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This article is about the metallic element. For other uses, see Aluminium (disambiguation).

Aluminium, 13Al
Aluminium
Pronunciation
Alternative nameAluminum (U.S., Canada)
AppearanceSilvery gray metallic
Standard atomic weight Ar°(Al)
Aluminium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
B
↑
Al
↓
Ga
magnesium ← aluminium → silicon
Atomic number (Z)13
Groupgroup 13 (boron group)
Periodperiod 3
Block  p-block
Electron configuration[Ne] 3s2 3p1
Electrons per shell2, 8, 3
Physical properties
Phase at STPsolid
Melting point933.47 K ​(660.32 °C, ​1220.58 °F)
Boiling point2743[4] K ​(2470 °C, ​4478 °F)
Density (at 20 °C)2.699 g/cm3[5]
when liquid (at m.p.)2.375 g/cm3
Heat of fusion10.71 kJ/mol
Heat of vaporization284 kJ/mol
Molar heat capacity24.20 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1482 1632 1817 2054 2364 2790
Atomic properties
Oxidation statescommon: +3
−2,? −1,? 0,[6] +1,[7][8] +2[9]
ElectronegativityPauling scale: 1.61
Ionization energies
  • 1st: 577.5 kJ/mol
  • 2nd: 1816.7 kJ/mol
  • 3rd: 2744.8 kJ/mol
  • (more)
Atomic radiusempirical: 143 pm
Covalent radius121±4 pm
Van der Waals radius184 pm
Color lines in a spectral range
Spectral lines of aluminium
Other properties
Natural occurrenceprimordial
Crystal structure ​face-centered cubic (fcc) (cF4)
Lattice constant
Face-centered cubic crystal structure for aluminium
a = 404.93 pm (at 20 °C)[5]
Thermal expansion22.87×10−6/K (at 20 °C)[5]
Thermal conductivity237 W/(m⋅K)
Electrical resistivity26.5 nΩ⋅m (at 20 °C)
Magnetic orderingparamagnetic[10]
Molar magnetic susceptibility+16.5×10−6 cm3/mol
Young's modulus70 GPa
Shear modulus26 GPa
Bulk modulus76 GPa
Speed of sound thin rod(rolled) 5000 m/s (at r.t.)
Poisson ratio0.35
Mohs hardness2.75
Vickers hardness160–350 MPa
Brinell hardness160–550 MPa
CAS Number7429-90-5
History
Namingfrom alumine, obsolete name for alumina
PredictionAntoine Lavoisier (1782)
DiscoveryHans Christian Ørsted (1824)
Named byHumphry Davy (1812[a])
Isotopes of aluminium
Main isotopes[11] Decay
abun­dance half-life (t1/2) mode pro­duct
26Al trace 7.17×105 y β+84% 26Mg
ε[12]16% 26Mg
γ –
27Al 100% stable
 Category: Aluminium
| references

Aluminium (in Commonwealth English) or aluminum (in American English) is a chemical element in the boron group with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic, ductile metal. Aluminium is the third most abundant element in the Earth's crust (after oxygen and silicon) and its most abundant metal. Aluminium makes up about 8% of the crust by mass, though it is less common in the mantle below. Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is found combined in over 270 different minerals.[13] The chief ore of aluminium is bauxite.

Aluminium is remarkable for the metal's low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the aerospace industry and important in transportation and structures, such as building facades and window frames.[clarification needed] The oxides and sulfates are the most useful compounds of aluminium.[citation needed]

Despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals.[14] Because of their abundance, the potential for a biological role is of continuing interest and studies continue.

Characteristics

"Bauxite tailings" storage facility in Stade, Germany. The aluminium industry generates about 70 million tons of this waste annually.

Physical

Aluminium is a relatively soft, durable, lightweight, ductile, and malleable metal with appearance ranging from silvery to dull gray, depending on the surface roughness. It is nonmagnetic and does not easily ignite. A fresh film of aluminium serves as a good reflector (approximately 92%) of visible light and an excellent reflector (as much as 98%) of medium and far infrared radiation. The yield strength of pure aluminium is 7–11 MPa, while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa.[15] Aluminium has about one-third the density and stiffness of steel. It is easily machined, cast, drawn and extruded.

Aluminium atoms are arranged in a face-centered cubic (fcc) structure. Aluminium has a stacking-fault energy of approximately 200 mJ/m2.[16]

Aluminium is a good thermal and electrical conductor, having 59% the conductivity of copper, both thermal and electrical, while having only 30% of copper's density. Aluminium is capable of superconductivity, with a superconducting critical temperature of 1.2 kelvin and a critical magnetic field of about 100 gauss (10 milliteslas).[17]

Chemical

Corrosion resistance can be excellent because a thin surface layer of aluminium oxide forms when the bare metal is exposed to air, effectively preventing further oxidation.[18] The strongest aluminium alloys are less corrosion resistant due to galvanic reactions with alloyed copper.[15] This corrosion resistance is greatly reduced by aqueous salts, particularly in the presence of dissimilar metals.

In highly acidic solutions, aluminium reacts with water to form hydrogen, and in highly alkaline ones to form aluminates— protective passivation under these conditions is negligible. Primarily because it is corroded by dissolved chlorides, such as common sodium chloride, household plumbing is never made from aluminium.[19]

However, because of its general resistance to corrosion, aluminium is one of the few metals that retains silvery reflectance in finely powdered form, making it an important component of silver-colored paints. Aluminium mirror finish has the highest reflectance of any metal in the 200–400 nm (UV) and the 3,000–10,000 nm (far IR) regions; in the 400–700 nm visible range it is slightly outperformed by tin and silver and in the 700–3000 nm (near IR) by silver, gold, and copper.[20]

Aluminium is oxidized by water at temperatures below 280 °C to produce hydrogen, aluminium hydroxide and heat:

2 Al + 6 H2O → 2 Al(OH)3 + 3 H2

This conversion is of interest for the production of hydrogen. However, commercial application of this fact has challenges in circumventing the passivating oxide layer, which inhibits the reaction, and in storing the energy required to regenerate the aluminium metal.[21]

Isotopes

Main article: Isotopes of aluminium

Aluminium has many known isotopes, with mass numbers range from 21 to 42; however, only 27Al (stable) and 26Al (radioactive, t1⁄2 = 7.2×105 year|y) occur naturally. 27Al has a natural abundance above 99.9%. 26Al is produced from argon in the atmosphere by spallation caused by cosmic-ray protons. Aluminium isotopes are useful in dating marine sediments, manganese nodules, glacial ice, quartz in rock exposures, and meteorites. The ratio of 26Al to 10Be has been used to study transport, deposition, sediment storage, burial times, and erosion on 105 to 106 year time scales.[22] Cosmogenic 26Al was first applied in studies of the Moon and meteorites. Meteoroid fragments, after departure from their parent bodies, are exposed to intense cosmic-ray bombardment during their travel through space, causing substantial 26Al production. After falling to Earth, atmospheric shielding drastically reduces 26Al production, and its decay can then be used to determine the meteorite's terrestrial age. Meteorite research has also shown that 26Al was relatively abundant at the time of formation of our planetary system. Most meteorite scientists believe that the energy released by the decay of 26Al was responsible for the melting and differentiation of some asteroids after their formation 4.55 billion years ago.[23]

Natural occurrence

See also: List of countries by bauxite production

Stable aluminium is created when hydrogen fuses with magnesium, either in large stars or in supernovae.[24] It is estimated to be the 14th most common element in the Universe, by mass-fraction.[25] However, among the elements that have odd atomic numbers, aluminium is the third most abundant by mass fraction, after hydrogen and nitrogen.[25]

In the Earth's crust, aluminium is the most abundant (8.3% by mass) metallic element and the third most abundant of all elements (after oxygen and silicon).[26] The Earth's crust has a greater abundance of aluminium than the rest of the planet, primarily in aluminium silicates. In the Earths mantle, which is only 2% aluminium by mass, these aluminium silicate minerals are largely replaced by silica and magnesium oxides. Overall, the Earth is about 1.4% aluminium by mass (eighth in abundance by mass). Aluminium occurs in greater proportion in the Earth than in the Solar system and Universe because the more common elements (hydrogen, helium, neon, nitrogen, carbon as hydrocarbon) are volatile at Earth's proximity to the Sun and large quantities of those were lost.

