Solar cell

A solar cell is a solid state device that converts the energy of sunlight directly into electricity by the photovoltaic effect. Assemblies of cells are used to make solar modules, also known as solar panels. The energy generated this from solar modules, referred to as solar power, is an example of solar energy.

Photovoltaics is the field of technology and research related to the practical application of photovoltaic cells in producing electricity from light, though it is often used specifically to refer to the generation of electricity from sunlight.

Cells are described as photovoltaic cells when the light source is not necesssarily sunlight. These are used for detecting light or other electromagnetic radiation near the visible range, for example infrared detectors), or measurement of light intensity.

A solar cell made from a monocrystalline silicon wafer

A monocrystalline solar cell

History of solar cells

Main article: Timeline of solar cells

The term "photovoltaic" comes from the Greek φῶς (phōs) meaning "light", and "voltaic", meaning electric, from the name of the Italian physicist Volta, after whom a unit of electro-motive force, the volt, is named. The term "photo-voltaic" has been in use in English since 1849.

The photovoltaic effect was first recognized in 1839 by French physicist A. E. Becquerel. However, it was not until 1883 that the first solar cell was built, by Charles Fritts, who coated the semiconductor selenium with an extremely thin layer of gold to form the junctions. The device was only around 1% efficient. In 1888 Russian physicist Aleksandr Stoletov built the first photoelectric cell (based on the outer photoelectric effect discovered by Heinrich Hertz earlier in 1887). Albert Einstein explained the photoelectric effect in 1905 for which he received the Nobel prize in Physics in 1921. Russell Ohl patented the modern junction semiconductor solar cell in 1946, which was discovered while working on the series of advances that would lead to the transistor. The photovoltaic cell was developed in 1954 at Bell Laboratories. The highly efficient solar cell was first developed by Daryl Chapin, Calvin Souther Fuller and Gerald Pearson in 1954 using a diffused silicon p-n junction. In the past four decades, remarkable progress has been made, with Megawatt solar power generating plants having now been built.

Applications and implementations

Polycrystalline photovoltaic cells laminated to backing material in a module

Polycrystalline photovoltaic cells

Main article: photovoltaic array

Solar cells are often electrically connected and encapsulated as a module. Photovoltaic modules often have a sheet of glass on the front (sun up) side, allowing light to pass while protecting the semiconductor wafers from the elements (rain, hail, etc.). Solar cells are also usually connected in series in modules, creating an additive voltage. Connecting cells in parallel will yield a higher current. Modules are then interconnected, in series or parallel, or both, to create an array with the desired peak DC voltage and current.

To make practical use of the solar-generated energy, the electricity is most often fed into the electricity grid using inverters (grid-connected photovoltaic systems); in stand-alone systems, batteries are used to store the energy that is not needed immediately. Solar panels can be used to power or recharge portable devices.

Theory

Main article: Theory of solar cell

The solar cell works in three steps:

1. Photons in sunlight hit the solar panel and are absorbed by semiconducting materials, such as silicon.
2. Electrons (negatively charged) are knocked loose from their atoms, allowing them to flow through the material to produce electricity. Due to the special composition of solar cells, the electrons are only allowed to move in a single direction.
3. An array of solar cells converts solar energy into a usable amount of direct current (DC) electricity.

Solar cell efficiency factors

Energy conversion efficiency

Main article: Energy conversion efficiency

Dust often accumulates on the glass of solar panels seen here as black dots.

A solar cell's energy conversion efficiency ($\eta$, "eta"), is the percentage of electric power converted from incident light. This is calculated at the maximum power point, P_m, divided by the input light irradiance (E, in W/m²) under standard test conditions (STC) and the surface area of the solar cell (A_c in m²).

$\eta ={\frac {P_{m}}{E\times A_{c}}}$

STC specifies a temperature of 25 °C and an irradiance of 1000 W/m² with an air mass 1.5 (AM1.5) spectrum. These correspond to the irradiance and spectrum of sunlight incident on a clear day upon a sun-facing 37°-tilted surface with the sun at an angle of 41.81° above the horizon. This condition approximately represents solar noon near the spring and autumn equinoxes in the continental United States with surface of the cell aimed directly at the sun. For example, under these test conditions a solar cell of 12% efficiency with a 100 cm² (0.01 m²) surface area would produce 1.2 watts of power.

The efficiency of a solar cell may be broken down into reflectance efficiency, thermodynamic efficiency, charge carrier separation efficiency and conductive efficiency. The overall efficiency is the product of each of these individual efficiencies.

Due to the difficulty in measuring these parameters directly, other parameters are measured instead: thermodynamic efficiency, quantum efficiency, V_OC ratio, and fill factor. Reflectance losses are a portion of the quantum efficiency under "external quantum efficiency". Recombination losses make up a portion of the quantum efficiency, V_OC ratio, and fill factor. Resistive losses are predominantly categorized under fill factor, but also make up minor portions of the quantum efficiency, V_OC ratio.

Thermodynamic efficiency limit

Solar cells operate as quantum energy conversion devices, and are therefore subject to the "thermodynamic efficiency limit". Photons with an energy below the band gap of the absorber material cannot generate a hole-electron pair, and so their energy is not converted to useful output and only generates heat if absorbed. For photons with an energy above the band gap energy, only a fraction of the energy above the band gap can be converted to useful output. When a photon of greater energy is absorbed, the excess energy above the band gap is converted to kinetic energy of the carrier combination. The excess kinetic energy is converted to heat through phonon interactions as the kinetic energy of the carriers slows to equilibrium velocity.

Solar cells with multiple band gap absorber materials imporove efficiiency by dividing the solar spectrum into smaller bins where the thermodynamic efficiency limit is higher for each bin.

