Jump to content

Alkaline earth metal

From Wikipedia, the free encyclopedia
(Redirected from Alkaline Earth Metal)
Not to be confused with Alkali metal.
Alkaline earth metals
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
alkali metals ←    → group 3
IUPAC group number 2
Name by element beryllium group
Trivial name alkaline earth metals
CAS group number
(US, pattern A-B-A)
 IIA
old IUPAC number
(Europe, pattern A-B)
 IIA
↓ Period
2
Image: Lump of beryllium
Beryllium (Be)
4
3
Image: Magnesium crystals
Magnesium (Mg)
12
4
Image: Calcium stored under argon atmosphere
Calcium (Ca)
20
5
Image: Strontium floating in paraffin oil
Strontium (Sr)
38
6
Image: Barium stored under argon atmosphere
Barium (Ba)
56
7
Image: Radium electroplated on copper foil and covered with polyurethane to prevent reaction with air
Radium (Ra)
88

Legend

primordial element
element by radioactive decay

The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).[1] The elements have very similar properties: they are all shiny, silvery-white, somewhat reactive metals at standard temperature and pressure.[2]

Together with helium, these elements have in common an outer s orbital which is full[2][3][4]—that is, this orbital contains its full complement of two electrons, which the alkaline earth metals readily lose to form cations with charge +2, and an oxidation state of +2.[5] Helium is grouped with the noble gases and not with the alkaline earth metals, but it is theorized to have some similarities to beryllium when forced into bonding and has sometimes been suggested to belong to group 2.[6][7][8]

All the discovered alkaline earth metals occur in nature, although radium occurs only through the decay chain of uranium and thorium and not as a primordial element.[9] There have been experiments, all unsuccessful, to try to synthesize element 120, the next potential member of the group.

Characteristics

[edit]

Chemical

[edit]

As with other groups, the members of this family show patterns in their electronic configuration, especially the outermost shells, resulting in trends in chemical behavior:

Z Element No. of electrons/shell Electron configuration[n 1]
4 beryllium 2, 2 [He] 2s2
12 magnesium 2, 8, 2 [Ne] 3s2
20 calcium 2, 8, 8, 2 [Ar] 4s2
38 strontium 2, 8, 18, 8, 2 [Kr] 5s2
56 barium 2, 8, 18, 18, 8, 2 [Xe] 6s2
88 radium 2, 8, 18, 32, 18, 8, 2 [Rn] 7s2

Most of the chemistry has been observed only for the first five members of the group. The chemistry of radium is not well-established due to its radioactivity;[2] thus, the presentation of its properties here is limited.

The alkaline earth metals are all silver-colored and soft, and have relatively low densities, melting points, and boiling points. In chemical terms, all of the alkaline earth metals react with the halogens to form the alkaline earth metal halides, all of which are ionic crystalline compounds (except for beryllium chloride, beryllium bromide and beryllium iodide, which are covalent). All the alkaline earth metals except beryllium also react with water to form strongly alkaline hydroxides and, thus, should be handled with great care. The heavier alkaline earth metals react more vigorously than the lighter ones.[2] The alkaline earth metals have the second-lowest first ionization energies in their respective periods of the periodic table[4] because of their somewhat low effective nuclear charges and the ability to attain a full outer shell configuration by losing just two electrons. The second ionization energy of all of the alkaline metals is also somewhat low.[2][4]

Beryllium is an exception: It does not react with water or steam unless at very high temperatures,[10] and its halides are covalent. If beryllium did form compounds with an ionization state of +2, it would polarize electron clouds that are near it very strongly and would cause extensive orbital overlap, since beryllium has a high charge density. All compounds that include beryllium have a covalent bond.[11] Even the compound beryllium fluoride, which is the most ionic beryllium compound, has a low melting point and a low electrical conductivity when melted.[12][13][14]

All the alkaline earth metals have two electrons in their valence shell, so the energetically preferred state of achieving a filled electron shell is to lose two electrons to form doubly charged positive ions.

Compounds and reactions

[edit]

The alkaline earth metals all react with the halogens to form ionic halides, such as calcium chloride (CaCl
2), as well as reacting with oxygen to form oxides such as strontium oxide (SrO). Calcium, strontium, and barium react with water to produce hydrogen gas and their respective hydroxides (magnesium also reacts, but much more slowly), and also undergo transmetalation reactions to exchange ligands.

Solubility-related constants for alkaline-earth-metal fluorides
Metal M2+ hydration (-MJ/mol) [15] "MF2" unit hydration (-MJ/mol)[16] MF2 lattice (-MJ/mol)[17] Solubility (mol/kL)[18]
Be 2.455 3.371 3.526 soluble
Mg 1.922 2.838 2.978 1.2
Ca 1.577 2.493 2.651 0.2
Sr 1.415 2.331 2.513 0.8
Ba 1.361 2.277 2.373 6

Physical and atomic

[edit]
Key physical and atomic properties of the alkaline earth metals
Alkaline earth metal Standard atomic weight
(u)[n 2][20][21] 		Melting point
(K) 		Melting point
(°C) 		Boiling point
(K)[4] 		Boiling point
(°C)[4] 		Density
(g/cm3)[22] 		Electronegativity
(Pauling) 		First ionization energy
(kJ·mol−1)		 Covalent radius
(pm)[23] 		Flame test color
Beryllium 9.012182(3) 1560 1287 2744 2471 1.845 1.57 899.5 105 White[24]
Magnesium 24.3050(6) 923 650 1363 1090 1.737 1.31 737.7 150 Brilliant-white[2]
Calcium 40.078(4) 1115 842 1757 1484 1.526 1.00 589.8 180 Brick-red[2]
Strontium 87.62(1) 1050 777 1655 1382 2.582 0.95 549.5 200 Crimson[2]
Barium 137.327(7) 1000 727 2170 1897 3.594 0.89 502.9 215 Apple-green[2]
Radium [226][n 3] 969 696 2010 1737 5.502 0.9 509.3 221 Crimson red[n 4]

Nuclear stability

[edit]

Isotopes of all six alkaline earth metals are present in the Earth's crust and the solar system at varying concentrations, dependent upon the nuclides' half lives and, hence, their nuclear stabilities. The first five have one, three, five, four, and six stable (or observationally stable) isotopes respectively, for a total of 19 stable nuclides, as listed here: beryllium-9; magnesium-24, -25, -26; calcium-40, -42, -43, -44, -46; strontium-84, -86, -87, -88; barium-132, -134, -135, -136, -137, -138. The four underlined isotopes in the list are predicted by radionuclide decay energetics to be only observationally stable and to decay with extremely long half-lives through double-beta decay, though no decays attributed definitively to these isotopes have yet been observed as of 2024. Radium has no stable nor primordial isotopes.