Because of its strong affinity for oxygen, aluminium is almost never found in the elemental state; instead it is found in oxides or silicates. Feldspars, the most common group of minerals in the Earth's crust, are aluminosilicates. Native aluminium metal can only be found as a minor phase in low oxygen fugacity environments, such as the interiors of certain volcanoes.[27] Native aluminium has been reported in cold seeps in the northeastern continental slope of the South China Sea. Chen et al. (2011)[28] propose the theory that these deposits resulted from bacterialreduction of tetrahydroxoaluminate Al(OH)4−.[28]

Aluminium also occurs in the minerals beryl, cryolite, garnet, spinel, and turquoise. Impurities in Al2O3, such as chromium and iron, yield the gemstones ruby and sapphire, respectively.

Although aluminium is a common and widespread element, not all aluminium minerals are economically viable sources of the metal. Almost all metallic aluminium is produced from the ore bauxite (AlOx(OH)3–2x). Bauxite occurs as a weathering product of low iron and silica bedrock in tropical climatic conditions.[29] Bauxite is mined from large deposits in Australia, Brazil, Guinea, and Jamaica; it is also mined from lesser deposits in China, India, Indonesia, Russia, and Suriname.

Production and refinement

See also: Category:Aluminium minerals and List of countries by aluminium production
Bauxite, a major aluminium ore. The red-brown color is due to the presence of iron minerals.

Bayer process and Hall-Héroult processes

Bauxite is converted to aluminium oxide (Al2O3) by the Bayer process.[14] Relevant chemical equations are:

Al2O3 + 2 NaOH → 2 NaAlO2 + H2O
2 H2O + NaAlO2 → Al(OH)3 + NaOH

The intermediate, sodium aluminate, with the simplified formula NaAlO2, is soluble in strongly alkaline water, and the other components of the ore are not. Depending on the quality of the bauxite ore, twice as much waste ("Bauxite tailings") as alumina is generated.

The conversion of alumina to aluminium metal is achieved by the Hall-Héroult process. In this energy-intensive process, a solution of alumina in a molten (950 and 980 °C (1,740 and 1,800 °F)) mixture of cryolite (Na3AlF6) with calcium fluoride is electrolyzed to produce metallic aluminium:

Al3+ + 3 e− → Al

The liquid aluminium metal sinks to the bottom of the solution and is tapped off, and usually cast into large blocks called aluminium billets for further processing. Oxygen is produced at the anode:

2 O2− + C → CO2 + 4 e−

The carbon anode is consumed by reaction with oxygen to form carbon dioxide gas, with a small quantity of fluoride gases. In modern smelters, the gas is filtered through alumina to remove fluorine compounds and return aluminium fluoride to the electrolytic cells. The anode this reduction cell must be replaced regularly, since it is consumed in the process. The cathode is also eroded, mainly by electrochemical processes and liquid metal movement induced by intense electrolytic currents. After five to ten years, depending on the current used in the electrolysis, a cell must be rebuilt because of cathode wear.

World production trend of aluminium

Aluminium electrolysis with the Hall-Héroult process consumes a lot of energy. The worldwide average specific energy consumption is approximately 15±0.5 kilowatt-hours per kilogram of aluminium produced (52 to 56 MJ/kg). Some smelters achieve approximately 12.8 kW·h/kg (46.1 MJ/kg). (Compare this to the heat of reaction, 31 MJ/kg, and the Gibbs free energy of reaction, 29 MJ/kg.) Minimizing line currents for older technologies are typically 100 to 200 kiloamperes; state-of-the-art smelters operate at about 350 kA. Trials have been reported with 500 kA cells.[citation needed]

The Hall-Heroult process produces aluminium with a purity of above 99%. Further purification can be done by the Hoopes process. This process involves the electrolysis of molten aluminium with a sodium, barium and aluminium fluoride electrolyte. The resulting aluminium has a purity of 99.99%.[14][30]

Electric power represents about 20% to 40% of the cost of producing aluminium, depending on the location of the smelter. Aluminium production consumes roughly 5% of electricity generated in the U.S.[31] Aluminium producers tend to locate smelters in places where electric power is both plentiful and inexpensive—such as the United Arab Emirates with its large natural gas supplies,[32] and Iceland[33] and Norway[34] with energy generated from renewable sources. The world's largest smelters of alumina are located in the People's Republic of China, Russia and the provinces of Quebec and British Columbia in Canada.[31][35][36]

Aluminium spot price 1987–2012

In 2005, the People's Republic of China was the top producer of aluminium with almost a one-fifth world share, followed by Russia, Canada, and the US, reports the British Geological Survey.

Over the last 50 years, Australia has become the world's top producer of bauxite ore and a major producer and exporter of alumina (before being overtaken by China in 2007).[35][37] Australia produced 77 million tonnes of bauxite in 2013.[38] The Australian deposits have some refining problems, some being high in silica, but have the advantage of being shallow and relatively easy to mine.[39]

Aluminium chloride electrolysis process

The high energy consumption of Hall-Héroult process motivated the development of the electrolytic process based on aluminium chloride. The pilot plant with 6500 tons/year output was started in 1976 by Alcoa. The plant offered two advantages: (i) energy requirements were 40% less than plants using the Hall-Héroult process, and (ii) the more accessible kaolinite (instead of bauxite and cryolite) was used for feedstock. Nonetheless, the pilot plant was shut down. The reasons for failure were the cost of aluminium chloride, general technology maturity problems, and leakage of the trace amounts of extremely toxic polychlorinated biphenyl compounds.[40][41]

Aluminium chloride process can also be used for the co-production of titanium, depending on titanium contents in kaolinite.

Aluminium carbothermic process

The non-electrolytic aluminium carbothermic process of aluminium production would theoretically be cheaper and consume less energy. However, it has been in the experimental phase for decades because the high operating temperature creates difficulties in material technology that have not yet been solved.[42][43] Research continues on lowering the operating temperature.[44][45]

Recycling

Aluminium recycling code
Main article: Aluminium recycling

Aluminium is theoretically 100% recyclable without any loss of its natural qualities. According to the International Resource Panel's Metal Stocks in Society report, the global per capita stock of aluminium in use in society (i.e. in cars, buildings, electronics etc.) is 80 kg (180 lb). Much of this is in more-developed countries (350–500 kg (770–1,100 lb) per capita) rather than less-developed countries (35 kg (77 lb) per capita). Knowing the per capita stocks and their approximate lifespans is important for planning recycling.

Recovery of the metal through recycling has become an important task of the aluminium industry. Recycling was a low-profile activity until the late 1960s, when the growing use of aluminium beverage cans brought it to public awareness.

Recycling involves melting the scrap, a process that requires only 5% of the energy used to produce aluminium from ore, though a significant part (up to 15% of the input material) is lost as dross (ash-like oxide).[46] An aluminium stack melter produces significantly less dross, with values reported below 1%.[47] The dross can undergo a further process to extract aluminium.

Europe has achieved high rates of aluminium recycling ranging from 42% of beverage cans, 85% of construction materials, and 95% of transport vehicles.[48]

Recycled aluminium is known as secondary aluminium, but maintains the same physical properties as primary aluminium. Secondary aluminium is produced in a wide range of formats and is employed in 80% of alloy injections. Another important use is extrusion.

