retrieved 2013-11-24.
- "Motorfuel based on gasoline and ethanol". World Intellectual Property Organization. 2006-12-28. Retrieved 2006-12-28.
- "Gasoline C made with Hydrous Ethanol in Brazil" (PDF). Delphi South America Technical Center – Brazil. 2008-07-30.
- "Effect of Alcohol Fuels on Fuel-Line Materials of Gasoline Vehicles". SAE.
- "HE Blends website". HE Blends BV.
- "Netherlands Technical agreement NTA 8115 "Automotive fuels - Hydrous ethanol as a blending component for petrol – Requirement and test methods"". NEN.
- "Portaria Nº 143, de 27 de Junho de 2007" (in Portuguese). Ministério da Agricultura, Pecuária e Abastecimento. Retrieved 2008-10-05. This decree fixed the mandatory blend at 25% starting July 1, 2007
- "Portaria No. 7 de 11 de Janeiro de 2010 do Ministério de Estado da Agricultura, Pecuária e Abastecimento e Resolução No. 1 do Conselho Interministeriarl do Açúcar e do Álcool" (PDF) (in Portuguese). Diário Oficial da União. 2010-01-12. Retrieved 2010-02-10. pp. 3
- "Dilma assina medida que dá poder à ANP para regular etanol" (in Portuguese). Reuters Brasil. 2011-04-28. Retrieved 2011-05-03.
- Julieta Andrea Puerto Rico (2008-05-08). "Programa de Biocombustíveis no Brasil e na Colômbia: uma análise da implantação, resultados e perspectivas" (in Portuguese). Universidade de São Paulo. Retrieved 2008-10-05. Ph.D. Dissertation Thesis, pp. 81-82
- Hugo Cilo (2011-04-29). "A gasolina vai matar a indústria do etanol". ISTOÉ Dinheiro (in Portuguese). Retrieved 2011-05-03.
- Manoela Alcântara. "Mistura de álcool anidro à gasolina vai subir de 23% para 25%, anuncia Stephanes" (in Portuguese). Agência Brasil. Retrieved 2008-10-05.[dead link]
- "Governo reduz mistura de etanol na gasolina para 20%" (in Portuguese). Reuters Brasil. 2010-01-11. Retrieved 2010-02-10.
- "Glossário ANP:G (Glossary: Letter G)" (in Portuguese). Agência Nacional do Petróleo, Gás Natural e Biocombustíveis. Archived from the original on April 20, 2008. Retrieved 2008-11-02. See definition of "Gasolina A" and "Gasolina C".
- Líria Alves. "Classificação e qualidade da Gasolina" (in Portuguese). Brasil Escola. Retrieved 2008-10-05.
- Bob Sharp. "Receita caseira para rodar fora do país sem problemas ao abastecer" (in Portuguese). Revista Quatro Rodas. Retrieved 2008-10-04.
- "Onda dos flex pode gerar desequilíbrio com a gasolina" (in Portuguese).
- A.C. Bispo (2008-07-19). "Clio Hi-Flex impressiona pelo desempenho" (in Portuguese). Parana Online. Retrieved 2008-10-05.
- Christine Lepisto (2006-08-27). "Fiat Siena Tetra Power: Your Choice of Four Fuels". Treehugger. Retrieved 2008-08-24.
- "Nouvelle Fiat Siena 2008: sans complexe" (in French). Caradisiac. 2007-11-01. Retrieved 2008-08-31.
- Xavier Navarro (2008-01-04). "Happy New Fuel: E20 on sale in Thailand". AutoblogGreen. Retrieved 2008-10-05.
- Yuthana Praiwan (2008-09-26). "Shell delays E20 on supply concerns". Bangkok Post. Retrieved 2008-10-05.
- "PTT widens E85 availability, prepares for boom in E20". Bangkok Post. 2010-06-18. Retrieved 2010-10-31.[dead link]
- Cindy Zimmerman (2008-03-05). "E20 Passes Minnesota Testing". Domestic Fuel. Retrieved 2008-10-05.
- Faye Sunderland (2013-09-23). "Advanced biofuels could cut GHG emissions for less than electric cars". The Green Car Website (UK). Retrieved 2013-09-25.
- Element Energy Limited (2013-09-16). "The Role of Biofuels Beyond 2020" (PDF). Element Energy. Retrieved 2013-09-25.
- "Sustainable biofuels: prospects and challenges". The Royal Society. January 2008. Retrieved 2010-12-08. Policy Document 01/08, Figure 4.3
- Ethanol Promotion and Information Council (2007-02-27). "When is E85 not 85 percent ethanol? When it's E70 with an E85 sticker on it". AutoblogGreen. Retrieved 2008-08-19.