Quantum efficiency

Main article: Quantum efficiency of a solar cell

As described above, when a photon is absorbed by a solar cell it can produce an electron-hole pair. One of the carriers may reach the p-n junction and contribute to the current produced by the solar cell; such a carrier is said to be collected. Or, the carriers recombine with no net contribution to cell current.

Quantum efficiency refers to the percentage of photons that are converted to electric current (i.e., collected carriers) when the cell is operated under short circuit conditions. Some of the light striking the cell is reflected, or passes throgh the cell; external quantum efficiency is the fraction of incident photons that are converted to electric current. Not all the photons captured by the cell contribute to electric current; internal quantum efficiency (IQE) is the fraction of absorbed photons that are converted to electric current. Thick cells let through little light.

Quantum efficiency is most usefully expressed as a spectral measurement (that is, as a function of photon wavelength or energy). Since some wavelengths are absorbed more effectively than others, spectral measurements of quantum efficiency can yield valuable information about the quality of the semiconductor bulk and surfaces. Quantum efficiency alone is not the same as overall energy conversion efficiency, as it does not convey information about the fraction of power that is converted by the solar cell.

Maximum-power point

A solar cell may operate over a wide range of voltages (V) and currents (I). By increasing the resistive load on an irradiated cell continuously from zero (a short circuit) to a very high value (an open circuit) one can determine the maximum-power point, the point that maximizes V×I; that is, the load for which the cell can deliver maximum electrical power at that level of irradiation. (The output power is zero in both the short circuit and open circuit extremes).

A high quality, monocrystalline silicon solar cell, at 25 °C cell temperature, may produce 0.60 volts open-circuit (V_OC). The cell temperature in full sunlight, even with 25 °C air temperature, will probably be close to 45 °C, reducing the open-circuit voltage to 0.55 volts per cell. The voltage drops modestly, with this type of cell, until the short-circuit current is approached (I_SC). Maximum power (with 45 °C cell temperature) is typically produced with 75% to 80% of the open-circuit voltage (0.43 volts in this case) and 90% of the short-circuit current. This output can be up to 70% of the V_OC x I_SC product. The short-circuit current (I_SC) from a cell is nearly proportional to the illumination, while the open-circuit voltage (V_OC) may drop only 10% with a 80% drop in illumination. Lower-quality cells have a more rapid drop in voltage with increasing current and could produce only 1/2 V_OC at 1/2 I_SC. The usable power output could thus drop from 70% of the V_OC x I_SC product to 50% or even as little as 25%. Vendors who rate their solar cell "power" only as V_OC x I_SC, without giving load curves, can be seriously distorting their actual performance.

The maximum power point of a photovoltaic varies with incident illumination. For systems large enough to justify the extra expense, a maximum power point tracker tracks the instantaneous power by continually measuring the voltage and current (and hence, power transfer), and uses this information to dynamically adjust the load so the maximum power is always transferred, regardless of the variation in lighting.

Fill factor

Another defining term in the overall behavior of a solar cell is the fill factor (FF). This is the ratio of the available power at the maximum power point (P_m) divided by the open circuit voltage (V_OC) and the short circuit current (I_SC):

$FF={\frac {P_{m}}{V_{OC}\times I_{SC}}}={\frac {\eta \times A_{c}\times E}{V_{OC}\times I_{SC}}}.$

The fill factor is directly affected by the values of the cell's series and shunt resistances. Increasing the shunt resistance (R_sh) and decreasing the series resistance (R_s) lead to a higher fill factor, thus resulting in greater efficiency, and bringing the cell's output power closer to its theoretical maximum.

Comparison of energy conversion efficiencies

Main article: Photovoltaics

Energy conversion efficiency is measured by dividing the electrical power produced by the cell by the light power falling on the cell. Many factors influence the electrical power output, including spectral distribution, spatial distribution of power, temperature, and resistive load applied to the cell. IEC standard 61215 is used to compare the performance of cells and is designed around terrestrial, temperate conditions, using its standard temperature and conditions (STC): irradiance) of 1 kW/m², a spectral distribution close to solar radiation through AM (airmass) of 1.5 and a cell temperature 25 °C. The resistive load is varied until the peak or maximum power point (MPP) is achieved. The power at this point is recorded as Watt-peak (Wp). The same standard is used for measuring the power and efficiency of PV modules,

Air mass has an effect on power output. In space, where there is no atmosphere, the spectrum of the sun is relatively unfiltered. However, on earth, with air filtering the incoming light, the solar spectrum changes. To account for the spectral differences, a system was devised to calculate this filtering effect. Simply, the filtering effect ranges from Air Mass 0 (AM0) in space, to approximately Air Mass 1.5 on Earth. Multiplying the spectral differences by the quantum efficiency of the solar cell in question will yield the efficiency of the device. For example, a silicon solar cell in space might have an efficiency of 14% at AM0, but have an efficiency of 16% on earth at AM 1.5. Terrestrial efficiencies typically are greater than space efficiencies.

Solar cell efficiencies vary from 6% for amorphous silicon-based solar cells to 40.7% with multiple-junction research lab cells and 42.8% with multiple dies assembled into a hybrid package. Solar cell energy conversion efficiencies for commercially available multicrystalline Si solar cells are around 14-19%. The highest efficiency cells have not always been the most economical — for example a 30% efficient multijunction cell based on exotic materials such as gallium arsenide or indium selenide and produced in low volume might well cost one hundred times as much as an 8% efficient amorphous silicon cell in mass production, while only delivering about four times the electrical power.