White dross from primary aluminium production and from secondary recycling operations still contains useful quantities of aluminium that can be extracted industrially.[49] The process produces aluminium billets, together with a highly complex waste material. This waste is difficult to manage. It reacts with water, releasing a mixture of gases (including, among others, hydrogen, acetylene, and ammonia), which spontaneously ignites on contact with air;[50] contact with damp air results in the release of copious quantities of ammonia gas. Despite these difficulties, the waste is used as a filler in asphalt and concrete.[51]

Compounds

See also: Category:Aluminium compounds

Oxidation state +3

The vast majority of compounds, including all Al-containing minerals and all commercially significant aluminium compounds, feature aluminium in the oxidation state 3+. The coordination number of such compounds varies, but generally Al3+ is six-coordinate or tetracoordinate. Almost all compounds of aluminium(III) are colorless.[26]

Halides

All four trihalides are well known. Unlike the structures of the three heavier trihalides, aluminium fluoride (AlF3) features six-coordinate Al. The octahedral coordination environment for AlF3 is related to the compactness of the fluoride ion, six of which can fit around the small Al3+ center. AlF3 sublimes (with cracking) at 1,291 °C (2,356 °F). With heavier halides, the coordination numbers are lower. The other trihalides are dimeric or polymeric with tetrahedral Al centers. These materials are prepared by treating aluminium metal with the halogen, although other methods exist. Acidification of the oxides or hydroxides affords hydrates. In aqueous solution, the halides often form mixtures, generally containing six-coordinate Al centers that feature both halide and aquo ligands. When aluminium and fluoride are together in aqueous solution, they readily form complex ions such as [AlF(H
2O)
5]2+
, AlF
3(H
2O)
3, and [AlF
6]3−
. In the case of chloride, polyaluminium clusters are formed such as [Al13O4(OH)24(H2O)12]7+.

Oxide and hydroxides

Aluminium forms one stable oxide, known by its mineral name corundum. Sapphire and ruby are impure corundum contaminated with trace amounts of other metals. The two oxide-hydroxides, AlO(OH), are boehmite and diaspore. There are three trihydroxides: bayerite, gibbsite, and nordstrandite, which differ in their crystalline structure (polymorphs). Most are produced from ores by a variety of wet processes using acid and base. Heating the hydroxides leads to formation of corundum. These materials are of central importance to the production of aluminium and are themselves extremely useful.

Aluminium carbide (Al4C3) is made by heating a mixture of the elements above 1,000 °C (1,832 °F). The pale yellow crystals consist of tetrahedral aluminium centers. It reacts with water or dilute acids to give methane. The acetylide, Al2(C2)3, is made by passing acetylene over heated aluminium.

Aluminium nitride (AlN) is the only nitride known for aluminium. Unlike the oxides, it features tetrahedral Al centers. It can be made from the elements at 800 °C (1,472 °F). It is air-stable material with a usefully high thermal conductivity. Aluminium phosphide (AlP) is made similarly; it hydrolyses to give phosphine:

AlP + 3 H2O → Al(OH)3 + PH3
Main article: Organoaluminium compound
Structure of trimethylaluminium, a compound that features five-coordinate carbon.

A variety of compounds of empirical formula AlR3 and AlR1.5Cl1.5 exist.[52] These species usually feature tetrahedral Al centers, e.g. "trimethylaluminium" has the formula Al2(CH3)6 (see figure). With large organic groups, triorganoaluminium exist as three-coordinate monomers, such as triisobutylaluminium. Such compounds are widely used in industrial chemistry, despite the fact that they are often highly pyrophoric. Few analogues exist between organoaluminium and organoboron compounds other than large organic groups.

The important aluminium hydride is lithium aluminium hydride (LiAlH4), which is used in as a reducing agent in organic chemistry. It can be produced from lithium hydride and aluminium trichloride:

4 LiH + AlCl3 → LiAlH4 + 3 LiCl

Several useful derivatives of LiAlH4 are known, e.g. sodium bis(2-methoxyethoxy)dihydridoaluminate. The simplest hydride, aluminium hydride or alane, remains a laboratory curiosity. It is a polymer with the formula (AlH3)n, in contrast to the corresponding boron hydride with the formula (BH3)2.

Oxidation states +1 and +2

Although the great majority of aluminium compounds feature Al3+ centers, compounds with lower oxidation states are known and sometime of significance as precursors to the Al3+ species.

Aluminium(I)

AlF, AlCl and AlBr exist in the gaseous phase when the trihalide is heated with aluminium. The composition AlI is unstable at room temperature, converting to triiodide:[53]

3 AlI → AlI3 + 2 Al

A stable derivative of aluminium monoiodide is the cyclic adduct formed with triethylamine, Al4I4(NEt3)4. Also of theoretical interest but only of fleeting existence are Al2O and Al2S. Al2O is made by heating the normal oxide, Al2O3, with silicon at 1,800 °C (3,272 °F) in a vacuum.[53] Such materials quickly disproportionate to the starting materials.

Aluminium(II)

Very simple Al(II) compounds are invoked or observed in the reactions of Al metal with oxidants. For example, aluminium monoxide, AlO, has been detected in the gas phase after explosion[54] and in stellar absorption spectra.[55] More thoroughly investigated are compounds of the formula R4Al2 which contain an Al-Al bond and where R is a large organic ligand.[56]

Analysis

The presence of aluminium can be detected in qualitative analysis using aluminon.

Applications

Etched surface from a high purity (99.9998%) aluminium bar, size 55×37 mm

General use

Aluminium is the most widely used non-ferrous metal.[57] Global production of aluminium in 2005 was 31.9 million tonnes. It exceeded that of any other metal except iron (837.5 million tonnes).[58] Forecast for 2012 was 42–45 million tonnes, driven by rising Chinese output.[59]

Aluminium is almost always alloyed, which markedly improves its mechanical properties, especially when tempered. For example, the common aluminium foils and beverage cans are alloys of 92% to 99% aluminium.[60] The main alloying agents are copper, zinc, magnesium, manganese, and silicon (e.g., duralumin) with the levels of other metals in a few percent by weight.[61]

Household aluminium foil
Aluminium-bodied Austin "A40 Sports" (c. 1951)
Aluminium slabs being transported from a smelter

Some of the many uses for aluminium metal are in:

  • Transportation (automobiles, aircraft, trucks, railway cars, marine vessels, bicycles, spacecraft, etc.) as sheet, tube, and castings.
  • Packaging (cans, foil, frame of etc.).
  • Food and beverage containers, because of its resistance to corrosion.
  • Construction (windows, doors, siding, building wire, sheathing, roofing, etc.).[62]
  • A wide range of household items, from cooking utensils to baseball bats and watches.[63]
  • Street lighting poles, sailing ship masts, walking poles.
  • Outer shells and cases for consumer electronics and photographic equipment.
  • Electrical transmission lines for power distribution ("creep" and oxidation are not issues in this application as the terminations are usually multi-sided "crimps" which enclose all sides of the conductor with a gas-tight seal).
  • MKM steel and Alnico magnets.
  • Super purity aluminium (SPA, 99.980% to 99.999% Al), used in electronics and CDs, and also in wires/cabling.
  • Heat sinks for transistors, CPUs, and other components in electronic appliances.
  • Substrate material of metal-core copper clad laminates used in high brightness LED lighting.
  • Light reflective surfaces and paint.
  • Pyrotechnics, solid rocket fuels, and thermite.
  • Production of hydrogen gas by reaction with hydrochloric acid or sodium hydroxide.
  • In alloy with magnesium to make aircraft bodies and other transportation components.
  • Cooking utensils, because of its resistant to corrosion and light-weight.
  • Coins in such countries as France, Italy, Poland, Finland, Romania, Israel, and the former Yugoslavia struck from aluminium or an aluminium-copper alloy.[64][65]
  • Musical instruments. Some guitar models sport aluminium diamond plates on the surface of the instruments, usually either chrome or black. Kramer Guitars and Travis Bean are both known for having produced guitars with necks made of aluminium, which gives the instrument a very distinctive sound. Aluminum is used to make some guitar resonators and some electric guitar speakers.[66]

Aluminium is usually alloyed – it is used as pure metal only when corrosion resistance and/or workability is more important than strength or hardness. The strength of aluminium alloys is abruptly increased with small additions of scandium, zirconium, or hafnium.[67] A thin layer of aluminium can be deposited onto a flat surface by physical vapor deposition or (very infrequently) chemical vapor deposition or other chemical means[which?] to form optical coatings and mirrors.

Aluminium compounds

Because aluminium is abundant and most of its derivatives exhibit low toxicity, the compounds of aluminium enjoy wide and sometimes large-scale applications.

Alumina

Main article: Aluminium oxide

Aluminium oxide (Al2O3) and the associated oxy-hydroxides and trihydroxides are produced or extracted from minerals on a large scale. The great majority of this material is converted to metallic aluminium. In 2013, about 10% of the domestic shipments in the United States were used for other applications.[68] One major use is to absorb water where it is viewed as a contaminant or impurity. Alumina is used to remove water from hydrocarbons in preparation for subsequent processes that would be poisoned by moisture.