In addition to the stable species, calcium and barium each have one extremely long-lived and primordial radionuclide: calcium-48 and barium-130, with half-lives of 5.6×1019 and 1.6×1021 years, respectively. Both are far longer than the current age of the universe (4.7× and 117× billion times longer, respectively) and less than one part per ten billion has decayed since the formation of the Earth. The two isotopes are stable for practical purposes.

Apart from the 21 stable or nearly-stable isotopes, the six alkaline earth elements each possess a large number of known radioisotopes. None of the isotopes other than the aforementioned 21 are primordial: all have half lives too short for even a single atom to have survived since the solar system's formation, after the seeding of heavy nuclei by nearby supernovae and collisions between neutron stars, and any present are derived from ongoing natural processes. Beryllium-7, beryllium-10, and calcium-41 are trace, as well as cosmogenic, nuclides, formed by the impact of cosmic rays with atmospheric or crustal atoms. The longest half-lives among them are 1.387 million years for beryllium-10, 99.4 thousand years for calcium-41, 1599 years for radium-226 (radium's longest-lived isotope), 28.90 years for strontium-90, 10.51 years for barium-133, and 5.75 years for radium-228. All others have half-lives of less than half a year, most significantly shorter.

Calcium-48 and barium-130, the two primordial and non-stable isotopes, decay only through double beta emission[n 5] and have extremely long half-lives, by virtue of the extremely low probability of both beta decays occurring at the same time. All isotopes of radium are highly radioactive and are primarily generated through the decay of heavier radionuclides. The longest-lived of them is radium-226, a member of the decay chain of uranium-238.[27] Strontium-90 and barium-140 are common fission products of uranium in nuclear reactors, accounting for 5.73% and 6.31% of uranium-235's fission products respectively when bombarded by thermal neutrons.[28] The two isotopes have half-lives each of 28.90 years and 12.7 days. Strontium-90 is produced in appreciable quantities in operating nuclear reactors running on uranium-235 or plutonium-239 fuel, and a minuscule secular equilibrium concentration is also present due to rare spontaneous fission decays in naturally occurring uranium.

Calcium-48 is the lightest nuclide known to undergo double beta decay.[29] Naturally occurring calcium and barium are very weakly radioactive: calcium contains about 0.1874% calcium-48,[30] and barium contains about 0.1062% barium-130.[31] On average, one double-beta decay of calcium-48 will occur per second for every 90 tons of natural calcium, or 230 tons of limestone (calcium carbonate).[32] Through the same decay mechanism, one decay of barium-130 will occur per second for every 16,000 tons of natural barium, or 27,000 tons of baryte (barium sulfate).[33]

The longest lived isotope of radium is radium-226 with a half-life of 1600 years; it along with radium-223, -224, and -228 occur naturally in the decay chains of primordial thorium and uranium. Beryllium-8 is notable by its absence as it splits in half virtually instantaneously into two alpha particles whenever it is formed. The triple alpha process in stars can only occur at energies high enough for beryllium-8 to fuse with a third alpha particle before it can decay, forming carbon-12. This thermonuclear rate-limiting bottleneck is the reason most main sequence stars spend billions of years fusing hydrogen within their cores, and only rarely manage to fuse carbon before collapsing into a stellar remnant, and even then merely for a timescale of ~1000 years.[34] The radioisotopes of alkaline earth metals tend to be "bone seekers" as they behave chemically similar to calcium, an integral component of hydroxyapatite in compact bone, and gradually accumulate in the human skeleton. The incorporated radionuclides inflict significant damage to the bone marrow over time through the emission of ionizing radiation, primarily alpha particles. This property is made use of in a positive manner in the radiotherapy of certain bone cancers, since the radionuclides' chemical properties causes them to preferentially target cancerous growths in bone matter, leaving the rest of the body relatively unharmed.

Compared to their neighbors in the periodic table, alkaline earth metals tend to have a larger number of stable isotopes as they all possess an even number of protons, owing to their status as group 2 elements. Their isotopes are generally more stable due to nucleon pairing. This stability is further enhanced if the isotope also has an even number of neutrons, as both kinds of nucleons can then participate in pairing and contribute to nuclei stability.

History

[edit]

Etymology

[edit]

The alkaline earth metals are named after their oxides, the alkaline earths, whose old-fashioned names were beryllia, magnesia, lime, strontia, and baria. These oxides are basic (alkaline) when combined with water. "Earth" was a term applied by early chemists to nonmetallic substances that are insoluble in water and resistant to heating—properties shared by these oxides. The realization that these earths were not elements but compounds is attributed to the chemist Antoine Lavoisier. In his Traité Élémentaire de Chimie (Elements of Chemistry) of 1789 he called them salt-forming earth elements. Later, he suggested that the alkaline earths might be metal oxides, but admitted that this was mere conjecture. In 1808, acting on Lavoisier's idea, Humphry Davy became the first to obtain samples of the metals by electrolysis of their molten earths,[35] thus supporting Lavoisier's hypothesis and causing the group to be named the alkaline earth metals.

Discovery

[edit]

The calcium compounds calcite and lime have been known and used since prehistoric times.[36] The same is true for the beryllium compounds beryl and emerald.[37] The other compounds of the alkaline earth metals were discovered starting in the early 15th century. The magnesium compound magnesium sulfate was first discovered in 1618 by a farmer at Epsom in England. Strontium carbonate was discovered in minerals in the Scottish village of Strontian in 1790. The last element is the least abundant: radioactive radium, which was extracted from uraninite in 1898.[38][39][40]

All elements except beryllium were isolated by electrolysis of molten compounds. Magnesium, calcium, and strontium were first produced by Humphry Davy in 1808, whereas beryllium was independently isolated by Friedrich Wöhler and Antoine Bussy in 1828 by reacting beryllium compounds with potassium. In 1910, radium was isolated as a pure metal by Curie and André-Louis Debierne also by electrolysis.[38][39][40]

Beryllium

[edit]
Emerald is a form of beryl, the principal mineral of beryllium.