However, there is a way to "boost" solar power. By increasing the light intensity, typically photogenerated carriers are increased, resulting in increased efficiency by up to 15%. These so-called "concentrator systems" have only begun to become cost-competitive as a result of the development of high efficiency GaAs cells. The increase in intensity is typically accomplished by using concentrating optics. A typical concentrator system may use a light intensity 6-400 times the sun, and increase the efficiency of a one sun GaAs cell from 31% at AM 1.5 to 35%. See Solar_cell#Concentrating photovoltaics (CPV) below and Concentrating solar power (CSP).

A common method used to express economic costs of electricity-generating systems is to calculate a price per delivered kilowatt-hour (kWh). The solar cell efficiency in combination with the available irradiation has a major influence on the costs, but generally speaking the overall system efficiency is important. Using the commercially available solar cells (as of 2006) and system technology leads to system efficiencies between 5 and 19%. As of 2005, photovoltaic electricity generation costs ranged from ~0.60 US$/kWh (0.50 €/kWh) (central Europe) down to ~0.30 US$/kWh (0.25 €/kWh) in regions of high solar irradiation. This electricity is generally fed into the electrical grid on the customer's side of the meter. The cost can be compared to prevailing retail electric pricing (as of 2005), which varied from between 0.04 and 0.50 US$/kWh worldwide. (Note: in addition to solar irradiance profiles, these costs/kWh calculations will vary depending on assumptions for years of useful life of a system. Most c-Si panels are warranted for 25 years and should see 35+ years of useful life.)

Solar cells and energy payback

The energy payback time, defined as the recovery time required for generating the energy spent for manufacturing a modern photovoltaic module is typically from 1 to 4 years depending on the module type and location. Generally, thin-film technologies - despite having comparatively low conversion efficiencies - achieve significantly shorter energy payback times than conventional systems (often < 1 year). With a typical lifetime of 20 to 30 years, this means that modern solar cells are net energy producers, i.e. they generate significantly more energy over their lifetime than the energy expended in producing them.

Crystalline silicon devices are approaching the theoretical limiting efficiency of 29% and achieve an energy payback period of 1–2 years.

Cost

The cost of a solar cell is given per unit of peak electrical power. Manufacturing costs necessarily including the cost of energy required for manufacture. Solar-specific feed in tariffs vary worldwide, and even state by state within various countries. Such feed-in tarrifs can be highly effective in encourage development of solar power projects.

High-efficiency solar cells are of interest to decrease the cost of solar energy. Many of the costs of a solar power plant are proportional to the area of the plant; a higher efficiency cell may reduce area and plant cost, even if the cells themselves are more costly. Efficiencies of bare cells, to be useful in evaluating solar power plant economics, msut be evaluated under realistic conditions. The basic parameters that need to be evaluated are the short circuit current, open circuit voltage.

The chart at the right illustrates the best laboratory efficiencies obtained for various materials and technologies, generally this is done on very small, i.e. one square cm, cells. Commercial efficiencies are significantly lower.

Reported timeline of solar cell energy conversion efficiencies (from National Renewable Energy Laboratory (USA)

Materials

Different materials display different efficiencies and have different costs. Materials for efficent solar cells must have characteristics matched to the spectrum of available light. Some cells are designed to efficiently convert wavelengths of solar light that reach the Earth surface. However, some solar cells are optimized for light absorption beyond Earth's atmosphere as well. Light absorbing materials can often be used in multiple physical configurations to take advantage of different light absorption and charge separation mechanisms.

Materials presently used for photovoltaic solar cells include monocrystalline silicon, polycrystalline silicon, amorphous silicon, cadmium telluride, and copper indium selenide/sulfide.

Many currently available solar cells are made from as bulk material that are cut into wafers between 180 to 240 micrometers thick that are then processed like other semiconductors.

Other materials are made as thin-films layers, organic dyes, and organic polymers) that are deposited on supporting substrates. A third group are made from nanocrystals and used as quantum dots (electron-confined nanoparticles). Silicon remains the only material that is well-researched in both bulk and thin-film forms.

Crystalline silicon

Main articles: Monocrystalline silicon, Polycrystalline silicon, Silicon, and list of silicon producers

Basic structure of a silicon based solar cell and its working mechanism.

By far, the most prevalent bulk material for solar cells is crystalline silicon (abbreviated as a group as c-Si), also known as "solar grade silicon". Bulk silicon is separated into multiple categories according to crystallinity and crystal size in the resulting ingot, ribbon, or wafer.

1. monocrystalline silicon (c-Si): often made using the Czochralski process. Single-crystal wafer cells tend to be expensive, and because they are cut from cylindrical ingots, do not completely cover a square solar cell module without a substantial waste of refined silicon. Hence most c-Si panels have uncovered gaps at the four corners of the cells.
2. Poly- or multicrystalline silicon (poly-Si or mc-Si): made from cast square ingots — large blocks of molten silicon carefully cooled and solidified. Poly-Si cells are less expensive to produce than single crystal silicon cells, but are less efficient. US DOE data shows that there were a higher number of multicrystalline sales than monocrystalline silicon sales.
3. Ribbon silicon is a type of multicrystalline silicon: it is formed by drawing flat thin films from molten silicon and results in a multicrystalline structure. These cells have lower efficiencies than poly-Si, but save on production costs due to a great reduction in silicon waste, as this approach does not require sawing from ingots.

Thin films

Main article: Thin film solar cell

Thin-film technologies reduce the amount of material required in creating a solar cell. Though this reduces material cost, it may also reduce energy conversion efficiency. Thin-film silicon cells have become popular due to cost, flexibility, lighter weight, and ease of integration, compared to wafer silicon cells.

Cadmium telluride solar cell

Main article: Cadmium telluride photovoltaics

A cadmium telluride solar cell uses a material that is easier than other to deposit in thin films.