Aluminium oxides are common catalysts for industrial processes; e.g. the Claus process to convert hydrogen sulfide to sulfur in refineries and to alkylate amines. Many industrial catalysts are "supported" by alumina, meaning that the expensive catalyst material (e.g., platinum) is dispersed over a surface of the inert alumina.

Being a very hard material (Mohs hardness 9), alumina is widely used as an abrasive; being extraordinarily chemically inert, it is useful in highly reactive environments such as high pressure sodium lamps.

Sulfates

Several sulfates of aluminium have industrial and commercial application. Aluminium sulfate (Al2(SO4)3·(H2O)18) is produced on the annual scale of several billions of kilograms. About half of the production is consumed in water treatment. The next major application is in the manufacture of paper. It is also used as a mordant, in fire extinguishers, in fireproofing, as a food additive (E number E173), and in leather tanning. Aluminium ammonium sulfate, which is also called ammonium alum, (NH4)Al(SO4)2·12H2O, is used as a mordant and in leather tanning,[69] as is aluminium potassium sulfate ([Al(K)](SO4)2)·(H2O)12. The consumption of both alums is declining.

Chlorides

Aluminium chloride (AlCl3) is used in petroleum refining and in the production of synthetic rubber and polymers. Although it has a similar name, aluminium chlorohydrate has fewer and very different applications, particularly as a colloidal agent in water purification and an antiperspirant. It is an intermediate in the production of aluminium metal.

Niche compounds

Many aluminium compounds have niche applications:

Aluminium alloys in structural applications

Main article: Aluminium alloy
Aluminium foam

Aluminium alloys with a wide range of properties are used in engineering structures. Alloy systems are classified by a number system (ANSI) or by names indicating their main alloying constituents (DIN and ISO).

The strength and durability of aluminium alloys vary widely, not only as a result of the components of the specific alloy, but also as a result of heat treatments and manufacturing processes. A lack of knowledge of these aspects has from time to time led to improperly designed structures and gained aluminium a bad reputation.

One important structural limitation of aluminium alloys is their fatigue strength. Unlike steels, aluminium alloys have no well-defined fatigue limit, meaning that fatigue failure eventually occurs, under even very small cyclic loadings. Engineers must assess applications and design for a fixed and finite life of the structure, rather than infinite life.

Another important property of aluminium alloys is sensitivity to heat. Workshop procedures are complicated by the fact that aluminium, unlike steel, melts without first glowing red. Manual blow torch operations require additional skill and experience. Aluminium alloys, like all structural alloys, are subject to internal stresses after heat operations such as welding and casting. The lower melting points of aluminium alloys make them more susceptible to distortions from thermally induced stress relief. Stress can be relieved and controlled during manufacturing by heat-treating the parts in an oven, followed by gradual cooling—in effect annealing the stresses.

The low melting point of aluminium alloys has not precluded use in rocketry, even in combustion chambers where gases can reach 3500 K. The Agena upper stage engine used regeneratively cooled aluminium in some parts of the nozzle, including the thermally critical throat region.

Another alloy of some value is aluminium bronze (Cu-Al alloy).

History

The statue of the Anteros in Piccadilly Circus, London, was made in 1893 and is one of the first statues cast in aluminium.

Ancient Greeks and Romans used aluminium salts as dyeing mordants and as astringents for dressing wounds; alum is still used as a styptic. In 1782, Guyton de Morveau suggested calling the "base" of (i.e., the metallic element in) alum alumine.[70] In 1808, Humphry Davy identified the existence of a metal base of alum, which he at first termed alumium and later aluminum (see etymology section, below).

The metal was first produced in 1825 in an impure form by Danish physicist and chemist Hans Christian Ørsted. He reacted anhydrous aluminium chloride with potassium amalgam, yielding a lump of metal looking similar to tin.[71][72] Friedrich Wöhler was aware of these experiments and cited them, but after redoing the experiments of Ørsted he concluded that this metal was pure potassium. He conducted a similar experiment in 1827 by mixing anhydrous aluminium chloride with potassium and yielded aluminium.[72] Wöhler is generally credited with isolating aluminium (Latin alumen, alum). Further, Pierre Berthier discovered aluminium in bauxite ore. Henri Etienne Sainte-Claire Deville improved Wöhler's method in 1846. As described in his 1859 book, aluminium trichloride could be reduced by sodium, which was more convenient and less expensive than potassium used by Wöhler.[73] In the mid-1880s, aluminium metal was exceedingly difficult to produce, which made pure aluminium more valuable than gold.[74] So celebrated was the metal that bars of aluminium were exhibited at the Exposition Universelle of 1855.[75] Napoleon III of France is reputed to have held a banquet where the most honored guests were given aluminium utensils, while the others made do with gold.[76][77]

Aluminium was selected as the material to use for the 100 ounces (2.8 kg) capstone of the Washington Monument in 1884, a time when one ounce (30 grams) cost the daily wage of a common worker on the project (in 1884 about $1 for 10 hours of labor; today, a construction worker in the US working on such a project might earn $25–$35 per hour and therefore around $300 in an equivalent single 10-hour day).[78] The capstone, which was set in place on 6 December 1884 in an elaborate dedication ceremony, was the largest single piece of aluminium cast at the time.[78]

The Cowles companies supplied aluminium alloy in quantity in the United States and England using smelters like the furnace of Carl Wilhelm Siemens by 1886.[79][80][81]

Hall-Heroult process: availability of cheap aluminium metal

Charles Martin Hall of Ohio in the U.S. and Paul Héroult of France independently developed the Hall-Héroult electrolytic process that facilitated large-scale production of metallic aluminium. This process remains in use today.[82] In 1888, with the financial backing of Alfred E. Hunt, the Pittsburgh Reduction Company started; today it is known as Alcoa. Héroult's process was in production by 1889 in Switzerland at Aluminium Industrie, now Alcan, and at British Aluminium, now Luxfer Group and Alcoa, by 1896 in Scotland.[83]

By 1895, the metal was being used as a building material as far away as Sydney, Australia in the dome of the Chief Secretary's Building.

With the explosive expansion of the airplane industry during World War I (1914–1917), major governments demanded large shipments of aluminium for light, strong airframes. They often subsidized factories and the necessary electrical supply systems.[84]

Many navies have used an aluminium superstructure for their vessels; the 1975 fire aboard USS Belknap that gutted her aluminium superstructure, as well as observation of battle damage to British ships during the Falklands War, led to many navies switching to all steel superstructures.

Aluminium wire was once widely used for domestic electrical wiring in the United States, and a number of fires resulted from creep and corrosion-induced failures at junctions and terminations; additional and preventable factors in the failures have been identified.[85][86] Aluminium is still used in electrical services with specially designed wire termination hardware.

Etymology

The various names all derive from its elemental presence in alum. The word comes into English from Old French, from alumen, a Latin word meaning "bitter salt".[87]

Two variants of the name are in current use: aluminium ( /ˌæljʊˈmɪniəm/) and aluminum (/əˈluːmɪnəm/). The obsolete word was alumium. The International Union of Pure and Applied Chemistry (IUPAC) adopted aluminium as the standard international name for the element in 1990 but, three years later, recognized aluminum as an acceptable variant. The IUPAC periodic table now includes both spellings.[88] IUPAC internal publications use the two spelling with nearly equal frequency.[89]

Different endings

Most countries use the ending "-ium" for "aluminium". In the United States and Canada, the ending "-um" predominates.[26][90] The Canadian Oxford Dictionary prefers aluminum, whereas the Australian Macquarie Dictionary prefers aluminium. In 1926, the American Chemical Society officially decided to use aluminum in its publications; American dictionaries typically label the spelling aluminium as "chiefly British".[91][92] The earliest citation given in the Oxford English Dictionary for any word used as a name for this element is alumium, which British chemist and inventor Humphry Davy employed in 1808 for the metal he was trying to isolate electrolytically from the mineral alumina. The citation is from the journal Philosophical Transactions of the Royal Society of London: "Had I been so fortunate as to have obtained more certain evidences on this subject, and to have procured the metallic substances I was in search of, I should have proposed for them the names of silicium, alumium, zirconium, and glucium."[93][94]