Beryl, a mineral that contains beryllium, has been known since the time of the Ptolemaic Kingdom in Egypt.[37] Although it was originally thought that beryl was an aluminum silicate,[41] beryl was later found to contain a then-unknown element when, in 1797, Louis-Nicolas Vauquelin dissolved aluminum hydroxide from beryl in an alkali.[42] In 1828, Friedrich Wöhler[43] and Antoine Bussy[44] independently isolated this new element, beryllium, by the same method, which involved a reaction of beryllium chloride with metallic potassium; this reaction was not able to produce large ingots of beryllium.[45] It was not until 1898, when Paul Lebeau performed an electrolysis of a mixture of beryllium fluoride and sodium fluoride, that large pure samples of beryllium were produced.[45]

Magnesium

[edit]

Magnesium was first produced by Humphry Davy in England in 1808 using electrolysis of a mixture of magnesia and mercuric oxide.[46] Antoine Bussy prepared it in coherent form in 1831. Davy's first suggestion for a name was magnium,[46] but the name magnesium is now used.

Calcium

[edit]

Lime has been used as a material for building since 7000 to 14,000 BCE,[36] and kilns used for lime have been dated to 2,500 BCE in Khafaja, Mesopotamia.[47][48] Calcium as a material has been known since at least the first century, as the ancient Romans were known to have used calcium oxide by preparing it from lime. Calcium sulfate has been known to be able to set broken bones since the tenth century. Calcium itself, however, was not isolated until 1808, when Humphry Davy, in England, used electrolysis on a mixture of lime and mercuric oxide,[49] after hearing that Jöns Jakob Berzelius had prepared a calcium amalgam from the electrolysis of lime in mercury.

Strontium

[edit]

In 1790, physician Adair Crawford discovered ores with distinctive properties, which were named strontites in 1793 by Thomas Charles Hope, a chemistry professor at the University of Glasgow,[50] who confirmed Crawford's discovery. Strontium was eventually isolated in 1808 by Humphry Davy by electrolysis of a mixture of strontium chloride and mercuric oxide. The discovery was announced by Davy on 30 June 1808 at a lecture to the Royal Society.[51]

Barium

[edit]
Barite, the material that was first found to contain barium.

Barite, a mineral containing barium, was first recognized as containing a new element in 1774 by Carl Scheele, although he was able to isolate only barium oxide. Barium oxide was isolated again two years later by Johan Gottlieb Gahn. Later in the 18th century, William Withering noticed a heavy mineral in the Cumberland lead mines, which are now known to contain barium. Barium itself was finally isolated in 1808 when Humphry Davy used electrolysis with molten salts, and Davy named the element barium, after baryta. Later, Robert Bunsen and Augustus Matthiessen isolated pure barium by electrolysis of a mixture of barium chloride and ammonium chloride.[52][53]

Radium

[edit]

While studying uraninite, on 21 December 1898, Marie and Pierre Curie discovered that, even after uranium had decayed, the material created was still radioactive. The material behaved somewhat similarly to barium compounds, although some properties, such as the color of the flame test and spectral lines, were much different. They announced the discovery of a new element on 26 December 1898 to the French Academy of Sciences.[54] Radium was named in 1899 from the word radius, meaning ray, as radium emitted power in the form of rays.[55]

Occurrence

[edit]
Series of alkaline earth metals.

Beryllium occurs in the Earth's crust at a concentration of two to six parts per million (ppm),[56] much of which is in soils, where it has a concentration of six ppm. Beryllium is one of the rarest elements in seawater, even rarer than elements such as scandium, with a concentration of 0.2 parts per trillion.[57][58] However, in freshwater, beryllium is somewhat more common, with a concentration of 0.1 parts per billion.[59]

Magnesium and calcium are very common in the Earth's crust, being respectively the fifth and eighth most abundant elements. None of the alkaline earth metals are found in their elemental state. Common magnesium-containing minerals are carnallite, magnesite, and dolomite. Common calcium-containing minerals are chalk, limestone, gypsum, and anhydrite.[2]

Strontium is the 15th most abundant element in the Earth's crust. The principal minerals are celestite and strontianite.[60] Barium is slightly less common, much of it in the mineral barite.[61]

Radium, being a decay product of uranium, is found in all uranium-bearing ores.[62] Due to its relatively short half-life,[63] radium from the Earth's early history has decayed, and present-day samples have all come from the much slower decay of uranium.[62]

Production

[edit]
Emerald, colored green with trace amounts of chromium, is a variety of the mineral beryl which is beryllium aluminum silicate.

Most beryllium is extracted from beryllium hydroxide. One production method is sintering, done by mixing beryl, sodium fluorosilicate, and soda at high temperatures to form sodium fluoroberyllate, aluminum oxide, and silicon dioxide. A solution of sodium fluoroberyllate and sodium hydroxide in water is then used to form beryllium hydroxide by precipitation. Alternatively, in the melt method, powdered beryl is heated to high temperature, cooled with water, then heated again slightly in sulfuric acid, eventually yielding beryllium hydroxide. The beryllium hydroxide from either method then produces beryllium fluoride and beryllium chloride through a somewhat long process. Electrolysis or heating of these compounds can then produce beryllium.[11]

In general, strontium carbonate is extracted from the mineral celestite through two methods: by leaching the celestite with sodium carbonate, or in a more complicated way involving coal.[64]

To produce barium, barite (impure barium sulfate) is converted to barium sulfide by carbothermic reduction (such as with coke). The sulfide is water-soluble and easily reacted to form pure barium sulfate, used for commercial pigments, or other compounds, such as barium nitrate. These in turn are calcined into barium oxide, which eventually yields pure barium after reduction with aluminum.[61] The most important supplier of barium is China, which produces more than 50% of world supply.[65]

Applications

[edit]

Beryllium is used mainly in military applications,[66] but non-military uses exist. In electronics, beryllium is used as a p-type dopant in some semiconductors,[67] and beryllium oxide is used as a high-strength electrical insulator and heat conductor.[68] Beryllium alloys are used for mechanical parts when stiffness, light weight, and dimensional stability are required over a wide temperature range.[69][70] Beryllium-9 is used in small-scale neutron sources that use the reaction 9Be + 4He (α) → 12C + 1n, the reaction used by James Chadwick when he discovered the neutron. Its low atomic weight and low neutron absorption cross-section would make beryllium suitable as a neutron moderator, but its high price and the readily available alternatives such as water, heavy water and nuclear graphite have limited this to niche applications. In the FLiBe eutectic used in molten salt reactors, beryllium's role as a moderator is more incidental than the desired property leading to its use.