The cadmium present in the cells would be toxic if released. However, release is impossible during normal operation of the cells and is unlikely during fires in residential roofs. A square meter of CdTe contains approximately the same amount of Cd as a single C cell Nickel-cadmium battery, in a more stable and less soluble form.

Copper-Indium Selenide

Main article: Copper indium gallium selenide solar cell

${\begin{pmatrix}\mathrm {Cu} \\\mathrm {Ag} \\\mathrm {Au} \end{pmatrix}}{\begin{pmatrix}\mathrm {Al} \\\mathrm {Ga} \\\mathrm {In} \end{pmatrix}}{\begin{pmatrix}\mathrm {S} \\\mathrm {Se} \\\mathrm {Te} \end{pmatrix}}_{2}$ Possible combinations of (I, III, VI) elements in the periodic table that have photovoltaic effect

The materials based on CuInSe₂ that are of interest for photovoltaic applications include several elements from groups I, III and VI in the periodic table. These semiconductors are especially attractive for thin film solar cell application because of their high optical absorption coefficients and versatile optical and electrical characteristics which can in principle be manipulated and tuned for a specific need in a given device.

CIS is an abbreviation for general chalcopyrite films of copper indium selenide (CuInSe₂), CIGS mentioned below is a variation of CIS. CIS films (no Ga) achieved greater than 14% efficiency. Manufacturing costs of CIS solar cells are high compared with amorphous silicon solar cells. Work continues on reducing cost. The first large-scale production of CIS modules was started in 2006 in Germany by Würth Solar.

When gallium is substituted for some of the indium in CIS, the material is referred to as CIGS, or copper indium/gallium diselenide, a solid mixture of the semiconductors CuInSe₂ and CuGaSe₂, often abbreviated by the chemical formula CuIn_xGa_(1-x)Se₂. Unlike the conventional silicon based solar cell, which can be modelled as a simple p-n junction (see under semiconductor), these cells are best described by a more complex heterojunction model. The best efficiency of a thin-film solar cell as of March 2008 was 19.9% with CIGS absorber layer. Higher efficiencies (around 30%) can be obtained by using optics to concentrate the incident light or by using multi-junction tandem solar cells. The use of gallium increases the optical bandgap of the CIGS layer as compared to pure CIS, thus increasing the open-circuit voltage, but decreasing the short circuit current. In another point of view, gallium is added to replace indium due to gallium's relative availability to indium. Approximately 70% of indium currently produced is used by the flat-screen monitor industry. However, the atomic ratio for Ga in the >19% efficient CIGS solar cells is ~7%, which corresponds to a bandgap of ~1.15 eV. CIGS solar cells with higher Ga amounts have lower efficiency. For example, CGS solar cells (which have a bandgap of ~1.7 eV have a record efficiency of 9.5% for pure CGS and 10.2% for surface-modified CGS. Some investors in solar technology worry that production of CIGS cells will be limited by the availability of indium. Producing 2 GW of CIGS cells (roughly the amount of silicon cells produced in 2006) would use about 10% of the indium produced in 2004. For comparison, silicon solar cells used up 33% of the world's electronic grade silicon production in 2006.

Se allows for better uniformity across the layer and so the number of recombination sites in the film are reduced which benefits the quantum efficiency and thus the conversion efficiency.

Gallium arsenide multijunction

Main article: Multijunction photovoltaic cell

High-efficiency multijunction cells were originally developed for special applications such as satellites and space exploration, but at present, their use in terrestrial concentrators might be the lowest cost alternative in terms of $/kWh and $/W. These multijunction cells consist of multiple thin films produced using metalorganic vapour phase epitaxy. A triple-junction cell, for example, may consist of the semiconductors: GaAs, Ge, and GaInP₂. Each type of semiconductor will have a characteristic band gap energy which, loosely speaking, causes it to absorb light most efficiently at a certain color, or more precisely, to absorb electromagnetic radiation over a portion of the spectrum. The semiconductors are carefully chosen to absorb nearly all of the solar spectrum, thus generating electricity from as much of the solar energy as possible.

GaAs based multijunction devices are the most efficient solar cells to date, reaching a record high of 40.7% efficiency under "500-sun" solar concentration and laboratory conditions.

This technology is currently being utilized in the Mars rover missions.

Tandem solar cells based on monolithic, series connected, gallium indium phosphide (GaInP), gallium arsenide GaAs, and germanium Ge pn junctions, are seeing demand rapidly rise. In just the past 12 months (12/2006 - 12/2007), the cost of 4N gallium metal has risen from about $350 per kg to $680 per kg. Additionally, germanium metal prices have risen substantially to $1000–$1200 per kg this year. Those materials include gallium (4N, 6N and 7N Ga), arsenic (4N, 6N and 7N) and germanium, pyrolitic boron nitride (pBN) crucibles for growing crystals, and boron oxide, these products are critical to the entire substrate manufacturing industry.

Triple-junction GaAs solar cells were also being used as the power source of the Dutch four-time World Solar Challenge winners Nuna in 2003, 2005 and 2007, and also by the Dutch solar cars Solutra (2005), Twente One (2007) and 21Revolution (2009).

The Dutch Radboud University Nijmegen set the record for thin film solar cell efficiency using a single junction GaAs to 25.8% in August 2008 using only 4 µm thick GaAs layer which can be transferred from a wafer base to glass or plastic film.