Davy settled on aluminum by the time he published his 1812 book Chemical Philosophy: "This substance appears to contain a peculiar metal, but as yet Aluminum has not been obtained in a perfectly free state, though alloys of it with other metalline substances have been procured sufficiently distinct to indicate the probable nature of alumina."[95] But the same year, an anonymous contributor to the Quarterly Review, a British political-literary journal, in a review of Davy's book, objected to aluminum and proposed the name aluminium, "for so we shall take the liberty of writing the word, in preference to aluminum, which has a less classical sound."[96]

The -ium suffix followed to the precedent set in other newly discovered elements of the time: potassium, sodium, magnesium, calcium, and strontium (all of which Davy isolated himself). Nevertheless, element names ending in -um were not unknown at the time; for example, platinum (known to Europeans since the 16th century), molybdenum (discovered in 1778), and tantalum (discovered in 1802). The -um suffix is consistent with the universal spelling alumina for the oxide (as opposed to aluminia), as lanthana is the oxide of lanthanum, and magnesia, ceria, and thoria are the oxides of magnesium, cerium, and thorium respectively.[citation needed]

The aluminum spelling is used in the Webster's Dictionary of 1828. In his advertising handbill for his new electrolytic method of producing the metal in 1892, Charles Martin Hall used the -um spelling, despite his constant use of the -ium spelling in all the patents[82] he filed between 1886 and 1903. Hall's domination of production of the metal ensured that aluminum became the standard English spelling in North America.[citation needed]

Biology

Schematic of Al absorption by human skin.[97]
There are five major Al forms absorbed by human body: the free solvated trivalent cation (Al3+(aq)); low-molecular-weight, neutral, soluble complexes (LMW-Al0(aq)); high-molecular-weight, neutral, soluble complexes (HMW-Al0(aq)); low-molecular-weight, charged, soluble complexes (LMW-Al(L)n+/−(aq)); nano and micro-particulates (Al(L)n(s)). They are transported across cell membranes or cell epi-/endothelia through five major routes: (1) paracellular; (2) transcellular; (3) active transport; (4) channels; (5) adsorptive or receptor-mediated endocytosis.[97]

Despite its widespread occurrence in the Earth crust, aluminium has no known function in biology. Aluminium salts are remarkably nontoxic, aluminium sulfate having an LD50 of 6207 mg/kg (oral, mouse), which corresponds to 500 grams for an 80 kg (180 lb) person.[14] The extremely low acute toxicity notwithstanding, the health effects of aluminium are of interest in view of the widespread occurrence of the element in the environment and in commerce.

Health concerns

In very high doses, aluminium is associated with altered function of the blood–brain barrier.[98] A small percentage of people are allergic to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium, such as antiperspirants and antacids. In those without allergies, aluminium is not as toxic as heavy metals, but there is evidence of some toxicity if it is consumed in amounts greater than 40 mg/day per kg of body mass.[99]The use of aluminium cookware has not been shown to lead to aluminium toxicity in general, however excessive consumption of antacids containing aluminium compounds and excessive use of aluminium-containing antiperspirants provide more significant exposure levels. Studies have shown that consumption of acidic foods or liquids with aluminium significantly increases aluminium absorption,[100] and maltol has been shown to increase the accumulation of aluminium in nervous and osseous tissue.[101] Furthermore, aluminium increases estrogen-related gene expression in human breast cancer cells cultured in the laboratory.[102] The estrogen-like effects of these salts have led to their classification as a metalloestrogen.

The effects of aluminium in antiperspirants have been examined over the course of decades with little evidence of skin irritation.[14] Nonetheless, its occurrence in antiperspirants, dyes (such as aluminium lake), and food additives has caused concern.[103] Although there is little evidence that normal exposure to aluminium presents a risk to healthy adults,[104] some studies point to risks associated with increased exposure to the metal.[103] Aluminium in food may be absorbed more than aluminium from water.[105] It is classified as a non-carcinogen by the US Department of Health and Human Services.[99]

In case of suspected sudden intake of a large amount of aluminium, deferoxamine mesylate may be given to help eliminate it from the body by chelation.[106]

Occupational safety

Exposure to powdered aluminium or aluminium welding fumes can cause pulmonary fibrosis. The United States Occupational Safety and Health Administration (OSHA) has set a permissible exposure limit of 15 mg/m3 time weighted average (TWA) for total exposure and 5 mg/m3 TWA for respiratory exposure. The US National Institute for Occupational Safety and Health (NIOSH) recommended exposure limit is the same for respiratory exposure but is 10 mg/m3 for total exposure, and 5 mg/m3 for fumes and powder.

Fine aluminium powder can ignite or explode, posing another workplace hazard.[107][108]

Alzheimer's disease

Aluminium has controversially been implicated as a factor in Alzheimer's disease.[109] According to the Alzheimer's Society, the medical and scientific opinion is that studies have not convincingly demonstrated a causal relationship between aluminium and Alzheimer's disease.[110] Nevertheless, some studies, such as those on the PAQUID cohort,[111] cite aluminium exposure as a risk factor for Alzheimer's disease. Some brain plaques have been found to contain increased levels of the metal.[112] Research in this area has been inconclusive; aluminium accumulation may be a consequence of the disease rather than a causal agent.[113][114]

Effect on plants

Aluminium is primary among the factors that reduce plant growth on acid soils. Although it is generally harmless to plant growth in pH-neutral soils, the concentration in acid soils of toxic Al3+ cations increases and disturbs root growth and function.[115][116][117][118]

Most acid soils are saturated with aluminium rather than hydrogen ions, a result of hydrolysis of aluminium compounds.[119] The concept of "corrected lime potential"[120] is now used to define the degree of base saturation in soil testing to determine the "lime requirement"[121][122]

Wheat has developed a tolerance to aluminium, releasing of organic compounds that bind to harmful aluminium cations. Sorghum is believed to have the same tolerance mechanism. The first gene for aluminium tolerance has been identified in wheat. It was shown that sorghum's aluminium tolerance is controlled by a single gene, as for wheat.[123] This adaptation is not found in all plants.

Biodegradation

A Spanish scientific report from 2001 claimed that the fungus Geotrichum candidum consumes the aluminium in compact discs.[124][125] Other reports all refer back to the 2001 Spanish report and there is no supporting original research. Better documented, the bacterium Pseudomonas aeruginosa and the fungus Cladosporium resinae are commonly detected in aircraft fuel tanks that use kerosene-based fuels (not AV gas), and laboratory cultures can degrade aluminium.[126] However, these life forms do not directly attack or consume the aluminium; rather, the metal is corroded by microbe waste products.[127]