- Vägverket (Swedish Road Administration) (2007-05-30). "Swedish comments on Euro 5/6 comitology version 4, 30 May 2007: Cold Temperature Tests For Flex Fuel Vehicles" (PDF). European Commission. Retrieved 2008-09-23.
- Davis, G.W.; et al. (2002-08-06). "Ethanol vehicle cold start improvement when using a hydrogensupplemented E85 fuel". Energy Conversion Engineering Conference and Exhibit, 2000. (IECEC) 35th Intersociety. Retrieved 2008-10-14.
- Gregory W. Davis (2001-06-11). "Development of Technologies to Improve Cold Start Performance of Ethanol Vehicles: Final Report" (PDF). State of Michigan. Retrieved 2008-10-14.
- "Ethanol fuel and cars". Interesting Energy Facts. Retrieved 2008-09-23.
- "FAQs: Do ethanol cars really start when it is cold outside?". SEKAB. Retrieved 2008-10-14.
- Goettemoeller, Jeffrey; Adrian Goettemoeller (2007). Sustainable Ethanol: Biofuels, Biorefineries, Cellulosic Biomass, Flex-Fuel Vehicles, and Sustainable Farming for Energy Independence. Prairie Oak Publishing, Maryville, Missouri. pp. 56–61. ISBN 978-0-9786293-0-4.
- "Ont om tankställen utanför Sverige? (Short of filling stations outside Sweden?)" (in Swedish). ethanol.nu. Retrieved 2010-10-31.
- "Search E85 stations". korridor.se. Retrieved 2010-10-31.
- "3,354 Total E85 Stations in the United States". E85prices.com. Retrieved 2014-08-01.
- "ED95". SEKAB. Retrieved 2009-06-03.
- "Scania Delivering 85 New Ethanol Buses for Stockholm Fleet". Green Car Congress. 2010-06-21. Retrieved 2010-06-25.
- "Biofuel in Sweden". SEKAB. Retrieved 2009-06-03.
- Moreira, José Roberto, Sandra Maria Apolinario, and Suani Teixeira Coelho (2010). "Ethanol Usage in Urban Public Transportation - Presentation of Results" (PDF). Brazilian Reference Center on Biomass (CENBIO). Retrieved 2011-05-28. Report 2010-36-0130I, pp. 5
- Brian Warshaw (2008-03-21). "England receives ethanol buses". Ethanol Producer Magazine. Retrieved 2008-11-22.
- BEST (2009). "Buses: 138 buses in five places". BEST Europe. Retrieved 2011-05-28.
- "São Paulo joins EU's BEST project with pure ethanol bus trial; over 400 in operation so far". Biopact. 2008-01-31. Retrieved 2008-11-22.
- "Começa a circular em São Paulo ônibus movido a etanol" (in Portuguese). Estado de São Paulo. Retrieved 2008-11-22.
- "Sao Paulo Puts Ethanol Bus into Service in BEST Project". Green Car Congress. 2007-12-23. Retrieved 2008-11-22.
- "O bom exemplo da Suécia:600 ônibus movidos com etanol para o transporte público de Estocolmo" (in Portuguese). UNICA, Brazil. 2010-06-25. Retrieved 2010-06-25.
- Martha San Juan França (2011-05-26). "São Paulo ganha frota de ônibus a etanol". Brasil Econômico (in Portuguese). Retrieved 2011-05-27.
- Reuters (2010-11-25). "São Paulo terá primeira frota de ônibus movida a etanol". Terra Networks (in Portuguese). Retrieved 2010-11-27.
- "São Paulo putting 50 Scania ethanol buses into service". Green Car Congress. 2010-11-29. Retrieved 2010-11-29.
- "Substituição de diesel por etanol: vantagem que novos ônibus trazem à cidade de São Paulo". UNICA (in Portuguese). 2011-05-26. Retrieved 2011-05-27.
- Revista Veja (1979-06-13). "O petróleo da cana" (in Portuguese). Editora Abril. Retrieved 2008-10-18.
- Adam Lashinsky and Nelson D. Schwartz (2006-01-24). "How to Beat the High Cost of Gasoline. Forever!". Fortune. Retrieved 2008-08-13.
- João Gabriel de Lima (2006-02-01). "A riqueza é o saber" (in Portuguese). Revista Veja. Retrieved 2008-08-19. Print edition No. 1941
- National Institute of Standards and Technology. "Standard Reference Material 1828: Ethanol-Water Solutions" (PDF).