Light-absorbing dyes (DSSC)

Main article: Dye-sensitized solar cells

Typically a ruthenium metalorganic dye (Ru-centered) is used as a monolayer of light-absorbing material. The dye-sensitized solar cell depends on a mesoporous layer of nanoparticulate titanium dioxide to greatly amplify the surface area (200–300 m²/g TiO₂, as compared to approximately 10 m²/g of flat single crystal). The photogenerated electrons from the light absorbing dye are passed on to the n-type TiO₂, and the holes are passed to an electrolyte on the other side of the dye. The circuit is completed by a redox couple in the electrolyte, which can be liquid or solid. This type of cell allows a more flexible use of materials, and is typically manufactured by screen printing and/or use of Ultrasonic Nozzles, with the potential for lower processing costs than those used for bulk solar cells. However, the dyes in these cells also suffer from degradation under heat and UV light, and the cell casing is difficult to seal due to the solvents used in assembly. In spite of the above, this is a popular emerging technology with some commercial impact forecast within this decade. The first commercial shipment of DSSC solar modules occurred in July 2009 from G24i Innovations (www.g24i.com).

Organic/polymer solar cells

Organic solar cells and polymer solar cells are built from thin films (typically 100 nm) of organic semiconductors such as polymers and small-molecule compounds like polyphenylene vinylene, copper phthalocyanine (a blue or green organic pigment) and carbon fullerenes and fullerene derivatives such as PCBM. Energy conversion efficiencies achieved to date using conductive polymers are low compared to inorganic materials. However, it improved quickly in the last few years and the highest NREL (National Renewable Energy Laboratory) certified efficiency has reached 6.77%. In addition, these cells could be beneficial for some applications where mechanical flexibility and disposability are important.

These devices differ from inorganic semiconductor solar cells in that they do not rely on the large built-in electric field of a PN junction to separate the electrons and holes created when photons are absorbed. The active region of an organic device consists of two materials, one which acts as an electron donor and the other as an acceptor. When a photon is converted into an electron hole pair, typically in the donor material, the charges tend to remain bound in the form of an exciton, and are separated when the exciton diffuses to the donor-acceptor interface. The short exciton diffusion lengths of most polymer systems tend to limit the efficiency of such devices. Nanostructured interfaces, sometimes in the form of bulk heterojunctions, can improve performance.

Silicon thin films

Silicon thin-film cells are mainly deposited by chemical vapor deposition (typically plasma-enhanced (PE-CVD)) from silane gas and hydrogen gas. Depending on the deposition parameters, this can yield:

1. Amorphous silicon (a-Si or a-Si:H)
2. Protocrystalline silicon or
3. Nanocrystalline silicon (nc-Si or nc-Si:H), also called microcrystalline silicon.

It has been found that protocrystalline silicon with a low volume fraction of nanocrystalline silicon is optimal for high open circuit voltage. These types of silicon present dangling and twisted bonds, which results in deep defects (energy levels in the bandgap) as well as deformation of the valence and conduction bands (band tails). The solar cells made from these materials tend to have lower energy conversion efficiency than bulk silicon, but are also less expensive to produce. The quantum efficiency of thin film solar cells is also lower due to reduced number of collected charge carriers per incident photon.

Amorphous silicon has a higher bandgap (1.7 eV) than crystalline silicon (c-Si) (1.1 eV), which means it absorbs the visible part of the solar spectrum more strongly than the infrared portion of the spectrum. As nc-Si has about the same bandgap as c-Si, the nc-Si and a-Si can advantageously be combined in thin layers, creating a layered cell called a tandem cell. The top cell in a-Si absorbs the visible light and leaves the infrared part of the spectrum for the bottom cell in nc-Si.

Recently, solutions to overcome the limitations of thin-film crystalline silicon have been developed. Light trapping schemes where the weakly absorbed long wavelength light is obliquely coupled into the silicon and traverses the film several times can significantly enhance the absorption of sunlight in the thin silicon films. Thermal processing techniques can significantly enhance the crystal quality of the silicon and thereby lead to higher efficiencies of the final solar cells.

A silicon thin film technology is being developed for building integrated photovoltaics (BIPV) in the form of semi-transparent solar cells which can be applied as window glazing. These cells function as window tinting while generating electricity.

Schema of Concentrating photovoltaics

Concentrating photovoltaics (CPV)

See also: Solar concentrator

Concentrating photovoltaic systems use a large area of lenses or mirrors to focus sunlight on a small area of photovoltaic cells. High concentration means a hundred or more times direct sunlight is focused when compared with crystalline silicon panels. Most commercial producers are developing systems that concentrate between 400 and 1000 suns. All concentration systems need a one axis or more often two axis tracking system for high precision, since most systems only use direct sunlight and need to aim at the sun with errors of less than 3 degrees. The primary attraction of CPV systems is their reduced usage of semiconducting material which is expensive and currently in short supply. Additionally, increasing the concentration ratio improves the performance of high efficiency photovoltaic cells. Despite the advantages of CPV technologies their application has been limited by the costs of focusing, sun tracking and cooling equipment. On October 25, 2006, the Australian federal government and the Victorian state government together with photovoltaic technology company Solar Systems announced a project using this technology, Solar power station in Victoria, planned to come online in 2008 and be completed by 2013. This plant, at 154 MW, would be ten times larger than the largest current photovoltaic plant in the world.

Silicon solar cell device manufacture

Because solar cells are semiconductor devices, they share many of the same processing and manufacturing techniques as other semiconductor devices such as computer and memory chips. However, the stringent requirements for cleanliness and quality control of semiconductor fabrication are a little more relaxed for solar cells. Most large-scale commercial solar cell factories today make screen printed poly-crystalline silicon solar cells. Single crystalline wafers which are used in the semiconductor industry can be made into excellent high efficiency solar cells, but they are generally considered to be too expensive for large-scale mass production.

Poly-crystalline silicon wafers are made by wire-sawing block-cast silicon ingots into very thin (180 to 350 micrometer) slices or wafers. The wafers are usually lightly p-type doped. To make a solar cell from the wafer, a surface diffusion of n-type dopants is performed on the front side of the wafer. This forms a p-n junction a few hundred nanometers below the surface.