Magnesium has many uses. It offers advantages over other structural materials such as aluminum, but magnesium's usage is hindered by its flammability.[71] Magnesium is often alloyed with aluminum, zinc and manganese to increase its strength and corrosion resistance.[72] Magnesium has many other industrial applications, such as its role in the production of iron and steel,[further explanation needed] and in the Kroll process for production of titanium.[73]

Calcium is used as a reducing agent in the separation of other metals such as uranium from ore. It is a major component of many alloys, especially aluminum and copper alloys, and is also used to deoxidize alloys. Calcium has roles in the making of cheese, mortars, and cement.[74]

Strontium and barium have fewer applications than the lighter alkaline earth metals. Strontium carbonate is used in the manufacturing of red fireworks.[75] Pure strontium is used in the study of neurotransmitter release in neurons.[76][77] Radioactive strontium-90 finds some use in RTGs,[78][79] which utilize its decay heat. Barium is used in vacuum tubes as a getter to remove gases.[61] Barium sulfate has many uses in the petroleum industry,[4][80] and other industries.[4][61][81]

Radium has many former applications based on its radioactivity, but its use is no longer common because of the adverse health effects and long half-life. Radium was frequently used in luminous paints,[82] although this use was stopped after it sickened workers.[83] The nuclear quackery that alleged health benefits of radium formerly led to its addition to drinking water, toothpaste, and many other products.[71] Radium is no longer used even when its radioactive properties are desired because its long half-life makes safe disposal challenging. For example, in brachytherapy, shorter-lived alternatives such as iridium-192 are usually used instead.[84][85]

Representative reactions of alkaline earth metals

[edit]

Reaction with halogens

Ca + Cl2 → CaCl2

Anhydrous calcium chloride is a hygroscopic substance that is used as a desiccant. Exposed to air, it will absorb water vapour from the air, forming a solution. This property is known as deliquescence.

Reaction with oxygen

Ca + 1/2O2 → CaO
Mg + 1/2O2 → MgO

Reaction with sulfur

Ca + 1/8S8 → CaS

Reaction with carbon

With carbon, they form acetylides directly. Beryllium forms carbide.

2Be + C → Be2C
CaO + 3C → CaC2 + CO (at 2500 °C in furnace)
CaC2 + 2H2O → Ca(OH)2 + C2H2
Mg2C3 + 4H2O → 2Mg(OH)2 + C3H4

Reaction with nitrogen

Only Be and Mg form nitrides directly.

3Be + N2 → Be3N2
3Mg + N2 → Mg3N2

Reaction with hydrogen

Alkaline earth metals react with hydrogen to generate saline hydride that are unstable in water.

Ca + H2 → CaH2

Reaction with water

Ca, Sr, and Ba readily react with water to form hydroxide and hydrogen gas. Be and Mg are passivated by an impervious layer of oxide. However, amalgamated magnesium will react with water vapor.

Mg + H2O → MgO + H2

Reaction with acidic oxides

Alkaline earth metals reduce the nonmetal from its oxide.

2Mg + SiO2 → 2MgO + Si
2Mg + CO2 → 2MgO + C (in solid carbon dioxide)

Reaction with acids

Mg + 2HCl → MgCl2 + H2
Be + 2HCl → BeCl2 + H2

Reaction with bases

Be exhibits amphoteric properties. It dissolves in concentrated sodium hydroxide.

Be + NaOH + 2H2O → Na[Be(OH)3] + H2

Reaction with alkyl halides

Magnesium reacts with alkyl halides via an insertion reaction to generate Grignard reagents.

RX + Mg → RMgX (in anhydrous ether)

Identification of alkaline earth cations

[edit]

The flame test

The table below[86] presents the colors observed when the flame of a Bunsen burner is exposed to salts of alkaline earth metals. Be and Mg do not impart colour to the flame due to their small size.[87]

Metal Colour
Ca Brick-red
Sr Crimson red
Ba Green/Yellow
Ra Carmine red

In solution

Mg2+

Disodium phosphate is a very selective reagent for magnesium ions and, in the presence of ammonium salts and ammonia, forms a white precipitate of ammonium magnesium phosphate.

Mg2+ + NH3 + Na2HPO4 → (NH4)MgPO4 + 2Na+

Ca2+

Ca2+ forms a white precipitate with ammonium oxalate. Calcium oxalate is insoluble in water, but is soluble in mineral acids.

Ca2+ + (COO)2(NH4)2 → (COO)2Ca + NH4+

Sr2+

Strontium ions precipitate with soluble sulfate salts.

Sr2+ + Na2SO4 → SrSO4 + 2Na+

All ions of alkaline earth metals form white precipitate with ammonium carbonate in the presence of ammonium chloride and ammonia.

Compounds of alkaline earth metals

[edit]

Oxides

The alkaline earth metal oxides are formed from the thermal decomposition of the corresponding carbonates.

CaCO3 → CaO + CO2 (at approx. 900°C)

In laboratory, they are obtained from hydroxides:

Mg(OH)2 → MgO + H2O

or nitrates:

Ca(NO3)2 → CaO + 2NO2 + 1/2O2

The oxides exhibit basic character: they turn phenolphthalein red and litmus, blue. They react with water to form hydroxides in an exothermic reaction.

CaO + H2O → Ca(OH)2 + Q

Calcium oxide reacts with carbon to form acetylide.

CaO + 3C → CaC2 + CO (at 2500°C)
CaC2 + N2 → CaCN2 + C
CaCN2 + H2SO4 → CaSO4 + H2N—CN
H2N—CN + H2O → (H2N)2CO (urea)
CaCN2 + 2H2O → CaCO3 + NH3

Hydroxides

They are generated from the corresponding oxides on reaction with water. They exhibit basic character: they turn phenolphthalein pink and litmus, blue. Beryllium hydroxide is an exception as it exhibits amphoteric character.