See also

References

  1. ^ "aluminum". Oxford English Dictionary (Online ed.). Oxford University Press. (Subscription or participating institution membership required.)
  2. ^ "Standard Atomic Weights: Aluminium". CIAAW. 2017.
  3. ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (4 May 2022). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  4. ^ Zhang, Yiming; Evans, Julian R. G.; Yang, Shoufeng (2011). "Corrected Values for Boiling Points and Enthalpies of Vaporization of Elements in Handbooks". J. Chem. Eng. Data. 56 (2): 328–337. doi:10.1021/je1011086.
  5. ^ a b c Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
  6. ^ Unstable carbonyl of Al(0) has been detected in reaction of Al2(CH3)6 with carbon monoxide; see Sanchez, Ramiro; Arrington, Caleb; Arrington Jr., C. A. (1 December 1989). "Reaction of trimethylaluminum with carbon monoxide in low-temperature matrixes". American Chemical Society. 111 (25): 9110-9111. doi:10.1021/ja00207a023. OSTI 6973516.
  7. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 28. ISBN 978-0-08-037941-8.
  8. ^ Dohmeier, C.; Loos, D.; Schnöckel, H. (1996). "Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions". Angewandte Chemie International Edition. 35 (2): 129–149. doi:10.1002/anie.199601291.
  9. ^ Tyte, D. C. (1964). "Red (B2Π–A2σ) Band System of Aluminium Monoxide". Nature. 202 (4930): 383. Bibcode:1964Natur.202..383T. doi:10.1038/202383a0. S2CID 4163250.
  10. ^ Lide, D. R. (2000). "Magnetic susceptibility of the elements and inorganic compounds" (PDF). CRC Handbook of Chemistry and Physics (81st ed.). CRC Press. ISBN 0849304814.
  11. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  12. ^ Mougeot, X. (2019). "Towards high-precision calculation of electron capture decays". Applied Radiation and Isotopes. 154 (108884). doi:10.1016/j.apradiso.2019.108884.
  13. ^ Shakhashiri, B. Z. (17 March 2008). "Chemical of the Week: Aluminum" (PDF). SciFun.org. University of Wisconsin. Retrieved 4 March 2012.
  14. ^ a b c d e Frank, W. B. (2009). "Aluminum". Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH. doi:10.1002/14356007.a01_459.pub2.
  15. ^ a b Polmear, I. J. (1995). Light Alloys: Metallurgy of the Light Metals (3rd ed.). Butterworth-Heinemann. ISBN 978-0-340-63207-9.
  16. ^ Dieter, G. E. (1988). Mechanical Metallurgy. McGraw-Hill. ISBN 0-07-016893-8.
  17. ^ Cochran, J. F.; Mapother, D. E. (1958). "Superconducting Transition in Aluminum". Physical Review. 111 (1): 132–142. Bibcode:1958PhRv..111..132C. doi:10.1103/PhysRev.111.132.
  18. ^ Vargel, Christian (2004) [French edition published 1999]. Corrosion of Aluminium. Elsevier. ISBN 0-08-044495-4.
  19. ^ Beal, Roy E. (1 January 1999). Engine Coolant Testing : Fourth Volume. ASTM International. p. 90. ISBN 978-0-8031-2610-7.
  20. ^ Macleod, H. A. (2001). Thin-film optical filters. CRC Press. pp. 158–159. ISBN 0-7503-0688-2.
  21. ^ "Reaction of Aluminum with Water to Produce Hydrogen" (PDF). U.S. Department of Energy. 1 January 2008.
  22. ^ Dickin, A. P. (2005). "In situ Cosmogenic Isotopes". Radiogenic Isotope Geology. Cambridge University Press. ISBN 978-0-521-53017-0.
  23. ^ Dodd, R. T. (1986). Thunderstones and Shooting Stars. Harvard University Press. pp. 89–90. ISBN 0-674-89137-6.
  24. ^ Cameron, A. G. W. (1957). Stellar Evolution, Nuclear Astrophysics, and Nucleogenesis (PDF) (2nd ed.). Atomic Energy of Canada.
  25. ^ a b http://periodictable.com/Properties/A/UniverseAbundance.v.log.html
  26. ^ a b c Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 217. ISBN 978-0-08-037941-8.
  27. ^ Barthelmy, D. "Aluminum Mineral Data". Mineralogy Database. Archived from the original on 4 July 2008. Retrieved 9 July 2008. {{cite web}}: Unknown parameter |deadurl= ignored (|url-status= suggested) (help)
  28. ^ a b Chen, Z.; Huang, Chi-Yue; Zhao, Meixun; Yan, Wen; Chien, Chih-Wei; Chen, Muhong; Yang, Huaping; Machiyama, Hideaki; Lin, Saulwood (2011). "Characteristics and possible origin of native aluminum in cold seep sediments from the northeastern South China Sea". Journal of Asian Earth Sciences. 40 (1): 363–370. Bibcode:2011JAESc..40..363C. doi:10.1016/j.jseaes.2010.06.006.
  29. ^ Guilbert, J. F.; Park, C. F. (1986). The Geology of Ore Deposits. W. H. Freeman. pp. 774–795. ISBN 0-7167-1456-6.
  30. ^ Totten, G. E.; Mackenzie, D. S. (2003). Handbook of Aluminum. Marcel Dekker. p. 40. ISBN 978-0-8247-4843-2.
  31. ^ a b Emsley, J. (2001). "Aluminium". Nature's Building Blocks: An A–Z Guide to the Elements. Oxford University Press. p. 24. ISBN 0-19-850340-7.{{cite book}}: CS1 maint: ref duplicates default (link)
  32. ^ Dipaola, Anthony (4 June 2013). "U.A.E. Plans to Merge Aluminum Makers in $15 Billion Venture". http://www.bloomberg.com. Retrieved 18 March 2015. {{cite news}}: External link in |website= (help)
  33. ^ Hilmarsson, Thorsteinn. "Energy and aluminium in Iceland" (PDF). https://www.institutenorth.org. Retrieved 18 March 2015. {{cite web}}: External link in |website= (help)
  34. ^ "From alumina to aluminium". http://www.hydro.com. Retrieved 18 March 2015. {{cite web}}: External link in |website= (help)
  35. ^ a b Brown, T. J. (2009). World Mineral Production 2003–2007. British Geological Survey.
  36. ^ Schmitz, C.; Domagala, J.; Haag, P. (2006). Handbook of Aluminium Recycling. Vulkan-Verlag. p. 27. ISBN 3-8027-2936-6.
  37. ^ "The Australian Industry". Australian Aluminium Council. Archived from the original on 17 July 2007. Retrieved 11 August 2007.
  38. ^ "Bauxite and Alumina, U.S. Geological Survey, Mineral Commodity Summaries" (PDF). USGS. February 2014. p. 26. Retrieved 2 June 2014.
  39. ^ "Australian Bauxite". Australian Aluminium Council. Archived from the original on 18 July 2007. Retrieved 11 August 2007.
  40. ^ http://cecri.csircentral.net/2112/1/21-1985.pdf
  41. ^ Aluminum Recycling and Processing for Energy Conservation and Sustainability. By John A. S. Green. p. 197
  42. ^ http://www1.eere.energy.gov/manufacturing/resources/aluminum/pdfs/act-arp.pdf
  43. ^ http://www.labmet.ntua.gr/ENEXAL/news/02_03_Balomenos.pdf
  44. ^ http://www.calsmelt.com/thermical-process.html
  45. ^ https://www.researchgate.net/publication/259496389_Low_Temperature_Aluminium_Carbothermic_Smelting_Process
  46. ^ "Benefits of Recycling". Ohio Department of Natural Resources. Archived from the original on 24 June 2003. {{cite web}}: Unknown parameter |deadurl= ignored (|url-status= suggested) (help)
  47. ^ "Theoretical/Best Practice Energy Use In Metalcasting Operations" (PDF).
  48. ^ "Reciclado del aluminio. Confemetal.es ASERAL" (in Spanish). Archived from the original on 20 July 2011.
  49. ^ Hwang, J. Y.; Huang, X.; Xu, Z. (2006). "Recovery of Metals from Aluminium Dross and Salt cake" (PDF). Journal of Minerals & Materials Characterization & Engineering. 5 (1): 47.
  50. ^ "Why are dross & saltcake a concern?". www.experts123.com.
  51. ^ Dunster, A. M.; et al. (2005). "Added value of using new industrial waste streams as secondary aggregates in both concrete and asphalt". Waste & Resources Action Programme.
  52. ^ Elschenbroich, C. (2006). Organometallics. Wiley-VCH. ISBN 978-3-527-29390-2.
  53. ^ a b Dohmeier, C.; Loos, D.; Schnöckel, H. (1996). "Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions". Angewandte Chemie International Edition. 35 (2): 129–149. doi:10.1002/anie.199601291.