Antireflection coatings,to increase the amount of light coupled into the solar cell, are typically next applied. Silicon nitride has gradually replaced titanium dioxide as the antireflection coating because of its excellent surface passivation qualities. It prevents carrier recombination at the surface of the solar cell. It is typically applied in a layer several hundred nanometers thick using plasma-enhanced chemical vapor deposition (PECVD). Some solar cells have textured front surfaces that, like antireflection coatings, serve to increase the amount of light coupled into the cell. Such surfaces can usually only be formed on single-crystal silicon, though in recent years methods of forming them on multicrystalline silicon have been developed.

The wafer then has a full area metal contact made on the back surface, and a grid-like metal contact made up of fine "fingers" and larger "busbars" are screen-printed onto the front surface using a silver paste. The rear contact is also formed by screen-printing a metal paste, typically aluminium. Usually this contact covers the entire rear side of the cell, though in some cell designs it is printed in a grid pattern. The paste is then fired at several hundred degrees Celsius to form metal electrodes in ohmic contact with the silicon. Some companies use an additional electro-plating step to increase the cell efficiency. After the metal contacts are made, the solar cells are interconnected in series (and/or parallel) by flat wires or metal ribbons, and assembled into modules or "solar panels". Solar panels have a sheet of tempered glass on the front, and a polymer encapsulation on the back. Tempered glass cannot be used with amorphous silicon cells because of the high temperatures during the deposition process.

Lifespan

Most commercially available solar cells are capable of producing electricity for at least twenty years without a significant decrease in efficiency. The typical warranty given by panel manufacturers is for a period of 25 – 30 years, wherein the output shall not fall below 85% of the rated capacity.

Current research on materials and devices

See also: Timeline of solar cells

There are currently many research groups active in the field of photovoltaics in universities and research institutions around the world. This research can be divided into three areas: making current technology solar cells cheaper and/or more efficient to effectively compete with other energy sources; developing new technologies based on new solar cell architectural designs; and developing new materials to serve as light absorbers and charge carriers.

Silicon processing

One way of reducing the cost is to develop cheaper methods of obtaining silicon that is sufficiently pure. Silicon is a very common element, but is normally bound in silica, or silica sand. Processing silica (SiO₂) to produce silicon is a very high energy process - at current efficiencies, it takes one to two years for a conventional solar cell to generate as much energy as was used to make the silicon it contains. More energy efficient methods of synthesis are not only beneficial to the solar industry, but also to industries surrounding silicon technology as a whole.

The current industrial production of silicon is via the reaction between carbon (charcoal) and silica at a temperature around 1700 °C. In this process, known as carbothermic reduction, each tonne of silicon (metallurgical grade, about 98% pure) is produced with the emission of about 1.5 tonnes of carbon dioxide.

Solid silica can be directly converted (reduced) to pure silicon by electrolysis in a molten salt bath at a fairly mild temperature (800 to 900 °C). While this new process is in principle the same as the FFC Cambridge Process which was first discovered in late 1996, the interesting laboratory finding is that such electrolytic silicon is in the form of porous silicon which turns readily into a fine powder, with a particle size of a few micrometres, and may therefore offer new opportunities for development of solar cell technologies.

Another approach is also to reduce the amount of silicon used and thus cost, is by micromachining wafers into very thin, virtually transparent layers that could be used as transparent architectural coverings. The technique involves taking a silicon wafer, typically 1 to 2 mm thick, and making a multitude of parallel, transverse slices across the wafer, creating a large number of slivers that have a thickness of 50 micrometres and a width equal to the thickness of the original wafer. These slices are rotated 90 degrees, so that the surfaces corresponding to the faces of the original wafer become the edges of the slivers. The result is to convert, for example, a 150 mm diameter, 2 mm-thick wafer having an exposed silicon surface area of about 175 cm² per side into about 1000 slivers having dimensions of 100 mm × 2 mm × 0.1 mm, yielding a total exposed silicon surface area of about 2000 cm² per side. As a result of this rotation, the electrical doping and contacts that were on the face of the wafer are located at the edges of the sliver, rather than at the front and rear as in the case of conventional wafer cells. This has the interesting effect of making the cell sensitive from both the front and rear of the cell (a property known as bifaciality). Using this technique, one silicon wafer is enough to build a 140 watt panel, compared to about 60 wafers needed for conventional modules of same power output.

Nanocrystalline solar cells

Main article: Nanocrystal solar cell

These structures make use of some of the same thin-film light absorbing materials but are overlain as an extremely thin absorber on a supporting matrix of conductive polymer or mesoporous metal oxide having a very high surface area to increase internal reflections (and hence increase the probability of light absorption). Using nanocrystals allows one to design architectures on the length scale of nanometers, the typical exciton diffusion length. In particular, single-nanocrystal ('channel') devices, an array of single p-n junctions between the electrodes and separated by a period of about a diffusion length, represent a new architecture for solar cells and potentially high efficiency.

Thin-film processing

Main article: Thin-film

Thin-film photovoltaic cells can use less than 1% of the expensive raw material (silicon or other light absorbers) compared to wafer-based solar cells, leading to a significant price drop per Watt peak capacity. There are many research groups around the world actively researching different thin-film approaches and/or materials.

One particularly promising technology is crystalline silicon thin films on glass substrates. This technology combines the advantages of crystalline silicon as a solar cell material (abundance, non-toxicity, high efficiency, long-term stability) with the cost savings of using a thin-film approach.

Another interesting aspect of thin-film solar cells is the possibility to deposit the cells on all kind of materials, including flexible substrates (PET for example), which opens a new dimension for new applications.