Be(OH)2 + 2HCl → BeCl2 + 2 H2O
Be(OH)2 + NaOH → Na[Be(OH)3]

Salts

Ca and Mg are found in nature in many compounds such as dolomite, aragonite, magnesite (carbonate rocks). Calcium and magnesium ions are found in hard water. Hard water represents a multifold issue. It is of great interest to remove these ions, thus softening the water. This procedure can be done using reagents such as calcium hydroxide, sodium carbonate or sodium phosphate. A more common method is to use ion-exchange aluminosilicates or ion-exchange resins that trap Ca2+ and Mg2+ and liberate Na+ instead:

Na2O·Al2O3·6SiO2 + Ca2+ → CaO·Al2O3·6SiO2 + 2Na+

Biological role and precautions

[edit]

Magnesium and calcium are ubiquitous and essential to all known living organisms. They are involved in more than one role, with, for example, magnesium or calcium ion pumps playing a role in some cellular processes, magnesium functioning as the active center in some enzymes, and calcium salts taking a structural role, most notably in bones.

Strontium plays an important role in marine aquatic life, especially hard corals, which use strontium to build their exoskeletons. It and barium have some uses in medicine, for example "barium meals" in radiographic imaging, whilst strontium compounds are employed in some toothpastes. Excessive amounts of strontium-90 are toxic due to its radioactivity and strontium-90 mimics calcium (i.e. Behaves as a "bone seeker") where it bio-accumulates with a significant biological half life. While the bones themselves have higher radiation tolerance than other tissues, the rapidly dividing bone marrow does not and can thus be significantly harmed by Sr-90. The effect of ionizing radiation on bone marrow is also the reason why acute radiation syndrome can have anemia-like symptoms and why donation of red blood cells can increase survivability.

Beryllium and radium, however, are toxic. Beryllium's low aqueous solubility means it is rarely available to biological systems; it has no known role in living organisms and, when encountered by them, is usually highly toxic.[11] Radium has a low availability and is highly radioactive, making it toxic to life.

Extensions

[edit]

The next alkaline earth metal after radium is thought to be element 120, although this may not be true due to relativistic effects.[88] The synthesis of element 120 was first attempted in March 2007, when a team at the Flerov Laboratory of Nuclear Reactions in Dubna bombarded plutonium-244 with iron-58 ions; however, no atoms were produced, leading to a limit of 400 fb for the cross-section at the energy studied.[89] In April 2007, a team at the GSI attempted to create element 120 by bombarding uranium-238 with nickel-64, although no atoms were detected, leading to a limit of 1.6 pb for the reaction. Synthesis was again attempted at higher sensitivities, although no atoms were detected. Other reactions have been tried, although all have been met with failure.[90]

The chemistry of element 120 is predicted to be closer to that of calcium or strontium[91] instead of barium or radium. This noticeably contrasts with periodic trends, which would predict element 120 to be more reactive than barium and radium. This lowered reactivity is due to the expected energies of element 120's valence electrons, increasing element 120's ionization energy and decreasing the metallic and ionic radii.[91]

The next alkaline earth metal after element 120 has not been definitely predicted. Although a simple extrapolation using the Aufbau principle would suggest that element 170 is a congener of 120, relativistic effects may render such an extrapolation invalid. The next element with properties similar to the alkaline earth metals has been predicted to be element 166, though due to overlapping orbitals and lower energy gap below the 9s subshell, element 166 may instead be placed in group 12, below copernicium.[92][93]

See also

[edit]

Explanatory notes

[edit]
  1. ^ Noble gas notation is used for conciseness; the nearest noble gas that precedes the element in question is written first, and then the electron configuration is continued from that point forward.
  2. ^ The number given in parentheses refers to the measurement uncertainty. This uncertainty applies to the least significant figure(s) of the number prior to the parenthesized value (i.e., counting from rightmost digit to left). For instance, 1.00794(7) stands for 1.00794±0.00007, whereas 1.00794(72) stands for 1.00794±0.00072.[19]
  3. ^ The element does not have any stable nuclides, and a value in brackets indicates the mass number of the longest-lived isotope of the element.[20][21]
  4. ^ The color of the flame test of pure radium has never been observed; the crimson-red color is an extrapolation from the flame test color of its compounds.[25]
  5. ^ Calcium-48 is theoretically capable of single beta decay, but such process has never been observed.[26]