  54. ^ Tyte, D. C. (1964). "Red (B2Π–A2σ) Band System of Aluminium Monoxide". Nature. 202 (4930): 383–384. Bibcode:1964Natur.202..383T. doi:10.1038/202383a0.
  55. ^ Merrill, P. W.; Deutsch, A. J.; Keenan, P. C. (1962). "Absorption Spectra of M-Type Mira Variables". The Astrophysical Journal. 136: 21. Bibcode:1962ApJ...136...21M. doi:10.1086/147348.
  56. ^ Uhl, W. (2004). "Organoelement Compounds Possessing Al—Al, Ga—Ga, In—In, and Tl—Tl Single Bonds". Advances in Organometallic Chemistry. Advances in Organometallic Chemistry. 51: 53–108. doi:10.1016/S0065-3055(03)51002-4. ISBN 0-12-031151-8.
  57. ^ "Aluminum". Encyclopædia Britannica. Retrieved 6 March 2012.
  58. ^ Hetherington, L. E. (2007). World Mineral Production: 2001–2005. British Geological Survey. ISBN 978-0-85272-592-4.
  59. ^ "Rising Chinese Costs to Support Aluminum Prices". Bloomberg News. 23 November 2009.
  60. ^ Millberg, L. S. "Aluminum Foil". How Products are Made. Archived from the original on 13 July 2007. Retrieved 11 August 2007. {{cite web}}: Unknown parameter |deadurl= ignored (|url-status= suggested) (help)
  61. ^ Lyle, J. P.; Granger, D. A.; Sanders, R. E. (2005). "Aluminum Alloys". Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH. doi:10.1002/14356007.a01_481.
  62. ^ "Sustainability of Aluminium in Buildings" (PDF). European Aluminium Association. Retrieved 6 March 2012.
  63. ^ "Materials in Watchmaking – From Traditional to Exotic". Watches. Infoniac.com. Retrieved 6 June 2009.
  64. ^ "World's coinage uses 24 chemical elements, Part 1". World Coin News. 17 February 1992.
  65. ^ "World's coinage uses 24 chemical elements, Part 2". World Coin News. 2 March 1992.
  66. ^ "What is the difference between paper-cone and aluminum-cone woofers in your bass guitar speaker cabinets? – MUSIC Group. All rights reserved". musicgroup-prod.mindtouch.us. Retrieved 21 April 2016.
  67. ^ Skachkov, V. M.; Pasechnik, L. A.; Yatsenko, S.P. (2014). "Introduction of scandium, zirconium and hafnium into aluminum alloys. Dispersion hardening of intermetallic compounds with nanodimensional particles" (PDF). Nanosystems: physics, chemistry, mathematics. 5 (4).
  68. ^ "Minerals Yearbook Bauxite and Alumina" (PDF). USGS. Retrieved 8 August 2014.
  69. ^ Helmboldt, O. (2007). "Aluminum Compounds, Inorganic". Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH. doi:10.1002/14356007.a01_527.pub2.
  70. ^ de Morveau (1782) "Mémoire sur les dénominations chimiques, la nécessité d'en perfectionner le système, & les règles pour y parvenir" (Memoir on chemical names, the necessity of improving the system, and rules for attaining it), Observations sur la physique, sur l'histoire naturelle, et sur les arts, …, 19 : 370–382 ; see especially p. 378. From p. 378: "La seconde terre est celle qui sert de base à l'alun: en la nommant argille, il faudroit chercher un autre nom au minéral, qui n'en recèle jamais qu'une portion; il faudroit, suivant notre second principe, substituer le mot argilleux au mot alumineux, pour tous ses composés. Il est plus simple de conserver le dernier, & en tirer un substantif, pour indiquer l'étre primitif. Ainsi, l'on dira que l'alun ou vitriol alumineux a pour base l'alumine, que la Nature nous offre abondamment dans les argilles." (The second earth is what serves as the base in alum: by naming it "clay", one would have to seek another name for the mineral, which never harbors even a part of it; one would have to, following our second principle [for naming chemical compounds], substitute the word "clay-ish" for the word "aluminous" in all its compounds. It is simpler to retain the latter and to draw a noun from it, in order to indicate the primitive entity [i.e., element]. Thus, one will say that alum or aluminous sulfate has as [its] base alumine [i.e., aluminium], which Nature offers us abundantly in clays.)
  71. ^ Ørsted (1827) "Fra 31 Maj 1824 til 31 Maj 1825" ([Proceedings of the Society] from 31 May 1824 until 31 May 1825), Det Kongelige Danske Videnskabernes Selskabs, Philosphiske og Historiske Afhandlinger (The Royal Danish Scientific Society, Philosophical and Historical Papers), 3 : xxv–xxvi. Ørsted produced aluminium chloride (Chlorleeræret, chloride of clay ore) by passing chlorine over heated clay (Leer), and then reacted it with potassium amalgam (Kaliamalgam), which mixture, after distillation, left a lump of metal (Metalklump) resembling tin (Tinnet), which he called "clay metal" (Leermetal).
  72. ^ a b Wöhler, F. (1827). "Ueber das Aluminium". Annalen der Physik und Chemie. 2nd series. 11: 146–161.
  73. ^ Sainte-Claire Deville, H. E. (1859). De l'aluminium, ses propriétés, sa fabrication. Paris: Mallet-Bachelier.
  74. ^ Polmear, I. J. (2006). "Production of Aluminium". Light Alloys from Traditional Alloys to Nanocrystals. Elsevier/Butterworth-Heinemann. pp. 15–16. ISBN 978-0-7506-6371-7.
  75. ^ Karmarsch, C. (1864). "Fernerer Beitrag zur Geschichte des Aluminiums". Polytechnisches Journal. 171 (1): 49.
  76. ^ Venetski, S. (1969). ""Silver" from clay". Metallurgist. 13 (7): 451–453. doi:10.1007/BF00741130.
  77. ^ "Friedrich Wohler's Lost Aluminum". ChemMatters: 14. October 1990.
  78. ^ a b Binczewski, G. J. (1995). "The Point of a Monument: A History of the Aluminum Cap of the Washington Monument". JOM. 47 (11): 20–25. Bibcode:1995JOM....47k..20B. doi:10.1007/BF03221302.
  79. ^ "Cowles' Aluminium Alloys". The Manufacturer and Builder. 18 (1): 13. 1886. Retrieved 6 March 2012.
  80. ^ McMillan, W. G. (1891). A Treatise on Electro-Metallurgy. London: Charles Griffin and Company, Philadelphia: J. B. Lippincott Company. pp. 302–305. Retrieved 26 October 2007.
  81. ^ Sackett, W. E.; Scannell, J. J.; Watson, M. E. (1917). Scannel's New Jersey's First Citizens and State Guide. J.J. Scannell. pp. 103–105. Retrieved 25 October 2007.
  82. ^ a b US patent 400664, Charles Martin Hall, "Process of Reducing Aluminium from its Fluoride Salts by Electrolysis", issued 1889-04-02 
  83. ^ Wallace, D. H. (1977) [1937]. Market Control in the Aluminum Industry (Reprint ed.). Arno Press. p. 6. ISBN 0-405-09786-7.
  84. ^ Mats Ingulstad, "'We Want Aluminum, No Excuses': Business-Government Relations in the American Aluminum Industry, 1917–1957," in From Warfare to Welfare: Business-Government Relations in the Aluminium Industry, ed. Mats Ingulstad and Hans Otto Frøland, 33–68. (Oslo: Tapir Academic Press, 2012.)
  85. ^ Home Inspection and Building Inspection: The Hazards of Aluminum Wiring
  86. ^ Aluminum wiring
  87. ^ "Online Etymology Dictionary". Etymonline.com. Retrieved 3 May 2010.
  88. ^ IUPAC Periodic Table of the Elements. iupac.org
  89. ^ IUPAC Web site publication search for 'aluminum'.
  90. ^ Bremner, John Words on Words: A Dictionary for Writers and Others Who Care about Words, pp. 22–23. ISBN 0-231-04493-3.
  91. ^ "Aluminium – Definition and More from the Free Merriam-Webster Dictionary". Retrieved 23 July 2013.
  92. ^ "aluminium – Definition of aluminium (Webster's New World and American Heritage Dictionary)". Retrieved 23 July 2013.
  93. ^ "alumium", Oxford English Dictionary. Ed. J.A. Simpson and E.S.C. Weiner, second edition Oxford: Clarendon Press, 1989. OED Online Oxford University Press. Accessed 29 October 2006. Citation is listed as "1808 SIR H. DAVY in Phil. Trans. XCVIII. 353". The ellipsis in the quotation is as it appears in the OED citation.