Metamorphic multijunction solar cell

The National Renewable Energy Laboratory won one of R&D Magazine's R&D 100 Awards for its Metamorphic Multijunction Solar Cell, an ultra-light and flexible cell that converts solar energy with record efficiency.

The ultra-light, highly efficient solar cell was developed at NREL and is being commercialized by Emcore Corp. of Albuquerque, N.M., in partnership with the Air Force Research Laboratories Space Vehicles Directorate at Kirtland Air Force Base in Albuquerque.

It represents a new class of solar cells with clear advantages in performance, engineering design, operation and cost. For decades, conventional cells have featured wafers of semiconducting materials with similar crystalline structure. Their performance and cost effectiveness is constrained by growing the cells in an upright configuration. Meanwhile, the cells are rigid, heavy and thick with a bottom layer made of germanium.

In the new method, the cell is grown upside down. These layers use high-energy materials with extremely high quality crystals, especially in the upper layers of the cell where most of the power is produced. Not all of the layers follow the lattice pattern of even atomic spacing. Instead, the cell includes a full range of atomic spacing, which allows for greater absorption and use of sunlight. The thick, rigid germanium layer is removed, reducing the cell's cost and 94% of its weight. By turning the conventional approach to cells on its head, the result is an ultra-light and flexible cell that also converts solar energy with record efficiency (40.8% under 326 suns concentration).

Polymer processing

The invention of conductive polymers (for which Alan Heeger, Alan G. MacDiarmid and Hideki Shirakawa were awarded a Nobel prize) may lead to the development of much cheaper cells that are based on inexpensive plastics. However, organic solar cells generally suffer from degradation upon exposure to UV light, and hence have lifetimes which are far too short to be viable. The bonds in the polymers, are always susceptible to breaking up when radiated with shorter wavelengths. Additionally, the conjugated double bond systems in the polymers which carry the charge, react more readily with light and oxygen. So most conductive polymers, being highly unsaturated and reactive, are highly sensitive to atmospheric moisture and oxidation, making commercial applications difficult.

Nanoparticle processing

Experimental non-silicon solar panels can be made of quantum heterostructures, e.g. carbon nanotubes or quantum dots, embedded in conductive polymers or mesoporous metal oxides. In addition, thin films of many of these materials on conventional silicon solar cells can increase the optical coupling efficiency into the silicon cell, thus boosting the overall efficiency. By varying the size of the quantum dots, the cells can be tuned to absorb different wavelengths. Although the research is still in its infancy, quantum dot modified photovoltaics may be able to achieve up to 42% energy conversion efficiency due to multiple exciton generation (MEG).

Transparent conductors

Main article: Transparent conducting film

Many new solar cells use transparent thin films that are also conductors of electrical charge. The dominant conductive thin films used in research now are transparent conductive oxides (abbreviated "TCO"), and include fluorine-doped tin oxide (SnO₂:F, or "FTO"), doped zinc oxide (e.g.: ZnO:Al), and indium tin oxide (abbreviated "ITO"). These conductive films are also used in the LCD industry for flat panel displays. The dual function of a TCO allows light to pass through a substrate window to the active light-absorbing material beneath, and also serves as an ohmic contact to transport photogenerated charge carriers away from that light-absorbing material. The present TCO materials are effective for research, but perhaps are not yet optimized for large-scale photovoltaic production. They require very special deposition conditions at high vacuum, they can sometimes suffer from poor mechanical strength, and most have poor transmittance in the infrared portion of the spectrum (e.g.: ITO thin films can also be used as infrared filters in airplane windows). These factors make large-scale manufacturing more costly.

A relatively new area has emerged using carbon nanotube networks as a transparent conductor for organic solar cells. Nanotube networks are flexible and can be deposited on surfaces a variety of ways. With some treatment, nanotube films can be highly transparent in the infrared, possibly enabling efficient low-bandgap solar cells. Nanotube networks are p-type conductors, whereas traditional transparent conductors are exclusively n-type. The availability of a p-type transparent conductor could lead to new cell designs that simplify manufacturing and improve efficiency.

Silicon wafer-based solar cells

Despite the numerous attempts at making better solar cells by using new and exotic materials, the reality is that the photovoltaics market is still dominated by silicon wafer-based solar cells (first-generation solar cells). This means that most solar cell manufacturers are currently equipped to produce this type of solar cells. Consequently, a large body of research is being done all over the world to manufacture silicon wafer-based solar cells at lower cost and to increase the conversion efficiencies without an exorbitant increase in production cost. The ultimate goal for both wafer-based and alternative photovoltaic concepts is to produce solar electricity at a cost comparable to currently market-dominant coal, natural gas, and nuclear power in order to make it the leading primary energy source. To achieve this it may be necessary to reduce the cost of installed solar systems from currently about US$ 1.80 (for bulk Si technologies) to about US$ 0.50 per Watt peak power. Since a major part of the final cost of a traditional bulk silicon module is related to the high cost of solar grade polysilicon feedstock (about US$ 0.4/Watt peak) there exists substantial drive to make Si solar cells thinner (material savings) or to make solar cells from cheaper upgraded metallurgical silicon (so called "dirty Si").

IBM has a semiconductor wafer reclamation process that uses a specialized pattern removal technique to repurpose scrap semiconductor wafers to a form used to manufacture silicon-based solar panels. The new process was recently awarded the “2007 Most Valuable Pollution Prevention Award” from The National Pollution Prevention Roundtable (NPPR).