References

[edit]
  1. ^ International Union of Pure and Applied Chemistry (2005). Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005). Cambridge (UK): RSC–IUPAC. ISBN 0-85404-438-8. pp. 51. Electronic version..
  2. ^ a b c d e f g h i j Royal Society of Chemistry. "Visual Elements: Group 2–The Alkaline Earth Metals". Visual Elements. Royal Society of Chemistry. Archived from the original on 5 October 2011. Retrieved 13 January 2012.
  3. ^ "Periodic Table: Atomic Properties of the Elements" (PDF). nist.gov. National Institute of Standards and Technology. September 2010. Archived (PDF) from the original on 2012-08-09. Retrieved 17 February 2012.
  4. ^ a b c d e f g Lide, D. R., ed. (2003). CRC Handbook of Chemistry and Physics (84th ed.). Boca Raton, FL: CRC Press.
  5. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  6. ^ Grochala, Wojciech (1 November 2017). "On the position of helium and neon in the Periodic Table of Elements". Foundations of Chemistry. 20 (2018): 191–207. doi:10.1007/s10698-017-9302-7.
  7. ^ Bent Weberg, Libby (18 January 2019). ""The" periodic table". Chemical & Engineering News. 97 (3). Archived from the original on 1 February 2020. Retrieved 27 March 2020.
  8. ^ Grandinetti, Felice (23 April 2013). "Neon behind the signs". Nature Chemistry. 5 (2013): 438. Bibcode:2013NatCh...5..438G. doi:10.1038/nchem.1631. PMID 23609097.
  9. ^ "Abundance in Earth's Crust". WebElements.com. Archived from the original on 9 March 2007. Retrieved 14 April 2007.
  10. ^ Clark, Jim (December 2021). "Reactions of the Group 2 elements with water". Retrieved 2012-08-14. 'Beryllium has no reaction with water or steam even at red heat.' This was commonly quoted in textbooks....However, a researcher...sent me a photo showing the result of exposing beryllium to steam at 800°C. It definitely reacts. I think the problem is that beryllium is both expensive and carries major health risks....Textbook (or these days, web) statements about it never get checked.
  11. ^ a b c Jakubke, Hans-Dieter; Jeschkeit, Hans, eds. (1994). Concise Encyclopedia Chemistry. trans. rev. Eagleson, Mary. Berlin: Walter de Gruyter.
  12. ^ Bell, N. A. (1972). "Beryllium halide and pseudohalides". In Emeléus, Harry Julius; Sharpe, A. G. (eds.). Advances in inorganic chemistry and radiochemistry, Volume 14. New York: Academic Press. pp. 256–277. ISBN 978-0-12-023614-5.
  13. ^ Walsh, Kenneth A. (2009-08-01). Beryllium chemistry and processing. ASM International. pp. 99–102, 118–119. ISBN 978-0-87170-721-5.
  14. ^ Hertz, Raymond K. (1987). "General analytical chemistry of beryllium". In Coyle, Francis T. (ed.). Chemical analysis of metals: a symposium. ASTM. pp. 74–75. ISBN 978-0-8031-0942-1.
  15. ^ Wiberg, Wiberg & Holleman 2001, pp. XXXVI–XXXVII.
  16. ^ Wiberg, Wiberg & Holleman 2001, p. XXXVI.
  17. ^ Lide 2004, p. 12-23.
  18. ^ Wiberg, Wiberg & Holleman 2001, p. 1073.
  19. ^ "Standard Uncertainty and Relative Standard Uncertainty". CODATA reference. National Institute of Standards and Technology. Archived from the original on 16 October 2011. Retrieved 26 September 2011.
  20. ^ a b Wieser, Michael E.; Berglund, Michael (2009). "Atomic weights of the elements 2007 (IUPAC Technical Report)" (PDF). Pure Appl. Chem. 81 (11). IUPAC: 2131–2156. doi:10.1351/PAC-REP-09-08-03. S2CID 98084907. Archived (PDF) from the original on 2 November 2012. Retrieved 7 February 2012.
  21. ^ a b Wieser, Michael E.; Coplen, Tyler B. (2011). "Atomic weights of the elements 2009 (IUPAC Technical Report)" (PDF). Pure Appl. Chem. 83 (2). IUPAC: 359–396. doi:10.1351/PAC-REP-10-09-14. S2CID 95898322. Archived (PDF) from the original on 11 February 2012. Retrieved 11 February 2012.
  22. ^ Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
  23. ^ Slater, J. C. (1964). "Atomic Radii in Crystals". Journal of Chemical Physics. 41 (10): 3199–3205. Bibcode:1964JChPh..41.3199S. doi:10.1063/1.1725697.
  24. ^ Jensen, William B. (2003). "The Place of Zinc, Cadmium, and Mercury in the Periodic Table" (PDF). Journal of Chemical Education. 80 (8). American Chemical Society: 952–961. Bibcode:2003JChEd..80..952J. doi:10.1021/ed080p952. Archived from the original (PDF) on 2010-06-11. Retrieved 2012-05-06.
  25. ^ Kirby, H. W; Salutsky, Murrell L (1964). The Radiochemistry of Radium. National Academies Press.[permanent dead link‍]
  26. ^ Belli, P.; Bernabei, R.; Danevich, F. A.; et al. (2019). "Experimental searches for rare alpha and beta decays". European Physical Journal A. 55 (8): 140–1–140–7. arXiv:1908.11458. Bibcode:2019EPJA...55..140B. doi:10.1140/epja/i2019-12823-2. ISSN 1434-601X. S2CID 201664098.
  27. ^ "Uranium-235 and Uranium-238 | Hazardous Waste Cleanup Levels | Washington University in St. Louis". sites.wustl.edu. Retrieved 2024-01-18.
  28. ^ "Nuclear Data for Safeguards". www-nds.iaea.org. Retrieved 2024-01-18.
  29. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  30. ^ Richard B. Firestone (15 March 2010). "Isotopes of Calcium (Z=20)". Lawrence Berkeley National Laboratory. Archived from the original on 6 May 2012. Retrieved 12 June 2012.
  31. ^ Richard B. Firestone (15 March 2010). "Isotopes of Barium (Z=56)". Lawrence Berkeley National Laboratory. Archived from the original on 6 May 2012. Retrieved 12 June 2012.
  32. ^ "1/(1.87e-3*1000/40.078*6.02e 23*ln2*1/(5.6e 19y/s))*1e-3*100.0869/40.078 - Wolfram|Alpha". www.wolframalpha.com. Retrieved 2024-01-18.
  33. ^ "1/(1.06e-3*1000/137.327*6.02e 23*ln2*1/(1.6e 21y/s))*1e-3*233.38/137.327 - Wolfram|Alpha". www.wolframalpha.com. Retrieved 2024-01-18.
  34. ^ "Lecture 7: Basics of SF Stellar Nucleosynthesis" (PDF). www2.mpia-hd.mpg.de.
  35. ^ Robert E. Krebs (2006). The history and use of our earth's chemical elements: a reference guide. Greenwood Publishing Group. pp. 65–81. ISBN 0-313-33438-2.
  36. ^ a b Miller, M. Michael. "Commodity report:Lime" (PDF). United States Geological Survey. Archived (PDF) from the original on 2011-11-12. Retrieved 2012-03-06.