- Agência Nacional do Petróleo, Gás Natural e Biocombustíveis (ANP) (2005-12-06). "Resolução ANP Nº 36, Delaware 6.12.2005 - DOU 7.12.2005" (in Portuguese). ANP. Retrieved 2008-11-15. See Table I – Specifications for AEAC and AEHC at "Anexo: Regulamente Técnico ANP Nº 7/2005.
- Márcia Azanha Ferraz Dias de Moraes. "Reflections on Brazil's Ethanol Industry" (PDF). Ministério de Relações Exteriores (Brazil). Retrieved 2008-11-15. Here Brazilian flex cars are called E95 flexible-fuel vehicles.[dead link]
- "Fuels of the Future". ThinkQuest. Retrieved 2008-11-15. Here E95 is defined as pure ethanol before it is denatured, so straight hydrated ethanol would be E95 and not E100 by this definition.
- Hunt, V, D, The Gasohol Handbook, Industrial Press Inc., 1981, pp 9, 420,421, 442
- English, Andrew (2008-07-25). "Ford Model T reaches 100". London: The Telegraph. Retrieved 2008-08-11.
- "Ethanol: Introduction". Journey to Forever. Retrieved 2008-08-11.
- William Lemos (2007-02-05). "The Brazilian ethanol model". ICIS news. Retrieved 2008-08-14.
- UNICA, Brazil (October 2012). "Frota brasileira de autoveículos leves (ciclo Otto)" [Brazilian fleet of light vehicles (Otto cycle)] (in Portuguese). UNICA Data. Retrieved 2012-10-31.
- Ron Kotrba (March 2008). "Cold Start 101". Ethanol Producer Magazine. Retrieved 2008-10-14.
- "Here comes the 'Flex' vehicles third generation" (PDF). Revista Brasileira de BioEnergia (in Portuguese) (Centro Nacional de Referência em Biomassa (Cenbio)). August 2008. Retrieved 2008-09-23. Ano 2, No. 3 (every article is presented in both English and Portuguese)
- Agência Estado (2008-06-10). "[Bosch] investe na segunda geração do motor flex" (in Portuguese). Gazeta do Povo. Retrieved 2008-09-23.
- Priscila Dal Poggetto (2008-03-13). "Nova tecnologia dispensa gasolina na partida de carros bicombustíveis" (in Portuguese). Globo G1. Retrieved 2008-10-15.
- Marli Olmos (2007-11-26). "Partida a Frio Chega com a Linha 2009" (in Portuguese). Automotive Business. Retrieved 2008-10-15. Originally published in Revista Valor Econômico.
- Quatro Rodas (March 2009). "Volkswagen Polo E-Flex" (in Portuguese). Editora Abril. Retrieved 2003-03-12.
- "Volks lança sistema que elimina tanquinho de gasolina para partida a frio" (in Portuguese). UNICA. 2009-03-12. Retrieved 2003-03-12.
- "Saab BioPower Aero X". Saab. Retrieved 2008-10-19.
- Bill Siuru. "Saab BioPower 100 Concept E100 Ethanol Vehicle". GreenCar.com. Retrieved 2008-10-19.
- Peter Grunet (2007-03-05). "Green Flash". Top Gear Magazine. pp. 138–142.
- "Geneva Preview: Koenigsegg CCX & CCXR Edition Models". Zimbio. 2008-02-27. Retrieved 2008-09-01.
- Timothy Charles Holms (2008-05-27). "Indianapolis 500 continues E100 use". Ethanol Producer Magazine. Retrieved 2008-10-19.
- "The Vehicle Adaptation to Ethanol Fuel". Archived from the original on Oct 13, 2007., slide presentation by Henry Joseph, Jr., Brazilian Vehicle Manufacturers Association, presented at the Royal Society Multilateral Second Generation Biofuels Event, April 2007. Referenced in: "Sustainable biofuels: prospects and challenges". The Royal Society. January 2008. Retrieved 2010-12-08. Policy Document 01/08
- Is fuel with an increased level of ethanol a problem for small gas engines?, Tools & Power Equipment, Consumer Reports, 24 June 2009
- Vatalaro, Michael,A Serious Problem - A Corny Solution, Boat US Magazine, (July 2006)
- Maloney, William,Ethanol Pros & Cons in Automotive Gas, retrieved 8 August 2011
- "Manufacturer E10 (Ethanol) Fuel Recommendations". Fuel Testers. Retrieved 6 August 2012.
- FAA to STC Holders: No Ethanol in Auto Fuel, EAA, retrieved 8 August 2011
- Bioenergywiki: Renewable fuel targets at bioenergywiki. See here a complete list of mandatory blends that will go into effect in several countries and regions on 2010 and thereafter
- 2011 NACS Annual Fuels Report