Infrared solar cells

Researchers at Idaho National Laboratory, along with partners at Lightwave Power Inc. in Cambridge, MA and Patrick Pinhero of the University of Missouri, have devised an inexpensive way to produce plastic sheets containing billions of nanoantennas that collect heat energy generated by the sun and other sources, which garnered two 2007 Nano50 awards. The company ceased operations in 2010. While methods to convert the energy into usable electricity still need to be developed, the sheets could one day be manufactured as lightweight "skins" that power everything from hybrid cars to computers and iPods with higher efficiency than traditional solar cells. The nanoantennas target mid-infrared rays, which the Earth continuously radiates as heat after absorbing energy from the sun during the day; also double-sided nanoantenna sheets can harvest energy from different parts of the Sun's spectrum. In contrast, traditional solar cells can only use visible light, rendering them idle after dark.

UV solar cells

Japan's National Institute of Advanced Industrial Science and Technology (AIST) has succeeded in developing a transparent solar cell that uses ultraviolet (UV) light to generate electricity but allows visible light to pass through it. Most conventional solar cells use visible and infrared light to generate electricity. Used to replace conventional window glass, the installation surface area could be large, leading to potential uses that take advantage of the combined functions of power generation, lighting and temperature control.

Also, easily fabricated PEDOT:PSS photovoltaic cells are ultraviolet light selective and sensitive.

3D solar cells

Three-dimensional solar cells that capture nearly all of the light that strikes them and could boost the efficiency of photovoltaic systems while reducing their size, weight and mechanical complexity. The new 3D solar cells capture photons from sunlight using an array of miniature “tower” structures that resemble high-rise buildings in a city street grid.

Metamaterials

Main article: Metamaterial

Metamaterials are heterogeneous materials employing the juxtaposition of many microscopic elements, giving rise to properties not seen in ordinary solids. Using these, it may become possible to fashion solar cells that are excellent absorbers over a narrow range of wavelengths. High absorption in the microwave regime has been demonstrated, but not yet in the 300-1100-nm wavelength regime.

Photovoltaic thermal hybrid

Main article: Photovoltaic thermal hybrid solar collector

Some systems combine photovoltaic with thermal solar, with the advantage that the thermal solar part carries heat away and cools the photovoltaic cells. Keeping temperature down lowers the resistance and improves the cell efficiency.

Validation, certification and manufacturers

National Renewable Energy Laboratory tests and validates solar technologies. There are three reliable certifications of solar equipment: UL and IEEE (both U.S. standards) and IEC.

Solar cells are manufactured primarily in Japan, Germany, Mainland China, Taiwan and United States, though numerous other nations have or are acquiring significant solar cell production capacity. While technologies are constantly evolving toward higher efficiencies, the most effective cells for low cost electrical production are not necessarily those with the highest efficiency, but those with a balance between low-cost production and efficiency high enough to minimize area-related balance of systems cost. Those companies with large scale manufacturing technology for coating inexpensive substrates may, in fact, ultimately be the lowest cost net electricity producers, even with cell efficiencies that are lower than those of single-crystal technologies.

China

Backed by Chinese government's unprecedented plan to offer subsidies for utility-scale solar power projects that is likely to spark a new round of investment from Chinese solar panel makers. Chinese companies have already played a more important role in solar panels manufacturing in recent years. China produced solar cells/modules with an output of 1,180 MW in 2007 making it the largest producer in the world, according to statistics from China Photovoltaic Association. Some Chinese companies such as Suntech Power, Yingli, LDK Solar Co, JA Solar and ReneSola have already announced projects in cooperation with regional governments with hundreds of megawatts each after the ‘Golden Sun’ incentive program was announced by the government. The new development of solar module manufacturers with thin-film technology such as Veeco and Anwell Technologies Limited will further help to boost the domestic solar industry.

United States

Main article: Photovoltaics in the United States

New manufacturing facilities for solar cells and modules in Massachusetts, Michigan, New York, Ohio, Oregon, and Texas promise to add enough capacity to produce thousands of megawatts of solar devices per year within the next few years from 2008.

In late September 2008, Sanyo Electric Company, Ltd. announced its decision to build a manufacturing plant for solar ingots and wafers in Salem, Oregon. The plant will begin operating in October 2009 and will reach its full production capacity of 70 megawatts (MW) of solar wafers per year by April 2010.

In early October 2008, First Solar, Inc. broke ground on an expansion of its Perrysburg, Ohio, facility that will add enough capacity to produce another 57 MW per year of solar modules at the facility, bringing its total capacity to roughly 192 MW per year. The company expects to complete construction early next year and reach full production by mid-2010.

In mid-October 2008, SolarWorld AG opened a manufacturing plant in Hillsboro, Oregon, that is expected to produce 500 MW of solar cells per year when it reaches full production in 2011.

In March 2010, SpectraWatt, Inc. began production at its manufacturing plant in Hopewell Junction, NY, which is expected to produce 120 MW of solar cells per year when it reaches full production in 2011.

See also

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• Multijunction solar cell
• Thin film solar cell
• Anomalous photovoltaic effect
• Autonomous building
• Black silicon
• Energy development
• Flexible substrate
• Green technology
• Helianthos
• Junction
• List of solar cell manufacturers
• Metallurgical grade silicon
• Microgeneration
• Maximum Power Point Tracking
• Carbon nanotubes in photovoltaics

• Plasmonic solar cell
• Printed electronics
• Renewable energy
• Roll-to-roll processing
• Shockley-Queisser limit
• Solar roof
• Solar shingles
• Solar tracker
• Spectrophotometry

External links

• Howstuffworks.com: How Solar Cells Work
• Solar cell manufacturing techniques
• Renewable Energy: Solar at Curlie
• Solar Energy Laboratory at University of Southampton
• NASA's Photovoltaic Info
• Photovoltaics CDROM online
• Nanotechnology Based Improvements for Solar Cells
• Solar Cells and Türkey