  37. ^ a b Weeks 1968, p. 535.
  38. ^ a b Weeks, Mary Elvira (1932). "The discovery of the elements. X. The alkaline earth metals and magnesium and cadmium". Journal of Chemical Education. 9 (6): 1046. Bibcode:1932JChEd...9.1046W. doi:10.1021/ed009p1046.
  39. ^ a b Weeks, Mary Elvira (1932). "The discovery of the elements. XII. Other elements isolated with the aid of potassium and sodium: Beryllium, boron, silicon, and aluminum". Journal of Chemical Education. 9 (8): 1386. Bibcode:1932JChEd...9.1386W. doi:10.1021/ed009p1386.
  40. ^ a b Weeks, Mary Elvira (1933). "The discovery of the elements. XIX. The radioactive elements". Journal of Chemical Education. 10 (2): 79. Bibcode:1933JChEd..10...79W. doi:10.1021/ed010p79.
  41. ^ Weeks 1968, p. 537.
  42. ^ Vauquelin, Louis-Nicolas (1798). "De l'Aiguemarine, ou Béril; et découverie d'une terre nouvelle dans cette pierre". Annales de Chimie (26): 155–169. Archived from the original on 2016-04-27.
  43. ^ Wöhler, Friedrich (1828). "Ueber das Beryllium und Yttrium". Annalen der Physik. 89 (8): 577–582. Bibcode:1828AnP....89..577W. doi:10.1002/andp.18280890805.
  44. ^ Bussy, Antoine (1828). "D'une travail qu'il a entrepris sur le glucinium". Journal de Chimie Médicale (4): 456–457. Archived from the original on 2016-05-22.
  45. ^ a b Weeks 1968, p. 539.
  46. ^ a b Davy, H. (1808). "Electro-chemical researches on the decomposition of the earths; with observations on the metals obtained from the alkaline earths, and on the amalgam procured from ammonia". Philosophical Transactions of the Royal Society of London. 98: 333–370. Bibcode:1808RSPT...98..333D. doi:10.1098/rstl.1808.0023. JSTOR 107302. S2CID 96364168. Archived from the original on 2015-09-30.
  47. ^ Williams, Richard (2004). Lime Kilns and Lime Burning. Bloomsbury USA. p. 4. ISBN 978-0-7478-0596-0.[permanent dead link‍]
  48. ^ Oates, J. A. H (2008-07-01). Lime and Limestone: Chemistry and Technology, Production and Uses. Wiley. ISBN 978-3-527-61201-7.
  49. ^ Davy H (1808). "Electro-chemical researches on the decomposition of the earths; with observations on the metals obtained from the alkaline earths, and on the amalgam procured from ammonia". Philosophical Transactions of the Royal Society of London. 98: 333–370. Bibcode:1808RSPT...98..333D. doi:10.1098/rstl.1808.0023. S2CID 96364168. Archived from the original on 2015-09-30.
  50. ^ Murray, T. (1993). "Elemementary Scots: The Discovery of Strontium". Scottish Medical Journal. 38 (6): 188–189. doi:10.1177/003693309303800611. PMID 8146640. S2CID 20396691.
  51. ^ Davy, Humphry (1808). researches on the decomposition of the earths; with observations on the metals obtained from the alkaline earths, and on the amalgam procured from ammonia. Vol. 98. Philosophical Transactions of the Royal Society of London. pp. 333–370. Archived from the original on 2015-09-30.
  52. ^ "Masthead". Annalen der Chemie und Pharmacie. 93 (3): fmi. 1855. doi:10.1002/jlac.18550930301.
  53. ^ Wagner, Rud.; Neubauer, C.; Deville, H. Sainte-Claire; Sorel; Wagenmann, L.; Techniker; Girard, Aimé (1856). "Notizen". Journal für Praktische Chemie. 67: 490–508. doi:10.1002/prac.18560670194.
  54. ^ Curie, Pierre; Curie, Marie; Bémont, Gustave (1898). "Sur une nouvelle substance fortement radio-active, contenue dans la pechblende (On a new, strongly radioactive substance contained in pitchblende)". Comptes Rendus. 127: 1215–1217. Archived from the original on 2009-08-06. Retrieved 2009-08-01.
  55. ^ "radium". Online Etymology Dictionary. Archived from the original on 13 January 2012. Retrieved 20 August 2011.
  56. ^ O'Neil, Marydale J.; Heckelman, Patricia E.; Roman, Cherie B., eds. (2006). The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals (14th ed.). Whitehouse Station, NJ, US: Merck Research Laboratories, Merck & Co., Inc. ISBN 0-911910-00-X.
  57. ^ Emsley, John (2001). Nature's Building Blocks: An A–Z Guide to the Elements. Oxford, England, UK: Oxford University Press. ISBN 0-19-850340-7.
  58. ^ "Abundance in oceans". Mark Winter, The University of Sheffield and WebElements Ltd, UK. WebElements. Archived from the original on 5 August 2011. Retrieved 6 August 2011.
  59. ^ "Abundance in stream water". Mark Winter, The University of Sheffield and WebElements Ltd, UK. WebElements. Archived from the original on 4 August 2011. Retrieved 6 August 2011.
  60. ^ Ober, Joyce A. "Mineral Commodity Summaries 2010: Strontium" (PDF). United States Geological Survey. Archived (PDF) from the original on 2010-07-16. Retrieved 2010-05-14.
  61. ^ a b c d Kresse, Robert; Baudis, Ulrich; Jäger, Paul; Riechers, H. Hermann; Wagner, Heinz; Winkler, Jocher; Wolf, Hans Uwe (2007). "Barium and Barium Compounds". In Ullman, Franz (ed.). Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH. doi:10.1002/14356007.a03_325.pub2. ISBN 978-3527306732.
  62. ^ a b "Radium" Archived 2012-11-15 at the Wayback Machine, Los Alamos National Laboratory. Retrieved on 2009-08-05.
  63. ^ Malley, Marjorie C (2011-08-25). Radioactivity. Oxford University Press, USA. pp. 115–. ISBN 978-0-19-983178-4. Archived from the original on 2015-09-05.
  64. ^ Kemal, Mevlüt; Arslan, V; Akar, A; Canbazoglu, M (1996). Production of SrCO, by black ash process: Determination of reductive roasting parameters. CRC Press. p. 401. ISBN 9789054108290. Archived from the original on 2016-04-27.
  65. ^ Miller, M. M. "Barite" (PDF). USGS.gov. Archived (PDF) from the original on 2012-07-07.
  66. ^ Petzow, G. N.; Aldinger, F.; Jönsson, S.; Welge, P.; Van Kampen, V.; Mensing, T.; Brüning, T. (2005). "Beryllium and Beryllium Compounds". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a04_011.pub2. ISBN 3527306730. S2CID 262306041.
  67. ^ Diehl, Roland (2000). High-power diode lasers. Springer. p. 104. ISBN 3-540-66693-1.
  68. ^ "Purdue engineers create safer, more efficient nuclear fuel, model its performance". Purdue University. 27 September 2005. Archived from the original on 27 May 2012. Retrieved 18 September 2008.
