|Jmol-3D images||Image 1|
|Molar mass||57.9552 g/mol|
|Appearance||yellow or gray crystals|
|Density||2.85 g/cm3, solid|
|Solubility in water||reacts|
|Band gap||2.5 eV (indirect)|
|Refractive index (nD)||2.75 (IR), ~3 (Vis) |
|Lattice constant||a = 546.35 pm|
|EU classification|| T
|Flash point||>800 °C|
| (what is: / ?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Aluminium phosphide (AlP) is an inorganic compound used as a wide band gap semiconductor and a fumigant. This colourless solid is generally sold as a grey-green-yellow powder due to the presence of impurities arising from hydrolysis and oxidation.
AlP crystals are dark grey to dark yellow in color and have a zincblende crystal structure with a lattice constant of 5.4510 Å at 300 K. They are thermodynamically stable up to 1,000 °C (1,830 °F).
- AlP + 3 H2O → Al(OH)3 + PH3
- AlP + 3 H+ → Al3+ + PH3
- 4Al + P4 → 4AlP
Caution must be taken to avoid exposing the AlP to any sources of moisture, as this generates toxic phosphine gas.
AlP is used as a rodenticide, insecticide, and fumigant for stored cereal grains. It is used to kill small verminous mammals such as moles and rodents. The tablets or pellets typically also contain other chemicals that evolve ammonia which helps to reduce the potential for spontaneous ignition or explosion of the phosphine gas.
AlP is used as both a fumigant and an oral pesticide. As a rodenticide, aluminium phosphide pellets are provided as a mixture with food for consumption by the rodents. The acid in the digestive system of the rodent reacts with the phosphide to generate the toxic phosphine gas. Other pesticides similar to aluminium phosphide are zinc phosphide and calcium phosphide. In this application, aluminium phosphide can be encountered under various brand names, e.g. Celphos, Fumitoxin, Phostoxin, Talunex and Quick Phos. It generates phosphine gas according to the following hydrolysis equation.
- 2 AlP + 6 H2O → Al2O3∙3 H2O + 2 PH3
It is used as a fumigant when other pesticide applications are impractical and when structures and installations are being treated, such as in ships, aircraft, and grain silos. All of these structures can be effectively sealed or enclosed in a gastight membrane, thereby containing and concentrating the phosphine fumes. Fumigants are also applied directly to rodent burrows.
Industrially, AlP is a semiconductor material that is usually alloyed with other binary materials for applications in devices such as light-emitting diodes (e.g. aluminium gallium indium phosphide).
Evidently poisonous, aluminium phosphide has been used for suicide. Fumigation has also caused unintentional deaths, such as examples in Saudi Arabia and the United States. Known as "rice tablet" in Iran, for its use to preserve rice, there have been frequent incidents of accidental or intentional death. There is a campaign by the Iranian Forensic Medicine Organization to stop its use as a pesticide.
- Berger, L. I. (1996). Semiconductor Materials. CRC Press. p. 125. ISBN 0-8493-8912-7.
- Van Zeghbroeck, B. J. (1997). "Bravais Lattices; Zincblende Lattice". University of Colorado.
- "Lattice Constants". SiliconFarEast.com. 2004. Retrieved 10/02/2011.
- White, W. E.; Bushey, A. H.; Holtzclaw, H. F.; Hengeveld, F. W. (1953). "Aluminum Phosphide". In Bailar, J. C. Inorganic Syntheses 4: 23–25. doi:10.1002/9780470132357.ch7.
- Holleman, A. F.; Wiberg, E. (2001), Inorganic Chemistry, San Diego: Academic Press, ISBN 0-12-352651-5
- White, W. E.; Bushey, A. H. (1944). "Aluminum Phosphide – Preparation and Composition". Journal of the American Chemical Society 66 (10): 1666. doi:10.1021/ja01238a018.
- Buckle, A. (2005), "Rodenticides", Ullmann's Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, doi:10.1002/14356007.a23_211
- Corbridge, D. E. C. (1995). Phosphorus: An Outline of its Chemistry, Biochemistry, and Technology (5th ed.). Amsterdam: Elsevier. ISBN 0-444-89307-5.
- "Millionaire's death sparks poison scare". BBC News. 2002-10-10. Retrieved 2009-04-05.
- "Fumes kill two Danes in Jeddah". BBC News. 2009-02-24. Archived from the original on 25 February 2009. Retrieved 2009-02-25.
- "Family loses 2nd child in suspected pesticide poisoning". KSL-TV. 2010-02-09. Archived from the original on 11 February 2010. Retrieved 2010-02-09.
- Shadnia, S.; Sasanian, G.; Allami, P.; Hosseini, A.; Ranjbar, A.; Amini-Shirazi, N.; Abdollahi, M. (2009). "A Retrospective 7-Years Study of Aluminum Phosphide Poisoning in Tehran: Opportunities for Prevention". Human & Experimental Toxicology 28 (4): 209–213. doi:10.1177/0960327108097194. PMID 19734272.
- Mehrpour, O.; Singh, S. (2010). "Rice Tablet Poisoning: A Major Concern in Iranian Population". Human & Experimental Toxicology 29 (8): 701–702. doi:10.1177/0960327109359643. PMID 20097728.
- Siwach, SB; Gupta, A (1995). "The profile of acute poisonings in Harayana-Rohtak Study". The Journal of the Association of Physicians of India 43 (11): 756–9. PMID 8773034.
- Singh, D; Jit, I; Tyagi, S (1999). "Changing trends in acute poisoning in Chandigarh zone: A 25-year autopsy experience from a tertiary care hospital in northern India". The American journal of forensic medicine and pathology 20 (2): 203–10. PMID 10414665.