  94. ^ Davy, Humphry (1808). "Electro Chemical Researches, on the Decomposition of the Earths; with Observations on the Metals obtained from the alkaline Earths, and on the Amalgam procured from Ammonia". Philosophical Transactions of the Royal Society. 98. Royal Society of London.: 353. doi:10.1098/rstl.1808.0023. Retrieved 10 December 2009.
  95. ^ Davy, Humphry (1812). Elements of Chemical Philosophy. ISBN 0-217-88947-6. Retrieved 10 December 2009.
  96. ^ "Elements of Chemical Philosophy By Sir Humphry Davy". Quarterly Review. VIII. John Murray: 72. 1812. ISBN 0-217-88947-6. Retrieved 10 December 2009.
  97. ^ a b Exley, C. (2013). "Human exposure to aluminium". Environmental Science: Processes & Impacts. 15 (10): 1807. doi:10.1039/C3EM00374D.
  98. ^ Banks, W.A.; Kastin, AJ (1989). "Aluminum-induced neurotoxicity: alterations in membrane function at the blood–brain barrier". Neurosci Biobehav Rev. 13 (1): 47–53. doi:10.1016/S0149-7634(89)80051-X. PMID 2671833.
  99. ^ a b Dolara, Piero (21 July 2014). "Occurrence, exposure, effects, recommended intake and possible dietary use of selected trace compounds (aluminium, bismuth, cobalt, gold, lithium, nickel, silver)". International Journal of Food Sciences and Nutrition. 65. Informa Plc.: 911–924. doi:10.3109/09637486.2014.937801. ISSN 1465-3478. PMID 25045935.
  100. ^ Slanina, P.; French, W; Ekström, LG; Lööf, L; Slorach, S; Cedergren, A (1986). "Dietary citric acid enhances absorption of aluminum in antacids". Clinical Chemistry. 32 (3). American Association for Clinical Chemistry: 539–541. PMID 3948402.
  101. ^ Van Ginkel, MF; Van Der Voet, GB; D'haese, PC; De Broe, ME; De Wolff, FA (1993). "Effect of citric acid and maltol on the accumulation of aluminum in rat brain and bone". The Journal of laboratory and clinical medicine. 121 (3): 453–60. PMID 8445293.
  102. ^ Darbre, P. D. (2006). "Metalloestrogens: an emerging class of inorganic xenoestrogens with potential to add to the oestrogenic burden of the human breast". Journal of Applied Toxicology. 26 (3): 191–7. doi:10.1002/jat.1135. PMID 16489580.
  103. ^ a b Ferreira, PC; Piai Kde, A; Takayanagui, AM; Segura-Muñoz, SI (2008). "Aluminum as a risk factor for Alzheimer's disease". Revista Latino-americana de enfermagem. 16 (1): 151–7. doi:10.1590/S0104-11692008000100023. PMID 18392545.
  104. ^ Gitelman, H. J. "Physiology of Aluminum in Man", in Aluminum and Health, CRC Press, 1988, ISBN 0-8247-8026-4, p. 90
  105. ^ Yokel RA; Hicks CL; Florence RL (2008). "Aluminum bioavailability from basic sodium aluminum phosphate, an approved food additive emulsifying agent, incorporated in cheese". Food and Chemical Toxicology. 46 (6): 2261–6. doi:10.1016/j.fct.2008.03.004. PMC 2449821. PMID 18436363.
  106. ^ Aluminum Toxicity from NYU Langone Medical Center. Last reviewed November 2012 by Igor Puzanov, MD
  107. ^ "CDC – NIOSH Pocket Guide to Chemical Hazards – Aluminum". www.cdc.gov. Retrieved 11 June 2015.
  108. ^ "CDC – NIOSH Pocket Guide to Chemical Hazards – Aluminum (pyro powders and welding fumes, as Al)". www.cdc.gov. Retrieved 11 June 2015.
  109. ^ Ferreira PC; Piai Kde A; Takayanagui AM; Segura-Muñoz SI (2008). "Aluminum as a risk factor for Alzheimer's disease". Rev Lat Am Enfermagem. 16 (1): 151–7. doi:10.1590/S0104-11692008000100023. PMID 18392545.
  110. ^ Aluminium and Alzheimer's disease, The Alzheimer's Society. Retrieved 30 January 2009.
  111. ^ Rondeau, V.; Jacqmin-Gadda, H.; Commenges, D.; Helmer, C.; Dartigues, J.-F. (2008). "Aluminum and Silica in Drinking Water and the Risk of Alzheimer's Disease or Cognitive Decline: Findings From 15-Year Follow-up of the PAQUID Cohort". American Journal of Epidemiology. 169 (4): 489–96. doi:10.1093/aje/kwn348. PMC 2809081. PMID 19064650.
  112. ^ Yumoto, Sakae; Kakimi, Shigeo; Ohsaki, Akihiro; Ishikawa, Akira (2009). "Demonstration of aluminum in amyloid fibers in the cores of senile plaques in the brains of patients with Alzheimer's disease". Journal of Inorganic Biochemistry. 103 (11): 1579–84. doi:10.1016/j.jinorgbio.2009.07.023. PMID 19744735.
  113. ^ "Alzheimer's Disease and Aluminum". National Institute of Environmental Health Sciences. 2005. Archived from the original on 3 February 2007. {{cite web}}: Unknown parameter |deadurl= ignored (|url-status= suggested) (help)
  114. ^ Hopkin, Michael (21 April 2006). "Death of Alzheimer victim linked to aluminium pollution". News@nature. doi:10.1038/news060417-10.
  115. ^ Belmonte Pereira, Luciane; Aimed Tabaldi, Luciane; Fabbrin Gonçalves, Jamile; Jucoski, Gladis Oliveira; Pauletto, Mareni Maria; Nardin Weis, Simone; Texeira Nicoloso, Fernando; Brother, Denise; Batista Teixeira Rocha, João; Chitolina Schetinger, Maria Rosa Chitolina (2006). "Effect of aluminum on δ-aminolevulinic acid dehydratase (ALA-D) and the development of cucumber (Cucumis sativus)". Environmental and experimental botany. 57 (1–2): 106–115. doi:10.1016/j.envexpbot.2005.05.004.
  116. ^ Andersson, Maud (1988). "Toxicity and tolerance of aluminium in vascular plants". Water, Air, & Soil Pollution. 39 (3–4): 439–462. doi:10.1007/BF00279487.
  117. ^ Horst, Walter J. (1995). "The role of the apoplast in aluminium toxicity and resistance of higher plants: A review". Zeitschrift für Pflanzenernährung und Bodenkunde. 158 (5): 419–428. doi:10.1002/jpln.19951580503.
  118. ^ Ma, Jian Feng; Ryan, PR; Delhaize, E (2001). "Aluminium tolerance in plants and the complexing role of organic acids". Trends in Plant Science. 6 (6): 273–278. doi:10.1016/S1360-1385(01)01961-6. PMID 11378470.
  119. ^ Turner, R.C.; Clark J.S. (1966). "Lime potential in acid clay and soil suspensions". Trans. Comm. II & IV Int. Soc. Soil Science: 208–215. {{cite journal}}: Unknown parameter |last-author-amp= ignored (|name-list-style= suggested) (help)
  120. ^ "corrected lime potential (formula)". Sis.agr.gc.ca. 27 November 2008. Retrieved 3 May 2010.
  121. ^ Turner, R.C. (1965). "A Study of the Lime Potential". Research Branch, Department Of Agriculture.
  122. ^ Applying lime to soils reduces the Aluminum toxicity to plants. "One Hundred Harvests Research Branch Agriculture Canada 1886–1986". Historical series / Agriculture Canada – Série historique / Agriculture Canada. Government of Canada. Retrieved 22 December 2008.
  123. ^ Magalhaes, J. V.; Garvin, DF; Wang, Y; Sorrells, ME; Klein, PE; Schaffert, RE; Li, L; Kochian, LV (2004). "Comparative Mapping of a Major Aluminum Tolerance Gene in Sorghum and Other Species in the Poaceae". Genetics. 167 (4): 1905–14. doi:10.1534/genetics.103.023580. PMC 1471010. PMID 15342528.
  124. ^ "Fungus 'eats' CDs". BBC. June 2001.
  125. ^ "Fungus eats CD". Nature. 2001.
  126. ^ J. E. Sheridan; Jan Nelson; Y. L. Tan¬. "STUDIES ON THE 'KEROSENE FUNGUS' CLADOSPORIUM RESINAE (LINDAU) DE VRIES — PART I. THE PROBLEM OF MICROBIAL CONTAMINATION OF AVIATION FUELS". Tuatara: 29.
  127. ^ "Fuel System Contamination & Starvation". Duncan Aviation. 2011.

Further reading

  • Mimi Sheller, Aluminum Dream: The Making of Light Modernity. Cambridge, MA: Massachusetts Institute of Technology Press, 2014.
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