  69. ^ Davis, Joseph R. (1998). "Beryllium". Metals handbook. ASM International. pp. 690–691. ISBN 978-0-87170-654-6.
  70. ^ Schwartz, Mel M. (2002). Encyclopedia of materials, parts, and finishes. CRC Press. p. 62. ISBN 1-56676-661-3.
  71. ^ a b Gray, Theodore (2009). The Elements: A Visual Exploration of Every Known Atom in the Universe. New York: Black Dog & Leventhal Publishers. ISBN 978-1-57912-814-2. [dead link‍]
  72. ^ Baker, Hugh D. R.; Avedesian, Michael (1999). Magnesium and magnesium alloys. Materials Park, OH: Materials Information Society. p. 4. ISBN 0-87170-657-1.
  73. ^ Amundsen, K.; Aune, T. K.; Bakke, P.; Eklund, H. R.; Haagensen, J. Ö.; Nicolas, C.; Rosenkilde, C.; Van Den Bremt, S.; Wallevik, O. (2003). "Magnesium". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a15_559. ISBN 3527306730.
  74. ^ Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton, Florida: CRC Press. ISBN 0-8493-0486-5.
  75. ^ Moreno, Teresa; Querol, Xavier; Alastuey, Andrés; Cruz Minguillón, Mari; Pey, Jorge; Rodriguez, Sergio; Vicente Miró, José; Felis, Carles; Gibbons, Wes (2007). "Recreational atmospheric pollution episodes: Inhalable metalliferous particles from firework displays" (PDF). Atmospheric Environment. 41 (5): 913. Bibcode:2007AtmEn..41..913M. doi:10.1016/j.atmosenv.2006.09.019. hdl:10261/185836.
  76. ^ Miledi, R. (1966). "Strontium as a Substitute for Calcium in the Process of Transmitter Release at the Neuromuscular Junction". Nature. 212 (5067): 1233–4. Bibcode:1966Natur.212.1233M. doi:10.1038/2121233a0. PMID 21090447. S2CID 11109902.
  77. ^ Hagler D.J., Jr; Goda Y. (2001). "Properties of synchronous and asynchronous release during pulse train depression in cultured hippocampal neurons". J. Neurophysiol. 85 (6): 2324–34. doi:10.1152/jn.2001.85.6.2324. PMID 11387379. S2CID 2907823.
  78. ^ Standring, WJF; Selnæs, ØG; Sneve, M; Finne, IE; Hosseini, A; Amundsen, I; Strand, P (2005), Assessment of environmental, health and safety consequences of decommissioning radioisotope thermal generators (RTGs) in Northwest Russia (PDF), Østerås: Norwegian Radiation Protection Authority, archived from the original (PDF) on 2016-03-03, retrieved 2019-03-13
  79. ^ "Power Sources for Remote Arctic Applications" (PDF). Washington, DC: U.S. Congress, Office of Technology Assessment. June 1994. OTA-BP-ETI-129. Archived (PDF) from the original on 2022-10-09.
  80. ^ "Barium - Element information, properties and uses | Periodic Table". www.rsc.org. Retrieved 2024-09-02.
  81. ^ Jones, Chris J.; Thornback, John (2007). Medicinal applications of coordination chemistry. Royal Society of Chemistry. p. 102. ISBN 978-0-85404-596-9.
  82. ^ Terrill, JG Jr.; Ingraham Sc, 2nd; Moeller, DW (1954). "Radium in the healing arts and in industry: Radiation exposure in the United States". Public Health Reports. 69 (3): 255–62. doi:10.2307/4588736. JSTOR 4588736. PMC 2024184. PMID 13134440.{{cite journal}}: CS1 maint: numeric names: authors list (link)
  83. ^ "Mass Media & Environmental Conflict – Radium Girls". Archived from the original on 2009-07-21. Retrieved 2009-08-01.
  84. ^ Committee On Radiation Source Use And Replacement, National Research Council (U.S.); Nuclear And Radiation Studies Board, National Research Council (U.S.) (January 2008). Radiation source use and replacement: Abbreviated version. National Academies Press. p. 24. ISBN 978-0-309-11014-3. Archived from the original on 2015-09-05.
  85. ^ Bentel, Gunilla Carleson (1996). Radiation therapy planning. McGraw Hill Professional. p. 8. ISBN 978-0-07-005115-7. Archived from the original on 2015-09-05.
  86. ^ "QUALITATIVE ANALYSIS TESTS for metal cations identifying positive ions, carbonates, ammonium ion, hydrogen ions, acids identification". www.docbrown.info.
  87. ^ "Beryllium and magnesium do not give colour to flame whereas other alkaline earth metals do so. Why?". www.askiitians.com.
  88. ^ Gäggeler, Heinz W. (5–7 November 2007). "Gas Phase Chemistry of Superheavy Elements" (PDF). Lecture Course Texas A&M. Archived from the original (PDF) on 20 February 2012. Retrieved 26 February 2012.
  89. ^ Oganessian, Yu. Ts.; Utyonkov, V.; Lobanov, Yu.; Abdullin, F.; Polyakov, A.; Sagaidak, R.; Shirokovsky, I.; Tsyganov, Yu.; Voinov, A. (2009). "Attempt to produce element 120 in the 244Pu+58Fe reaction". Phys. Rev. C. 79 (2): 024603. Bibcode:2009PhRvC..79b4603O. doi:10.1103/PhysRevC.79.024603.
  90. ^ "Home / FIAS". fias.institute. Retrieved 2024-02-11.
  91. ^ a b Seaborg, G. T. (c. 2006). "transuranium element (chemical element)". Encyclopædia Britannica. Archived from the original on 30 November 2010. Retrieved 16 March 2010.
  92. ^ Fricke, B.; Greiner, W.; Waber, J. T. (1971). "The continuation of the periodic table up to Z = 172. The chemistry of superheavy elements". Theoretica Chimica Acta. 21 (3): 235–260. doi:10.1007/BF01172015. S2CID 117157377.
  93. ^ Hoffman, Darleane C.; Lee, Diana M.; Pershina, Valeria (2006). "Transactinides and the future elements". In Morss; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer Science+Business Media. ISBN 978-1-4020-3555-5.

Bibliography

[edit]

Further reading

[edit]
  • Group 2 – Alkaline Earth Metals, Royal Chemistry Society.
  • Hogan, C. Michael. 2010. "Calcium". A. Jorgensen, C. Cleveland, eds. Encyclopedia of Earth. National Council for Science and the Environment.
  • Maguire, Michael E. "Alkaline Earth Metals". Chemistry: Foundations and Applications. Ed. J. J. Lagowski. Vol. 1. New York: Macmillan Reference USA, 2004. 33–34. 4 vols. Gale Virtual Reference Library. Thomson Gale.
  • Petrucci R.H., Harwood W.S., and Herring F.G., General Chemistry (8th edition, Prentice-Hall, 2002)
  • Silberberg, M.S., Chemistry: The Molecular Nature of Matter and Change (3rd edition, McGraw-Hill, 2009)
Retrieved from "https://en.wikipedia.org/w/index.php?title=Alkaline_earth_metal&oldid=1262094790"